Methanol production and purification via membrane-based technology: Recent advancements, challenges and the way forward.

Industrial revolution on the back of fossil fuels has costed humanity higher temperatures on the planet due to ever-growing concentration of carbon dioxide emissions in Earth's atmosphere. To tackle global warming demand for renewable energy sources continues to increase. Along renewables, there has been a growing interest in converting carbon dioxide to methanol, which can be used as a fuel or a feedstock for producing chemicals. The current review study provides a comprehensive overview of the recent advancements, challenges and future prospects of methanol production and purification via membrane-based technology. Traditional downstream processes for methanol production such as distillation and absorption have several drawbacks, including high energy consumption and environmental concerns. In comparison to conventional technologies, membrane-based separation techniques have emerged as a promising alternative for producing and purifying methanol. The review highlights recent developments in membrane-based methanol production and purification technology, including using novel membrane materials such as ceramic, polymeric and mixed matrix membranes. Integrating photocatalytic processes with membrane separation has been investigated to improve the conversion of carbon dioxide to methanol. Despite the potential benefits of membrane-based systems, several challenges need to be addressed. Membrane fouling and scaling are significant issues that can reduce the efficiency and lifespan of the membranes. The cost-effectiveness of membrane-based systems compared to traditional methods is a critical consideration that must be evaluated. In conclusion, the review provides insights into the current state of membrane-based technology for methanol production and purification and identifies areas for future research. The development of high-performance membranes and the optimization of membrane-based processes are crucial for improving the efficiency and cost-effectiveness of this technology and for advancing the goal of sustainable energy production.

Improved mechanical strength, proton conductivity and power density in an 'all-protonic' ceramic fuel cell at intermediate temperature.

Protonic ceramic fuel cells (PCFCs) have become the most efficient, clean and cost-effective electrochemical energy conversion devices in recent years. While significant progress has been made in developing proton conducting electrolyte materials, mechanical strength and durability still need to be improved for efficient applications. We report that adding 5 mol% Zn to the Y-doped barium cerate-zirconate perovskite electrolyte material can significantly improve the sintering properties, mechanical strength, durability and performance. Using same proton conducting material in anodes, electrolytes and cathodes to make a strong structural backbone shows clear advantages in mechanical strength over other arrangements with different materials. Rietveld analysis of the X-ray and neutron diffraction data of BaCe0.7Zr0.1Y0.15Zn0.05O3-δ (BCZYZn05) revealed a pure orthorhombic structure belonging to the Pbnm space group. Structural and electrochemical analyses indicate highly dense and high proton conductivity at intermediate temperature (400-700 °C). The anode-supported single cell, NiO-BCZYZn05|BCZYZn05|BSCF-BCZYZn05, demonstrates a peak power density of 872 mW cm-2 at 700 °C which is one of the highest power density in an all-protonic solid oxide fuel cell. This observation represents an important step towards commercially viable SOFC technology.