Geochemistry aspects of modern mercury accumulation in bottom sediments from the south-western Chukchi Sea.

Mercury (Hg) having a high migration capacity reach the Arctic region via the atmosphere. The absorbers for Hg are sea bottom sediments. Sedimentation in the Chukchi Sea occurs under the influence of highly productive Pacific waters entering through the Bering Strait and the inflow of a terrigenous component from the western direction with the Siberian Coastal Current. The Hg concentrations ranged from 12 µg kg-1 to 39 µg kg-1 in bottom sediments of study polygon. Based on dating sediment core the background concentration was 29 µg kg-1. Concentration of Hg in fine sediment fractions was 82 µg kg-1, in sandy fractions (>63 µm) varied from 8 to12 µg kg-1. In recent decades the Hg accumulation in bottom sediments has been controlled by the biogenic component. The Hg in the studied sediments presents as sulfide form.

Distribution and contamination assessment of trace metals in surface sediments of the South China Sea, Vietnam.

The distribution and enrichment of trace metals in sediments of the South China Sea along the entire coast of Vietnam were described. The concentrations of Cr, Ni, Zn, and Pb in the sediments showed a significant positive correlation with fine-sized fractions and TOC. In contrast, the concentration of As was not positively correlated with particle size and other metals. The relatively positive correlations of Cd with Fe, Al, Ti, Sc, TOC, P, Cr, Ni, Zn, and Pb indicated that it comes from different sources. Ecotoxicological indexes of all elements showed low values, except for Cd in the southwestern part of the South China Sea area, which is likely related to the influx of suspended matter from the Mekong River.

Trace metals in surface sediments from the Laptev and East Siberian Seas: Levels, enrichment, contamination assessment, and sources.

Trace metals in Laptev and East Siberian Sea sediments were analyzed to examine the element distribution pattern and to assess sediment contamination using contamination indices. The maximum Cr, Zn, Ni, Cu, and As concentrations occurred in the deeper parts of the East Siberian and Laptev Seas and the estuarine shelves of the Lena and Yana Rivers, and a high Cd content was observed in the sediment of the eastern part of the East Siberian Sea. The increased Cd concentration could be a result of the large number of phytoplankton supplied by the highly productive waters of the Bering Sea and the sorption capacity of Cd precipitation on Fe and Mn oxyhydroxides in seawater. The mean enrichment factors and geoaccumulation index values for Cr, Ni, Cu, Zn, Pb, and Cd showed no contamination by these metals at any sampling locations; however, slight As enrichment was found, possibly originating from natural sources.

Assessment of mercury levels in modern sediments of the East Siberian Sea.

Mercury (Hg) is an important environmental indicator of anthropogenic pollution. In this study, the Hg content in the bottom sediments of the East Siberian Sea was observed to range from 13 to 92 ppb, with an average of 36 ppb. Facies dependence was also observed and expressed as an increase in the Hg concentration in fine-sized sediments on the shelf edge and continental slope, compared to that in the sandy silts and sands of the inner shelf. The Hg accumulation in bottom sediments of the eastern part has increased over the past 150 years due to an increase in global emissions of anthropogenic Hg, which is caused by the transboundary transport of Hg to the Arctic. Moreover, changes in the Hg value, which occur due to the plankton arriving at the bottom sediments because of changes in hydrology and primary production, are thought to be associated with global warming.

Trace metals in deep-sea sediments collected from Kuril Basin (Sea of Okhotsk) and Kuril-Kamchatka Trench area.

Heavy metal concentrations in deep-sea sediments collected from Kuril Basin (Sea of Okhotsk) and Kuril-Kamchatka Trench area were analyzed. For the Kuril Basin, a geochemical natural background of these elements was identified based on a dated core. The results showed enrichment by heavy metals due to natural factors in the study area. All heavy metals showed a low ecological risk; thus, the potential ecological risk of the study area was also low.

Gaseous elemental mercury (Hg(0)) in the surface air over the Sea of Japan, the Sea of Okhotsk and the Kuril-Kamchatka sector of the Pacific Ocean in August-September 2017.

The northwestern Pacific Ocean including the Sea of Japan and the Sea of Okhotsk is one of the least studied regions in terms of mercury behavior and distribution in the sea-atmosphere system. In August and September 2017, we determined gaseous elemental mercury (Hg(0)) in the surface air over this water areas along a 12,000 km cruise. Concentrations varied from 1.07 to 2.74 ng m-3, with an average value of 1,68 ±â€¯0.23 ng m-3 (N = 1853). The average concentrations for the Sea of Japan, the Sea of Okhotsk and the Kuril-Kamchatka sector of the Pacific Ocean were 1.61 ng m-3, 1.71 ng m-3 and 1.61 ng m-3, respectively. The maximum concentrations were observed in the Sea of Okhotsk during periods when air masses arrived from the southern and central Kuril Islands. We believe that the reason for that was volcanic activity. The minimum concentrations were registered in air masses arriving from the northeastern Russia and from open sea areas. In the Sea of Okhotsk we measured Hg(0) concentrations near the cyclone eye and did not register any increase due to increased turbulence. This fact contradicts the previously expressed hypothesis that a strong turbulence above the sea surface causes enhanced Hg(0) concentrations in the air. Apparently there are additional or completely different influencing factors which could provide such increase. Also we found that the diurnal Hg(0) cycle in the Sea of Japan was the opposite of the diurnal Hg(0) cycle in the Sea of Okhotsk.