Preparation of chitosan-based ternary nanocomposite hydrogel film by loading graphene oxide nanosheets as adsorbent for enhanced methylene blue dye removal.

Our objective in this study is to fabricate a novel chitosan-based ternary nanocomposite hydrogel film by incorporating graphene oxide (GO) nanosheets into a chitosan/partially hydrolyzed polyacrylamide (PHPA) network to boost adsorption efficiency through one step self-assembly process in water. Basically, H-bonding interactions drive the formation of a crosslinking network structure. The Batch adsorption experiments evaluated the hydrogel nanocomposite's MB adsorption performance. By loading GO, surface roughness, swelling percentage (from 21,200 % to 35,800 %), elastic modulus of up to 73.7 Pa, and adsorption characteristics (from 282 mg/g to 468 mg/g) were enhanced. The nanocomposite displayed outstanding thermally/pH responsiveness properties. MB adsorption equilibrium was reached after 45 min and the adsorption capacity was 476.19 mg.g-1 when the initial concentration was 100 mg/L. The MB adsorption kinetics and isotherms by the nanocomposite were well correlated by the PSO and the Langmuir models (R2 > 0.99), respectively. The loaded nanocomposite was shown to be regenerative for five cycles through desorption studies. Thermodynamic analysis indicated that MB adsorption occurred spontaneously (ΔG°: -16.47 kJ/mol, 303 K) and exothermically (ΔH°: -79.49 kJ/mol). A plausible adsorption mechanism was proposed for the nanocomposite developed for MB removal. Our results can contribute to the design and fabrication of nanocomposite adsorbents to treat wastewater.

An all-biopolymer self-assembling hydrogel film consisting of chitosan and carboxymethyl guar gum: A novel bio-based composite adsorbent for Cu2+ adsorption from aqueous solution.

A novel bio-based composite adsorbent, all biopolymer self-assembled hydrogel film has been prepared by eco-friendly amalgamating chitosan (CS) and carboxymethyl guar gum (CMGG) biopolymers in water without needing small molecules for cross-linking. Various analysis demonstrated the electrostatic interactions and hydrogen bondings within the network structure are responsible for gelling, crosslinking, and forming a 3D structure. Various experimental parameters were optimized to evaluate the CS/CMGG's potential for removing Cu2+ ions from aqueous solution, including pH, dosage, Cu(II) initial concentration, contact time, and temperature. The pseudo-second-order kinetic and Langmuir isotherm models are highly correlated with the kinetic and equilibrium isotherm data, respectively. Using the Langmuir isotherm model for an initial metal concentration of 50 mg/L at pH 6.0 and 25 °C, the maximum adsorption of Cu(II) was calculated to be 155.51 mg/g. A combination of adsorption-complexation and ion exchange must be involved in Cu(II) adsorption on the CS/CMGG. Five cycles of the loaded CS/CMGG hydrogel regeneration and reuse were successfully achieved without an appreciable difference in Cu(II) removal percentage. Thermodynamic analysis indicated that copper adsorption occurred spontaneously (ΔG°: -2.85 J/mol, 298 K) and exothermically (ΔH°: -27.58 J/mol). A reusable bio-adsorbent for removing heavy metal ions was developed that is eco-friendly, sustainable, and efficient.