Hybrid carbon fiber/carbon nanotube composites for structural damping applications.

Carbon nanotubes (CNTs) were grown on the surface of carbon fibers utilizing a relatively low temperature synthesis technique; graphitic structures by design (GSD). To probe the effects of the synthesis protocols on the mechanical properties, other samples with surface grown CNTs were prepared using catalytic chemical vapor deposition (CCVD). The woven graphite fabrics were thermally shielded with a thin film of SiO2 and CNTs were grown on top of this film. Raman spectroscopy and electron microscopy revealed the grown species to be multi-walled carbon nanotubes (MWCNTs). The damping performance of the hybrid CNT-carbon fiber-reinforced epoxy composite was examined using dynamic mechanical analysis (DMA). Mechanical testing confirmed that the degradations in the strength and stiffness as a result of the GSD process are far less than those encountered through using the CCVD technique and yet are negligible compared to the reference samples. The DMA results indicated that, despite the minimal degradation in the storage modulus, the loss tangent (damping) for the hybrid composites utilizing GSD-grown MWCNTs improved by 56% compared to the reference samples (based on raw carbon fibers with no surface treatment or surface grown carbon nanotubes) over the frequency range 1-60 Hz. These results indicated that the energy dissipation in the GSD-grown MWCNTs composite can be primarily attributed to the frictional sliding at the nanotube/epoxy interface and to a lesser extent to the stiff thermal shielding SiO2 film on the fiber/matrix interface.

Synthesis of WS2 nanostructures from the reaction of WO3 with CS2 and mechanical characterization of WS2 nanotube composites.

Tungsten disulfide (WS(2)) nanometer sheets, spheres, fibers and tubes were generated by a synthetic pathway that avoids the use of H(2)S as the source of sulfur and employs instead CS(2) vapor, carried by an Ar or N(2)/H(2) stream in a heated tubular furnace, for the reaction with WO(3) precursor powders. The experiments were conducted at temperatures between 700 and 1000 °C, while the reaction times expanded between 30 min and 24 h. Characterization methods used to analyze the products of the synthesis include TEM, SEM, XRD and EDX. We found a strong correlation between precursor and product microstructure, although the temperature and reaction times play a critical role in the products' microstructural features as well. WS(2) inorganic fullerene (IF) nanospheres are generated in a wide window of conditions, while nanotubes and nanofibers are only produced at high temperatures or long reaction times. A proposed growth mechanism based on the CS(2) synthetic approach is presented. Nanoindentation and nano-impulse techniques were used to characterize the mechanical properties of polymer matrix-WS(2) nanotube composites, finding them superior to equivalent SWCNT composites. The improvements in toughness of nanocomposites based on WS(2) can be attributed to geometrical and morphological effects that assisted several toughening mechanisms such as crack pinning and the formation of an immobilized polymeric interphase around the nanotubes.