Selective uranyl ion-imprinting with clickable amidoxime-functionalized pullulan.

Manufacturing a highly effective sorbent for removing UO22+ ions from aqueous effluents is vital for safeguarding the environment and recovering valuable resources. This research presents an innovative strategy employing adsorbents derived from pullulan, specifically tailored with furfuryl-amidoxime (FAO), to improve their affinity for UO22+ ions. The formation of a UO22+ ion-imprinted sorbent (U-II-P) was achieved by crosslinking the UO22+/FAO-modified pullulan (FAO-P) complex with bis(maleimido)ethane (BME) via click Diels-Alder (DA) cyclization, enhancing its attraction and specificity for UO22+ ions. Detailed characterization of the synthesis was performed using NMR and FTIR spectroscopy, and the sorbent's external textures were analyzed using scanning electron microscopy (SEM). The U-II-P sorbent showcased outstanding preference for UO22+ over other metallic ions, with the most efficient adsorption occurring at pH 5. It exhibited a significant adsorption capacity of 262 mg/g, closely aligning with the predictions of the Langmuir adsorption model and obeying pseudo-second-order kinetic behavior. This investigation underlines the effectiveness of FAO-P as a specialized solution for UO22+ ion extraction from wastewater, positioning it as a viable option for the remediation of heavy metals.

Effects of pollution on hydrogeochemistry and water quality of the Damietta branch (Nile River, Egypt).

Currently, different sources of contamination threaten water quality in Damietta, Egypt. The aim of this study was to assess the pollution, hydrogeochemistry and suitability for use in agriculture of water collected atseven stations along the Damietta branch of the Nile River. In addition to pH, temperature, dissolved oxygen (DO), and electrical conductivity (EC), levels of Mg2+, Ca2+, K+, Na+, Cl-, HCO3-, SO42- and CO32- were measured. From the highest to the lowest, the concentrations of cations were Na+ > Ca2+ > Mg2+ > K+, whereas those of anions were HCO3- > SO42- > Cl- in water samples collected at seven stations along the Damietta branch. Moreover, water quality indexes, such as sodium percentage (Na%) ranged between 21.6 and 71.4, Kelly's ratio from 0.37 to 3.85, sodium adsorption ratio (SAR) varied from 1.73 to 61.8, residual sodium carbonate (RSC) found to be in range of 0.2 to 3.8. Also, the potential salinity (PS) and permeability index (PI), magnesium hazard (MH), were calculated. Most samples (71%) belonged to the Mg-Ca-Na-HCO3 watertype. Fertilization wastes were identified as the main contributors of alkaline earth metals, whereas ion exchange was the main source of alkali metals. This work also provides information on distinguishing geochemical behaviors and the pollution of water samples.

Synthesis of Fluorescent 1-(3-Amino-4-(4-(tert-butyl)phenyl)-6-(p-tolyl)furo[2,3-b]pyridin-2-yl)ethan-1-one: Crystal Structure, Fluorescence Behavior, Antimicrobial and Antioxidant Studies.

Furopyridine III, namely 1-(3-amino-4-(4-(tert-butyl)phenyl)-6-(p-tolyl)furo[2,3-b]pyridin-2-yl)ethan-1-one, synthesized from 4-(4-(tert-butyl)phenyl)-2-oxo-6-(p-tolyl)-1,2-dihydropyridine-3-carbonitrile I in two steps. The title compound is characterized by NMR, MS and its X-ray structure. The molecular structure consists of planar furopyridine ring with both phenyl rings being inclined from the furopyridine scaffold to a significant different extent. There are three intramolecular hydrogen bonds within the structure. The lattice is stabilized by N-H…O, H2C-H …π and π…π intermolecular interactions leading to three-dimensional network. Compound III exhibits fluorescent properties, which are investigated. Antimicrobial potential and antioxidant activity screening studies for the title compound III and the heterocyclic derivatives, I and II, show no activity towards neither bacterial nor fungal strains, while they exhibited weak to moderate antioxidant activity compared to reference.