Effect of crude oil exploration and exploitation activities on soil, water and air in a Nigerian community.

The continuous degradation of environmental ecosystems (land, water and soil) resulting from crude oil exploration and exploitation activities continues to gain global attention. This study investigates the effects of crude oil exploration and exploitation activities on soil, water and air in the study area. Soil samples were collected in three replicates at depths of 0-15 and 15-30 cm at sampling distances of 20, 100 and 200 m a from core oil exploitation operation area and a control point. Water samples were also taken from within the study area and analyzed using standard procedures. Major pollutants concentrations of particulate matter (PM2.5 and PM10) of the air were also measured using Air Quality Index (AQI). The results reveal that the soil, water and air parameters measured mostly at 20 m from the core oil operation area compromise the allowable standards provided for healthy living. In the same manner, some results at 100 and 200 m were slightly higher than the recommended values in some cases of heavy metals and bacteria activities in the soil. The AQI at 20 m was far above the permissible limit provided by the Environmental Protection Agency while others are gradually drawing towards the limit given for each pollutant. To safeguard the health of the residents of the host community and oil field workers, there is a need for proper and frequent environmental monitoring and assessment by authorized regulatory bodies in Nigeria. This will prevent any future exposure which may endanger the lives of the dwellers.

Risk Assessment of Heavy Metals Occurrence in Two Wild Edible Oyster Mushrooms (Pleurotus spp.) Collected from Rajaji National Park.

This study aimed at assessing the concentration of six heavy metals (Cd, Cr, Cu, Fe, Mn, and Zn) in two wild edible oyster mushrooms (Pleurotus ostreatus and Pleurotus djamor) collected from Rajaji National Park in Haridwar, India. For this purpose, mushroom samples were collected from selected locations (forest, residential, tourist, industrial areas, and transportation activities) from June 2021 to July 2022 and subsequently analyzed for selected heavy metals using atomic absorption spectroscopy (AAS). Results showed that both Pleurotus spp. had significantly varying (p < 0.05) concentrations of heavy metals. However, P. ostreatus showed relatively higher concentration levels of these metals compared to P. djamor. The mean concentrations (mg/kg dry weight) of the Cd, Cr, Cu, Fe, Mn, and Zn in P. ostreatus and P. djamor were 0.10 and 0.08, 0.87 and 0.64, 16.19 and 14.77, 28.49 and 27.15, 9.93 and 8.73, and 18.15 and 15.76, respectively. As indicated by the multivariate analysis tools i.e., principal component analysis (PCA) and hierarchical cluster analysis (HCA), the locations near the residential, industrial, and transportation activities had higher concentration levels of heavy metals. Moreover, the health risk studies using the target hazard quotient (THQ < 1) showed no significant health risk as the consumption of both Pleurotus spp., except for at one location, had high-traffic activities. The findings of this study provide vital information about the occurrence of potentially toxic heavy metals in wild edible Pleurotus spp. in Rajaji National Park in Haridwar, India representing a safeguard for mushroom consumers.

Integrated seawater intrusion and groundwater quality assessment of a coastal aquifer: GALDIT, geospatial and analytical approaches.

The pressure and dependence on coastal aquifers are on the rise in many parts of the globe. These lead to overexploitation, aggravated levels of groundwater pollution, and seawater intrusion. Integrated analyses can create holistic insights into the quality and the vulnerability of aquifers to seawater intrusion. In this study, Mombasa North coast's coastal aquifer was characterized by integrating multiple approaches-GALDIT overlay index, seawater intrusion groundwater quality index GQISWI, total hardness, water quality index (WQI)-and the results were further explored and interpreted with geospatial analysis techniques. The study suggests that the predominant water type in areas under moderate or high vulnerabilities to seawater intrusion is the Na-Cl water type. However, similar Na-Cl water types can produce a range of total hardness from soft to hard. GQISWI classification can be used to narrow down the observations from Stuyfzand's TH-based classification system. In the aquifer studied, the results of the GALDIT overlay index, a weighted aggregation of intrinsic parameters contributing to seawater intrusion, show that 29%, 59%, and 12% of the aquifer have low, moderate, and high vulnerabilities, respectively. The GQISWI analysis indicates that the groundwater is largely brackish (68%) but saline towards the southern end of the aquifer at 32%. Total hardness values indicate that 67% of the aquifer's coverage falls under the "moderately hard" category. The geodatabase creation introduced in the study provides a template for similar studies and a baseline for future WQI and water quality monitoring. However, temporal studies on chronological timescales are recommended for sustainable management of the aquifer.

Evaluating the effect of fenton pretreated pyridine wastewater under different biological conditions: Microbial diversity and biotransformation pathways.

Pyridine contamination poses a significant threat to human and environmental health. Due to the presence of nitrogen atom in the pyridine ring, the pi bond electrons are attracted toward it and make difficult for pyridine treatment with biological and chemical methods. In this study, coupling Fenton treatment with different biological process was designed to enhance pyridine biotransformation and further mineralization. After Fenton oxidation process optimized, pretreated pyridine was evaluated under three biological (anaerobic, aerobic and microaerobic) operating conditions. Under optimum Fenton oxidation, pyridine (30-75%) and TOC (5-25%) removal efficiencies were poor. Biological process alone also showed insignificant removal efficiency, particularly anaerobic (pyridine = 8.2%; TOC = 5.3%) culturing condition. However, combining Fenton pretreatment with biological process increased pyridine (93-99%) and TOC (87-93%) removals, suggesting that hydroxyl radical generated during Fenton oxidation enhanced pyridine hydroxylation and further mineralization in the biological (aerobic > microaerobic > anaerobic) process. Intermediates were analyzed with UPLC-MS and showed presence of maleic acid, pyruvic acid, glutaric dialdehyde, succinic semialdehyde and 4-formylamino-butyric acid. High-throughput sequencing analysis also indicated that Proteobacteria (35-43%) followed by Chloroflexi (10.6-24.3%) and Acidobacteria (8.0-29%) were the dominant phyla detected in the three biological treatment conditions. Co-existence of dominant genera under aerobic/microaerobic (Nitrospira > Dokdonella > Caldilinea) and anaerobic (Nitrospira > Caldilinea > Longilinea) systems most probably play significant role in biotransformation of pyridine and its intermediate products. Overall, integrating Fenton pretreatment with different biological process is a promising technology for pyridine treatment, especially the combined system enhanced anaerobic (>10 times) microbial pyridine biotransformation activity.