Application of Plant-Based Edible Coatings and Extracts Influences the Postharvest Quality and Shelf Life Potential of "Surahi" Guava Fruits.

Guava fruits have a short shelf life due to climacteric nature. The current work was conducted to extend the shelf life of guavas with garlic extract (GRE), ginger extract (GNE), gum arabic (GA), and Aloe vera (AV) gel coatings. After coating, fruits of guava were stored at 25 ± 3 °C and RH 85 ± 2% for 15 days. Results showed that guavas treated with plant-based edible coatings and extracts had lower weight loss than that of the control. GRE-treated guavas had the maximum shelf life in contrast to all other treatments including the control. GNE-treated guavas showed the lowest nonreducing sugar content, whereas they had higher antioxidant activity, vitamin C content, and total phenolics compared with all other coating treatments. After the control, antioxidant capacity was the highest in GNE- and GRE-treated fruits. On the other hand, GA-treated guavas had reduced total soluble solids and juice pH (more acidic) and exhibited higher total flavonoids compared with the control, while both GA- and GNE-treated guavas had the highest flavonoid content. GRE-treated fruits exhibited the highest total sugar content and taste and aroma scores. In conclusion, GRE treatment was more effective in conserving the quality and extending the shelf life of guava fruits.

Global material flow analysis of end-of-life of lithium nickel manganese cobalt oxide batteries from battery electric vehicles.

The global market for battery electric vehicles (BEVs) is continuously increasing which results in higher material demand for the production of Li-ion batteries (LIBs). Therefore, the end of life (EOL) of batteries must be handled properly through reusing or recycling to minimize the supply chain issues in future LIBs. This study analyses the global distribution of EOL lithium nickel manganese cobalt (NMC) oxide batteries from BEVs. The Stanford estimation model is used, assuming that the lifespan of NMC batteries follows a Weibull distribution. The global sales data of NMC batteries from 2009 to 2018 were collected and the sales data from 2019 to 2030 were estimated based on historical trends and BEV development plans in the top 10 countries for BEV sales. The result shows a view of EOL NMC batteries worldwide. In 2038, China, South Korea and the United States (US) will be the three leading countries in the recovery of NMC battery materials. An overall global flow of NMC battery materials (aluminium, copper, manganese, steel, lithium and graphite/carbon) was also predicted in this research. This study estimated the waste potential of NMC battery materials specifically in the top 10 countries and also in other countries. Finally, the economic value estimation results for recovered materials indicated that copper, aluminium and manganese will have cumulative economic values of 7.9, 4.4 and 3.9 billion US dollars in 2038, respectively. As this study considers the different specific energy of NMC batteries in the coming years due to technological advancement, the findings can provide a more realistic insight into the future demand for NMC battery materials. This study reveals that a high number of EOL NMC batteries will be accumulated in 2038 in several countries. Therefore, large-scale recycling infrastructures should be set up to improve the efficiency of the recovery of battery materials.

Improvement in Durability and Mechanical Performance of Concrete Exposed to Aggressive Environments by Using Polymer.

Concrete is the most widely used construction material. However, it cannot sustain the harsh environment and can easily deteriorate. It results in repair and reworks that amount to a considerable loss of money and time. The life span of concrete reduces if exposed to external attacks, for instance, sulfate attacks, alkali-silica reactions, corrosion, and drying shrinkage. These ubiquitous attacks cause a reduction in service life and raise the need for early repair and maintenance, resulting in higher life cycle costs and structural failures. To resolve these issues, the potential of styrene-butadiene-rubber (SBR) ultrafine powder as cement replacement polymeric admixture at 0%, 3%, 5%, 7%, and 10% have been evaluated. The effect of SBR-powder on concrete is investigated by conducting an alkali-silica reactivity test (ASR), rapid-chloride-permeability test (RCPT), drying shrinkage, and sulfate resistivity tests. Workability, compressive and flexural strength tests are also conducted. For ASR and drying shrinkage, mortar bar samples were cast, exposed to respective environments, and the percentage change in length was measured. For mechanical tests and RCPT, prisms, cylinders and cubes were cast and tested at 28 days. The SBR-powder modification reduces concrete's permeability, drying shrinkage, and expansions due to ASR and sulfate attacks. SBR powder increased workability by 90%, compressive strength by 23%, and flexural strength by 9.4% in concrete when used at 10% cement replacement by weight. The SBR-powder (10%) modification reduced the RCPT value by up to one-third (67%), drying shrinkage by 53%, ASR by 57%, and sulfate reaction by 73%. Consequently, SBR powder usage can adequately improve the workability, mechanical properties, and durability of the concrete and lead to advanced sustainable concrete with low repair requirements.

Recycling of Waste Facial Masks as a Construction Material, a Step towards Sustainability.

