Nanocomposite Marvels: Unveiling Breakthroughs in Photocatalytic Water Splitting for Enhanced Hydrogen Evolution.

An overview of the significant innovations in photocatalysts for H2 development, photocatalyst selection criteria, and photocatalytic modifications to improve the photocatalytic activity was examined in this Review, as well as mechanisms and thermodynamics. A variety of semiconductors have been examined in a structured fashion, such as TiO2-, g-C3N4-, graphene-, sulfide-, oxide-, nitride-, oxysulfide-, oxynitrides, and cocatalyst-based photocatalysts. The techniques for enhancing the compatibility of metals and nonmetals is discussed in order to boost photoactivity within visible light irradiation. In particular, further deliberation has been carried out on the development of heterojunctions, such as type I, type II, and type III, along with Z-systems, and S-scheme systems. It is important to thoroughly investigate these issues in the sense of visible light irradiations to enhance the efficacy of photocatalytic action. In fact, another advancement in this area may include hiring mediators including grapheme oxide and metals to establish indirect Z-scheme montages with a correct band adjustment. The potential consideration of reaction chemology, mass transfer, kinetics of reactions, restriction of light diffusion, and the process and selection of suitable light and photoreactor also will optimize sustainable hydrogen output efficiency and selectivity.

Exploring the antecedents of AI adoption for effective HRM practices in the Indian pharmaceutical sector.

Purpose: The aim of this research is to investigate the factors that facilitate the adoption of artificial intelligence (AI) in order to establish effective human resource management (HRM) practices within the Indian pharmaceutical sector. Design/methodology/approach: A model explaining the antecedents of AI adoption for building effective HRM practices in the Indian pharmaceutical sector is proposed in this study. The proposed model is based on task-technology fit theory. To test the model, a two-step procedure, known as partial least squares structural equational modeling (PLS-SEM), was used. To collect data, 160 HRM employees from pharmacy firms from pan India were approached. Only senior and specialized HRM positions were sought. Findings: An examination of the relevant literature reveals factors such as how prepared an organization is, how people perceive the benefits, and how technological readiness influences AI adoption. As a result, HR systems may become more efficient. The PLS-SEM data support all the mediation hypothesized by proving both full and partial mediation, demonstrating the accuracy of the proposed model. Originality: There has been little prior research on the topic; this study adds a great deal to our understanding of what motivates human resource departments to adopt AI in the pharmaceutical companies of India. Furthermore, AI-related recommendations are made available to HRM based on the results of a statistical analysis.

A graphene-based material for green sustainable energy technology for hydrogen storage.

The usage of graphene-based materials (GMs) as energy storage is incredibly popular. Significant obstacles now exist in the way of the generation, storage and consumption of sustainable energy. A primary focus in the work being done to advance environmentally friendly energy technology is the development of effective energy storage materials. Due to their distinct two-dimensional structure and intrinsic physical qualities like good electrical conductivity and wide area, graphene-based materials have a significant potential to be used in energy storage devices. Graphene and GMs have been employed extensively for this due to their special mechanical, thermal, catalytic and other functional qualities. In this review, we covered the topic of employing GMs to store hydrogen for green energy.

Mathematical modeling of active contraction of the human cardiac myocyte: A review.

Background and objective: In this present research paper, a mathematical model has been developed to study myocyte contraction in the human cardiac muscle, using the Land model. Different parts of the human heart with a focus on the composition of the myocyte cells have been explored numerically to enabling us to determine the interaction of various parameters in the heart muscle. The main objective of the work is to direct the study of the Land model, which has been exploited to simulate the contraction of real human myocytes. Methods: Mathematical models has been developed based on the Hill model and Huxley model. Myocyte contraction for different scenarios, such as in isometric tension and isotonic tension have been studied. Results: It is found that increase in stretch, the peak active tension increases, in line with well-established length-dependent tension generation. Five parameters are selected: [Ca2+]T50, Tref, TRPN50, ß0, and ß1, which have been varied in between the range of -50%-100%, to examine the isometric effects of each parameter on the behavior of the tension developed in the intact myocyte cells, with the most sensitive parameter being [Ca2+]T50. Conclusion: In conclusion, it is found that the Land model provides a good platform for the analysis of the active contraction of the human cardiac myocyte.

Impact of fermented organic formulations combined with inorganic fertilizers on broccoli (Brassica oleracea L. var. italica Plenck) cv. Palam Samridhi.

