A review of synthesis, fabrication, and emerging biomedical applications of metal-organic frameworks.

The overwhelming potential of porous coordination polymers (PCP), also known as Metal-Organic Frameworks (MOFs), especially their nanostructures for various biomedical applications, have made these materials worth investigating for more applications and uses. MOFs unique structure has enabled them for most applications, particularly in biomedical and healthcare. A number of very informative review papers are available on the biomedical applications of MOFs for the reader's convenience. However, many of those reviews focus mainly on drug delivery applications, and no significant work has been reported on other MOFs for biomedical applications. This review aims to present a compact and highly informative global assessment of the recent developments in biomedical applications (excluding drug-delivery) of MOFs along with critical analysis. Researchers have recently adopted both synthetic and post-synthetic routes for the fabrication and modification of MOFs that have been discussed and analyzed. A critical review of the latest reports on the significant and exotic area of bio-sensing capabilities and applications of MOFs has been given in this study. In addition, other essential applications of MOFs, including photothermal therapy, photodynamic therapy, and antimicrobial activities, are also included. These recently grown emergent techniques and cancer treatment options have gained attention and require further investigations to achieve fruitful outcomes. MOF's role in these applications has been thoroughly discussed, along with future challenges and valuable suggestions for the research community that will help meet future demands.

A review on bismuth oxyhalide based materials for photocatalysis.

Photocatalytic solar energy transformation is the most encouraging solution to alleviate the environmental crisis and energy scarcity. Bismuth oxyhalide (BiOX) is an emerging class of materials that exhibits photocatalytic properties, such as resilient response to light, which causes enhanced energy conversion (solar energy) owing to their exceptional layered structure and attractive band structure. The present review presents a summary of results from the recent developments on the tuning and design of BiOX-based materials to improve the energy conversion. In particular, the preparation and tuning approaches that have the potential to enhance the photocatalytic behavior of BiOX and some other techniques, such as elemental doping, are addressed, which prevent the rapid recombination of charges, and formation of oxygen vacancies, facilitating an improvement in the photocatalytic reaction. Various frameworks are also presented, displaying the significance of BiOX-based nanocomposites. Finally, the main challenges and opportunities associated with the future progress of BiOX-based materials are presented. This review will provide an extended understanding and offer a preferred direction for the innovative design of BiOX-based materials for environmental and especially energy-based applications.