Predictive modeling of pH on the transport of Co(II) Ions from aqueous solutions through supported ceramic polymer membrane.

Optimal pH is essential for efficient cobalt extraction from polymeric membrane systems, with D2EHPA used as an extractant for Co(II) at pH < 7, achieving 47% efficiency. The pH of piperazine as a stripping agent increases to a concentration of 0.48 M, and the extraction efficiency of Co(II) > 80%. Depending on the functional group of (C4H10N2), the optimal pH for separation was 9.8. The study revealed that pKa value was calculated to predict the ideal pH, and its value was 9.73, which is nearly to the pH, since the pH of the strip concentration and the properties of the membrane affect the extraction of cobalt at 30 °C. The partition ratio indicates the high distribution of the extract in supported ceramic polymer membrane (SCPM). The ceramic component provides mechanical strength and rigidity to the overall membrane structure, allowing it to withstand high pressures and temperatures during operation Study various factors such as the effect of pH on the ionization of the extract; effect of pH on band ionization; effect of pH on the temperature in the extract, effect of pH on the solute, effect of the band at different pH ranges and a comparison was made between the predictive model and experimental data that was proven through mathematical modeling using the MATLAB program.

Ni-alginate hydrogel beads for establishing breakthrough curves of lead ions removal from aqueous solutions.

The scientific impact of this work is the protection of the environment from hazardous pollutants using a column technique. Besides its higher stability at working pH and its time persisting, Ni-alginate has a higher ability to remove lead ions compared to the other prepared beads (Sr-alginate, Co-alginate, and Ca-alginate). Also, Ni-alginate possessed a higher removal percent, 93.3%, toward Pb2+ than the other ions, taking the sorption order of Pb2+ > Sr2+ > Co2+ > Cd2+ > Zn2+. Therefore, this study focused on using Ni-alginate as a selective sorbent for lead ions. Fixed-bed column was employed for the sorption process. The results for that efficiency are presented as breakthrough curves in view of the impact of various parameters; influent flow rate (1.5, 3.0, and 5.0 mL/min), lead concentration (100, 150, and 200 mg/L), and bed depth of sorbent (3.0, 5.0, and 7.0 cm). Breakthrough modeling including Thomas and Yan models was employed. The outcomes indicated that Thomas theory is more applicable. The overall outcomes indicated that Ni-alginate is recommended for selective removal of Pb2+ from waste solutions.

Removal of strontium radionuclides from liquid scintillation waste and environmental water samples.

Strontium-90 (t1/2 = 29 y) is one of the most concerned isotopes in both nuclear accidents and reprocessing of nuclear fuel. In this study, the removal of strontium using low cost and valuable Dowex-HCR-S/S (DHS) resin was achieved. The kinetic and equilibrium sorption studies have been investigated using batch technique. The results of kinetic studies showed that the pseudo-second-order kinetic model was found to correlate well with the experimental data. Equilibrium data were also analyzed by sorption isotherm models indicating that the monolayer capacity of Sr(II) at equilibrium is 400.0 mg/g. It was concluded that resin has an efficient sorption capacity compared to many sorbents. The thermodynamic parameters of the removal (ΔHo, ΔSo, and ΔGo) were also determined. The removal process was endothermic and spontaneous. The resin has been successfully applied for the removal of 85Sr from organic liquid scintillator waste and some environmental waters such as tap water, river water, sea water and ground water samples. The present work concludes that the low-cost and commercial DHS resin used under these conditions has a major possibility as an efficacious material for the removal of 90Sr from environmental and real radioactive wastewaters. It can therefore have a site in the treatment of radioactive liquid waste because it is of an affordable and commercially available retention material.

Preparation of activated carbon from doum stone and its application on adsorption of 60Co and 152+154Eu: Equilibrium, kinetic and thermodynamic studies.

Removal of radionuclides from wastewater before discharging to environment is necessary for the safety of living beings. Activated carbon prepared from doum stone (DS), an agricultural waste by-product, has been used for the sorption of 60Co and 152+154Eu radionuclides from aqueous solutions. DS has been characterized by different analytical tools. The efficiency of the adsorbent was investigated using batch sorption technique under different experimental conditions. The equilibrium sorption data were analyzed using Freundlich and Langmuir isotherm models. The kinetic experimental data were analyzed using four kinetic models including pseudo-first order, pseudo-second order, Elovich and intraparticle diffusion model to examine the mechanism of sorption and potential rate-controlling step. The maximum capacity of DS was found to be 121 mg/g and 166 mg/g for cobalt and europium, respectively. Sorption efficiency of DS to remove 60Co, 152+154Eu and 134Cs from real radioactive wastewater and environmental (river water and sea water) samples was also investigated. The results revealed that the prepared DS as low cost could be used as a promising material for the simultaneous removal of different radionuclides such as 60Co, 152+154Eu and 134Cs, or trivalent actinides such as 241, 242m,243Am from real radioactive waste and environmental water samples.