A two-year field experiment (2018-19 and 2019-20) was laid out in a randomized complete block design (RCBD) with a spacing of 60 × 45 cm involving three replications with ten treatments having cow manurial amendments along with integrated nutrient management in a plot size of 3.0 m × 1.8 m. The effect of the integration of cow manurial amendments and mineral fertilizers on soil fertility, nutrient uptake, yield, and economics of broccoli was studied. The experiment was laid out during the rabi season in the mid-hills of Himachal Pradesh. T8 [90% RDN (112.5 N: 67.5 P: 46.8 K kg/ha) + 5% jeevamrit (1.5 l/m2) + 5% jeevamrit foliar spray] obtained the greatest organic carbon (20.93 g kg-1), available N (375.13 kg ha-1), P (48.46 kg ha-1), K (260.53 kg ha-1) in the soil as well as more uptake of N (60.58 kg ha-1), P (7.25 kg ha-1) and K (37.88 g ha-1) by the plants. Further, this treatment obtained the greatest value for yield (186.77 q ha-1 and 12.44 kg plot-1), net income (₹ 245840) and cost-benefit ratio (1.93). Outcomes of this investigation suggested that combined usage of cow manure, jeevamrit, beejamrit, and ghanjeevamrit with inorganic fertilizers proved to be useful for enhancing soil health, increasing nutrient uptake, and ensuring sustainable production of broccoli.

A review of different twisted tape configurations used in heat exchanger and their impact on thermal performance of the system.

Heat transfer in water with the help of solar energy is an effective way to harness renewable energy and reduce reliance on non-renewable sources of energy. The utilization of turbulent promoters is an efficient solution to ameliorate the performance of heat exchangers (HE). The current work summarizes the experimental and numerical behaviour of HE reported in the literature, including the thermal examinations of HT and fluid flow characteristics with various turbulent promoters and tube arrangements. This article reviews multiple studies in which different twisted tape (TT) geometry enhances the HT rate in various HE tubes. The current work also compares the thermal performance (η) of TT configurations in HE tubes using correlations developed by different investigators. Maximum heat transfer and minimum friction factor concerning fluid utilized in the system may also produce the optimal form for twisted tapes.

UVC-Based Air Disinfection Systems for Rapid Inactivation of SARS-CoV-2 Present in the Air.

The World Health Organization (WHO) declared in May 2021 that SARS-CoV-2 is transmitted not only by close contact with infectious respiratory fluids from infected people or contaminated materials but also indirectly through air. Airborne transmission has serious implications for the control measures we can deploy, given the emergence of more transmissible variants. This emphasizes the need to deploy a mechanism to reduce the viral load in the air, especially in closed and crowded places such as hospitals, public transport buses, etc. In this study, we explored ultraviolet C (UVC) radiation for its ability to inactivate the SARS-CoV-2 particles present in aerosols and designed an air disinfection system to eliminate infectious viruses. We studied the virus inactivation kinetics to identify the UVC dosage required to achieve maximum virus inactivation. Based on the experimental data, UVC-based devices were designed for the sanitization of air through HVAC systems in closed spaces. Further, a risk assessment model to estimate the risk reduction was applied which showed that the use of UVC radiation could result in the reduction of the risk of infection in occupied spaces by up to 90%.

A Numerical Investigation on Hydrothermal Performance of Micro Channel Heat Sink with Periodic Spatial Modification on Sidewalls.

Electronic gadgets have been designed to incorporating very small components such as microcontrollers, electronic chips, transistors, microprocessors, etc. These components are exceptionally heat sensitive and can be wrecked if heat is not released. As a result, the thermal control of such components is critical to their optimum performance and extended life. The use of a microchannel heat sink (MCHS) has shown promising solutions to remove the excess heat. In this paper, we have proposed a novel design of MCHS and investigated it numerically. Four different surface modifications on the sidewall of the passage, namely, extended triangular surface (ETS), extended circular surface (ECS), triangular groove surface (TGS), and the circular groove surface (CGS) in the passage of the microchannel have been exploited in the Reynolds number of 100-900. In the presence of geometrical modification, the cooling capacities have been enhanced. The results show that the Nusselt numbers of ETS-MCHS, ECS-MCHS, TGS-MCHS, and CGS-MCHS are increased by 4.30, 3.61, 1.62, and 1.41 times in comparison to the Nusselt number of MCHS with smooth passage, while the friction factor values are increased by 7.33, 6.03, 2.74, and 1.68 times, respectively. In addition, the thermohydraulic performance parameter (THPP) has been evaluated and discussed. The fact that MCHS have THPP values greater than unity demonstrates that the passage's geometries are a practical means of achieving effective thermal management.

Analysis of Microchannel Heat Sink of Silicon Material with Right Triangular Groove on Sidewall of Passage.

