The performance of pharmaceutical wastewater treatment system of electrocoagulation assisted adsorption using perforated electrodes to reduce passivation.

The integrated electrocoagulation-assisted adsorption (ECA) system with a solar photovoltaic power supply has gained more attention as an effective approach for reduction chemical oxygen demand (COD) from pharmaceutical wastewater (PhWW). In this research, the ECA system was used for the treatment of PhWW. Several operating parameters were investigated, including electrode number, configuration, distance, operating time, current density, adsorption time, and temperature. A current density of 6.656 mA/cm2, six electrodes, a 20-min time, a 4 cm distance, an MP-P configuration, and a 45 °C temperature produced the maximum COD reductions, where the operating cost of conventional energy was 0.273 $/m3. The EC, adsorption, and combination of EC and adsorption processes achieved efficient COD reductions of 85.4, 69.1, and 95.5%, respectively. The pseudo-second-order kinetic model and the Freundlich isotherm fit the data of the endothermic adsorption process. Therefore, it was found that the combination processes were superior to the use of these processes in isolation to remove COD.

A critical review of state-of-the-art electrocoagulation technique applied to COD-rich industrial wastewaters.

Electrocoagulation (EC) is one of the emerging technologies in groundwater and wastewater treatment as it combines the benefits of coagulation, sedimentation, flotation, and electrochemical oxidation processes. Extensive research efforts implementing EC technology have been executed over the last decade to treat chemical oxygen demand (COD)-rich industrial wastewaters with the aim to protect freshwater streams (e.g., rivers, lakes) from pollution. A comprehensive review of the available recent literature utilizing EC to treat wastewater with high COD levels is presented. In addition, recommendations are provided for future studies to improve the EC technology and broaden its range of application. This review paper introduces some technologies which are often adopted for industrial wastewater treatment. Then, the EC process is compared with those techniques as a treatment for COD-rich wastewater. The EC process is considered as the most privileged technology by different research groups owing to its ability to deal with abundant volumes of wastewater. After, the application of EC as a single and combined treatment for COD-rich wastewaters is thoroughly reviewed. Finally, this review attempts to highlight the potentials and limitations of EC. Related to the EC process in batch operation mode, the best operational conditions are found at 10 V and 60 min of voltage and reaction time, respectively. These last values guarantee high COD removal efficiencies of > 90%. This review also concludes that considerably large operation costs of the EC process appears to be the serious drawback and renders it as an unfeasible approach for handling of COD rich wastewaters. In the end, this review has attempted to highlights the potential and limitation of EC and suggests that vast notably research in the field of continuous flow EC system is essential to introduce this technology as a convincing wastewater technology.

Combined electrocoagulation processes as a novel approach for enhanced pollutants removal: A state-of-the-art review.

A novel approach using the integration of electrocoagulation, with one or more treatment processes has been recently practiced to improve the removal of colloidal and non-biodegradable pollutants. Several treatment processes including adsorption, chemical coagulation, magnetic field, reverse osmosis, and membrane filtration have been combined with electrocoagulation treatment step to improve pollutants removal efficiency. These combined systems showed the potential to improve the performance of the treatment process. This paper presents a state-of-the-art review for the recent processes available in the literature that combine treatment electrocoagulation with one of the previously mentioned treatment processes. It is found that the removal efficiency of any combined processes is higher than that of any single treatment process and the combined process has up to 20% higher removal efficiency compared to electrocoagulation alone. However, most reported studies were conducted at bench-scale level with synthetic wastewater instead of real wastewater. The main aspects of these combined systems including process mechanism, kinetic models, cost and the scale up of combined processes were discussed and summarized. Finally, several concluding remarks were drawn in view of the literature investigations and the gaps that suggest more studies and insights for future development were addressed.

Production and Characterization of Controlled Release Urea Using Biopolymer and Geopolymer as Coating Materials.

Synthetic polymers-based controlled release urea (CRU) leaves non-biodegradable coating shells when applied in soil. Several alternative green materials are used to produce CRU, but most of these studies have issues pertaining to nitrogen release longevity, process viability, and the ease of application of the finished product. In this study, we utilized tapioca starch, modified by polyvinyl alcohol and citric acid, as coating material to produce controlled release coated urea granules in a rotary fluidized bed equipment. Response surface methodology is employed for studying the interactive effect of process parameters on urea release characteristics. Statistical analysis indicates that the fluidizing air temperature and spray rate are the most influential among all five process parameters studied. The optimum values of fluidizing air temperature (80 °C), spray rate (0.13 mL/s), atomizing pressure (3.98 bar), process time (110 min), and spray temperature (70 °C) were evaluated by multi-objective optimization while using genetic algorithms in MATLAB®. Urea coated by modified-starch was double coated by a geopolymer to enhance the controlled release characteristics that produced promising results with respect to the longevity of nitrogen release from the final product. This study provides leads for the design of a fluidized bed for the scaled-up production of CRU.

On the performance of electrocoagulation-assisted biological treatment processes: a review on the state of the art.

The combined treatment systems have become a potential alternative to treat highly polluted industrial wastewater to achieve high-quality treated effluents. The current review focuses on the treatment systems compromising electrocoagulation (EC) as a pretreatment step followed by a biological treatment step. The reasons for applying EC as a pretreatment process were mainly to (1) detoxify the wastewater by removing inhibitors of the biotreatment step or (2) to remove the major part of the COD or (3) the dissolved materials that could cause fouling to membrane bioreactors or (4) to increase the activity of the microorganisms. This combination represents a new and promising application characterized by higher performance and removal efficiency. The main published findings related to this application are presented and analyzed. Besides, the statistical models used to optimize the process variables and the kinetics of microorganism growth rate are discussed herein. Most of the previous investigations were conducted in a laboratory-scale level with biologically treated water as a feed to the EC process. Only a few works applied a hybrid system consisting of the biological step and the EC step. In all studies, improved performance and higher removal efficiencies of the combined process were achieved particularly when applying aluminum electrodes, providing more than 95% removal efficiency. Many researchers have reported that they had faced a significant problem in the operation of the electrocoagulation process associated with the reduction of electrodes' efficiency caused by deposits of the coagulation complex. This problem needs to be effectively resolved.

Production and characterization of thermostable alpha-amylase by thermophilic Geobacillus stearothermophilus.

Studies on the alpha-amylase-producing thermophilic bacterium isolated and identified from a hot spring in Jordan and designated as Geobacillus stearothermophilus JT2 were carried out. The optimum conditions for growth and enzyme production were pH 7 and 55 degrees C. The study of the kinetics of cellular growth indicated a mu(max) of 0.22/h, a K(s) of 1.2 g/L, a tau(d) of 3.15 h and a Y(x/s) of 0.43 g cell/g starch. In addition, the activation energy for growth and death were estimated and found to be 30.5 and 210 J/mol, respectively. The effect of different carbon and nitrogen sources on the cellular growth was tested.