Amid the COVID-19 pandemic, a sudden surge in the production and utilization of disposable, single-use facial masks has been observed. Delinquency in proper disposal of used facial masks endangers the environment with a new form of non-biodegradable plastic waste that will take hundreds of years to break down. Therefore, there is an urgent need for the resourceful recycling of such waste in an environmentally friendly way. This study presents an efficient solution by using waste masks in fibered or crushed form to produce environmentally friendly and affordable green concrete. This investigation assessed the mechanical and durability properties of waste masks-incorporated concrete. A total of six mixes were prepared for standardized tests to determine compressive strength, split cylinder tensile strength and rapid chloride penetration test (RCPT), and freeze-thaw resistance. The percentage of mask fibers used were 0.5, 1, 1.5, and 2% of concrete by volume, while crushed masks were used at 0.5% only. The mask waste in both forms was found suitable to be used in concrete. One percent of waste mask fibers was found as an optimum value to increase compressive and tensile strength, reduce chloride permeability, and increase freeze-thaw resistance. Besides this, 0.5% crushed mask fiber also performed well, especially for producing less permeable and highly durable concrete. It is thus corroborated that waste masks that increase pollution worldwide can be utilized sustainably to help build green buildings. By reutilizing waste masks to produce improved concrete with better strengths and higher durability, circular economy and sustainability are achieved, along with efficient waste management.

Effect of Silicon Carbide and Tungsten Carbide on Concrete Composite.

Flexural strength of concrete is an important property, especially for pavements. Concrete with higher flexural strength has fewer cracking and durability issues. Researchers use different materials, including fibers, polymers, and admixtures, to increase the flexural strength of concrete. Silicon carbide and tungsten carbide are some of the hardest materials on earth. In this research, the mechanical properties of carbide concrete composites were investigated. The silicon carbide and tungsten carbide at different percentages (1%, 2%, 3%, and 4%) by weight of cement along with hybrid silicon carbide and tungsten carbide (2% and 4%) were used to produce eleven mixes of concrete composites. The mechanical tests, including a compressive strength test and flexural strength test, along with the rapid chloride permeability test (RCPT), were conducted. It was concluded that mechanical properties were enhanced by increasing the percentages of both individual and hybrid carbides. The compressive strength was increased by 17% using 4% tungsten carbide, while flexural strength was increased by 39% at 4% tungsten carbide. The significant effect of carbides on flexural strength was also corroborated by ANOVA analysis. The improvement in flexural strength makes both carbides desirable for use in concrete pavement. Additionally, the permeability, the leading cause of durability issues, was reduced considerably by using tungsten carbide. It was concluded that both carbides provide promising results by enhancing the mechanical properties of concrete and are compatible with concrete to produce composites.

Application of Gene Expression Programming (GEP) for the Prediction of Compressive Strength of Geopolymer Concrete.

For the production of geopolymer concrete (GPC), fly-ash (FA) like waste material has been effectively utilized by various researchers. In this paper, the soft computing techniques known as gene expression programming (GEP) are executed to deliver an empirical equation to estimate the compressive strength of GPC made by employing FA. To build a model, a consistent, extensive and reliable data base is compiled through a detailed review of the published research. The compiled data set is comprised of 298 experimental results. The utmost dominant parameters are counted as explanatory variables, in other words, the extra water added as percent FA (), the percentage of plasticizer (), the initial curing temperature (), the age of the specimen (), the curing duration (), the fine aggregate to total aggregate ratio (), the percentage of total aggregate by volume (), the percent SiO2 solids to water ratio () in sodium silicate (Na2SiO3) solution, the NaOH solution molarity (), the activator or alkali to FA ratio (), the sodium oxide (Na2O) to water ratio () for preparing Na2SiO3 solution, and the Na2SiO3 to NaOH ratio (). A GEP empirical equation is proposed to estimate the of GPC made with FA. The accuracy, generalization, and prediction capability of the proposed model was evaluated by performing parametric analysis, applying statistical checks, and then compared with non-linear and linear regression equations.

Prediction of Compressive Strength of Fly Ash Based Concrete Using Individual and Ensemble Algorithm.

Machine learning techniques are widely used algorithms for predicting the mechanical properties of concrete. This study is based on the comparison of algorithms between individuals and ensemble approaches, such as bagging. Optimization for bagging is done by making 20 sub-models to depict the accurate one. Variables like cement content, fine and coarse aggregate, water, binder-to-water ratio, fly-ash, and superplasticizer are used for modeling. Model performance is evaluated by various statistical indicators like mean absolute error (MAE), mean square error (MSE), and root mean square error (RMSE). Individual algorithms show a moderate bias result. However, the ensemble model gives a better result with R2 = 0.911 compared to the decision tree (DT) and gene expression programming (GEP). K-fold cross-validation confirms the model's accuracy and is done by R2, MAE, MSE, and RMSE. Statistical checks reveal that the decision tree with ensemble provides 25%, 121%, and 49% enhancement for errors like MAE, MSE, and RMSE between the target and outcome response.

Experimental Investigation of Hybrid Carbon Nanotubes and Graphite Nanoplatelets on Rheology, Shrinkage, Mechanical, and Microstructure of SCCM.

Carbon nanotubes (CNTs) and graphite nanoplatelets (GNPs) belong to the family of graphite nanomaterials (GNMs) and are promising candidates for enhancing properties of cementitious matrix. However, the problem lies with their improper dispersion. In this paper graphite nanoplatelets are used with carbon nanotubes for dispersion facilitation of CNTs in cement mortar. The intended role is to use the GNPs particles for dispersion of CNTs and to investigate the synergistic effect of resulting nano-intruded mortar. Mechanical properties such as flexure and compressive strength have been studied along with volumetric stability, rheology, and workability. Varying dosages of CNTs to GNPs have been formulated and were analyzed. The hybrid use of CNTs-GNPs shows promise. Scanning electron microscopy reveals that hybrid CNTs/GNPs are well-suited for use in cement mortar composite performing a dual function.