1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 7): m984-5, 2012 Jul 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22807801
RESUMO
In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl-ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol-ecule are disordered over two sets of sites in a 0.8976â (18):0.1024â (18) ratio. The DMSO O atom accepts three C-Hâ¯O hydrogen bonds from an adjacent complex mol-ecule.