Microchannel heat sink (MCHS) is a promising solution for removing the excess heat from an electronic component such as a microprocessor, electronic chip, etc. In order to increase the heat removal rate, the design of MCHS plays a vital role, and can avoid damaging heat-sensitive components. Therefore, the passage of the MCHS has been designed with a periodic right triangular groove in the flow passage. The motivation for this form of groove shape is taken from heat transfer enhancement techniques used in solar air heaters. In this paper, a numerical study of this new design of microchannel passage is presented. The microchannel design has five variable groove angles, ranging from 15° to 75°. Computational fluid dynamics (CFD) is used to simulate this unique microchannel. Based on the Navier-Stokes and energy equations, a 3D model of the microchannel heat sink was built, discretized, and laminar numerical solutions for heat transfer, pressure drop, and thermohydraulic performance were derived. It was found that Nusselt number and thermo-hydraulic performance are superior in the microchannel with a 15° groove angle. In addition, thermohydraulic performance parameters (THPP) were evaluated and discussed. THPP values were found to be more than unity for a designed microchannel that had all angles except 75°, which confirm that the proposed design of the microchannel is a viable solution for thermal management.

Performance of Microchannel Heat Sink Made of Silicon Material with the Two-Sided Wedge.

New designs of the microchannel with a two-sided wedge shape at the base were studied numerically. Five different wedge angles ranging from 3° to 15° were incorporated into the microchannel design. Simulation of this novel microchannel was carried out using Computational Fluid Dynamics (CFD). Three-dimensional models of the microchannel heat sink were created, discretized, and based on Navier-Stokes and energy equations; laminar numerical solutions were obtained for heat transfer and pressure drop. Flow characteristics of water as coolant in a microchannel were studied. It was observed that numerical results are in good agreement with experimental results. It was found that the Nusselt number and friction factor are significantly varied with the increase in Reynolds number. The Nusselt number varies in the following ranges of 5.963-8.521, 5.986-8.550, 6.009-8.568, 6.040-8.609, and 6.078-8.644 at 3°, 6°, 9°, 12°, and 15°, respectively. The microchannel with a wedge angle of 15° was found to be better in terms of Nusselt number and thermo-hydraulic performance. The enhancement in the Nusselt number is found as 1.017-1.036 for a wedge angle of 15°; however, friction factors do not show the perceptible values at distinct values of wedge angle. Moreover, the thermo-hydraulic performance parameters (THPP) were evaluated and found to be maximum in the range of 1.027-1.045 for a wedge angle of 15°. However, minimum THPP was found in the range of 1.005-1.0185 for a wedge angle of 3°.

The Effect of Roughness in Absorbing Materials on Solar Air Heater Performance.

Artificial roughness on the absorber of the solar air heater (SAH) is considered to be the best passive technology for performance improvement. The roughened SAHs perform better in comparison to conventional SAHs under the same operational conditions, with some penalty of higher pumping power requirements. Thermo-hydraulic performance, based on effective efficiency, is much more appropriate to design roughened SAH, as it considers both the requirement of pumping power and useful heat gain. The shape, size, and arrangement of artificial roughness are the most important factors for the performance optimization of SAHs. The parameters of artificial roughness and operating parameters, such as the Reynolds number (Re), temperature rise parameter (ΔT/I) and insolation (I) show a combined effect on the performance of SAH. In this case study, various performance parameters of SAH have been evaluated to show the effect of distinct artificial roughness, investigated previously. Therefore, thermal efficiency, thermal efficiency improvement factor (TEIF) and the effective efficiency of various roughened absorbers of SAH have been predicted. As a result, thermal and effective efficiencies strongly depend on the roughness parameter, Re and ΔT/I. Staggered, broken arc hybrid-rib roughness shows a higher value of TEIF, thermal and effective efficiencies consistently among all other distinct roughness geometries for the ascending values of ΔT/I. This roughness shows the maximum value of effective efficiency equals 74.63% at a ΔT/I = 0.01 K·m2/W. The unique combination of parameters p/e = 10, e/Dh = 0.043 and α = 60° are observed for best performance at a ΔT/I higher than 0.00789 K·m2/W.

Indoor air quality improvement in COVID-19 pandemic: Review.

INTRODUCTION: The advent of COVID-19 has impinged millions of people. The increased concern of the virus spread in confined spaces due to meteorological factors has sequentially fostered the need to improve indoor air quality. OBJECTIVE: This paper aims to review control measures and preventive sustainable solutions for the future that can deliberately help in bringing down the impact of declined air quality and prevent future biological attacks from affecting the occupant's health. METHODOLOGY: Anontology chart is constructed based on the set objectives and review of all the possible measures to improve the indoor air quality taking into account the affecting parameters has been done. OBSERVATIONS: An integrated approach considering non-pharmaceutical and engineering control measures together for a healthy indoor environment should be contemplated rather than discretizing the available solutions. Maintaining social distance by reducing occupant density and implementing a modified ventilation system with advance filters for decontamination of viral load can help in sustaining healthy indoor air quality. CONCLUSION: The review paper in the main, provides a brief overview of all the improvement techniques bearing in mind thermal comfort and safety of occupants and looks for a common ground for all the technologies based on literature survey and offers recommendation for a sustainable future.