Ferroelectric glycine silver nitrate: a single-crystal neutron diffraction study.

Protonated crystals of glycine silver nitrate (C4H10Ag2N4O10) undergo a displacive kind of structural phase transition to a ferroelectric phase at 218 K. Glycine silver nitrate (GSN) is a light-sensitive crystal. Single-crystal X-ray diffraction investigations are difficult to perform on these crystals due to the problem of crystal deterioration on prolonged exposure to X-rays. To circumvent this problem, single-crystal neutron diffraction investigations were performed. We report here the crystal structure of GSN in a ferroelectric phase. The final R value for the refined structure at 150 K is 0.059. A comparison of the low-temperature structure with the room-temperature structure throws some light on the mechanism of the structural phase change in this crystal. We have attempted to explain the structural transition in GSN within the framework of the vibronic theory of ferroelectricity, suggesting that the second-order Jahn-Teller (pseudo-Jahn-Teller) behavior of the Ag(+) ion in GSN leads to structural distortion at low temperature (218 K).

Magnetic structure of CuCrO2: a single crystal neutron diffraction study.

This paper presents results of a recent study of multiferroic CuCrO(2) by means of single crystal neutron diffraction. This system has two close magnetic phase transitions at T(N) = 24.2 K and T(mf) = 23.6 K. The low temperature magnetic structure below T(mf) is unambiguously determined to be a fully three-dimensional proper screw. Between T(N) and T(mf) antiferromagnetic order is found that is essentially two-dimensional. In this narrow temperature range, magnetic near neighbor correlations are still long range in the (H,K) plane, whereas nearest neighbors along the L direction are uncorrelated. Thus, the multiferroic state is realized only in the low temperature three-dimensional state and not in the two-dimensional state.

Novel features of the α-ß phase transition in quartz-type FePO4 as evidenced by x-ray diffraction and lattice dynamics.

We present novel results on the mechanism of the α-ß structural phase transition (STP) occurring in FePO4. High accuracy x-ray diffraction experiments followed by a structural analysis provide us with precise information on the thermal disorder change on different atomic sites. The data are analysed in the light of lattice dynamics simulation results. The rigid unit mode (RUM) approach of the dynamics simulation allows an understanding of the anisotropic displacement parameters (ADPs). Surprisingly, the role of critical fluctuations of the order parameter, in the sense of Landau and Lifshitz theory, appears not to be relevant in the case of this SPT and the understanding of the dynamics requires a knowledge and analysis of the microscopic details of the system.

Signature of checkerboard fluctuations in the phonon spectra of a possible polaronic metal La1.2Sr1.8Mn2O7.

Charge carriers in low-doped semiconductors may distort the atomic lattice around them and through this interaction form so-called small polarons. High carrier concentrations on the other hand can lead to short-range ordered polarons (large polarons) and even to a long-range charge and orbital order. These ordered systems should be insulating with a large electrical resistivity. However, recently a polaronic pseudogap was found in a metallic phase of La(2-2x)Sr(1+2x)Mn(2)O(7) (ref. 7). This layered manganite is famous for colossal magnetoresistance associated with a phase transition from this low-temperature metallic phase to a high-temperature insulating phase. Broad charge-order peaks due to large polarons in the insulating phase disappear when La(2-2x)Sr(1+2x)Mn(2)O(7) becomes metallic. Investigating how polaronic features survive in the metallic phase, here we report the results of inelastic neutron scattering measurements showing that inside the metallic phase polarons remain as fluctuations that strongly broaden and soften certain phonons near the wavevectors where the charge-order peaks appeared in the insulating phase. Our findings imply that polaronic signatures in metals may generally come from a competing insulating charge-ordered phase. Our findings are highly relevant to cuprate superconductors with both a pseudogap and a similar phonon effect associated with a competing stripe order.

Flop of electric polarization driven by the flop of the Mn spin cycloid in multiferroic TbMnO3.

Using in-field single-crystal neutron diffraction, we have determined the magnetic structure of TbMnO(3) in the high field P parallel a phase. We unambiguously establish that the ferroelectric polarization arises from a cycloidal Mn spin ordering, with spins rotating in the ab plane. Our results demonstrate directly that the flop of the ferroelectric polarization in TbMnO(3) with applied magnetic field is caused from the flop of the Mn cycloidal plane.

Coupling of frustrated ising spins to the magnetic cycloid in multiferroic TbMnO(3).

We report on diffraction measurements on multiferroic TbMnO(3) which demonstrate that the Tb- and Mn-magnetic orders are coupled below the ferroelectric transition T(FE) = 28 K. For T

Magnetic excitations in multiferroic TbMnO3: evidence for a hybridized soft mode.

The magnetic excitations in multiferroic TbMnO3 have been studied by inelastic neutron scattering in the spiral and sinusoidally ordered phases. At the incommensurate magnetic zone center of the spiral phase, we find three low-lying magnons whose character has been fully determined using neutron-polarization analysis. The excitation at the lowest energy is the sliding mode of the spiral, and two modes at 1.1 and 2.5 meV correspond to rotations of the spiral rotation plane. These latter modes are expected to couple to the electric polarization. The 2.5 meV mode is in perfect agreement with recent infrared-spectroscopy data giving strong support to its interpretation as a hybridized phonon-magnon excitation.

Enhanced ferroelectric polarization by induced Dy spin order in multiferroic DyMnO3.

Neutron powder diffraction and single crystal x-ray resonant magnetic scattering measurements suggest that Dy plays an active role in enhancing the ferroelectric polarization in multiferroic DyMnO3 above T(Dy)(N)=6.5 K. We observe the evolution of an incommensurate ordering of Dy moments with the same periodicity as the Mn spiral ordering. It closely tracks the evolution of the ferroelectric polarization. Below T(Dy)(N), where Dy spins order commensurately, the polarization decreases to values similar for those of TbMnO3. The higher P(s) found just above T(Dy)(N) arises from the contribution of Dy spins so as to effectively increase the amplitude of the Mn spin spiral.

Quasiparticlelike peaks, kinks, and electron-phonon coupling at the (pi,0) regions in the CMR oxide La2-2x Sr1+2x Mn2 O7.

Using angle-resolved photoemission, we have observed sharp quasiparticlelike peaks in the prototypical layered manganite La(2-2x)Sr(1+2x)Mn(2)O(7) (x=0.36,0.38). We focus on the (pi,0) regions of k space and study their electronic scattering rates and dispersion kinks, uncovering bilayer-split bands, the critical energy scales, momentum scales, and strengths of the interactions that renormalize the electrons. To identify these bosons, we measured phonon dispersions in the energy range of the kink by inelastic neutron scattering, finding a good match in both energy and momentum to the oxygen bond-stretching phonons.

Revised superconducting phase diagram of hole-doped Na(x)(H3O)(z)CoO2 x yH(2)O.

We have studied the superconducting phase diagram of NaxCoO2.yH(2)O as a function of electronic doping, characterizing our samples both in terms of Na content x and the Co valence state. Our findings are consistent with a recent report that intercalation of H3O+ ions into NaxCoO2, together with water, acts as an additional dopant, indicating that Na substoichiometry alone does not control the electronic doping of these materials. We find a superconducting phase diagram where optimal T(C) is achieved through a Co valence range of 3.24-3.35, while T(C) decreases for materials with a higher Co valence. The critical role of dimensionality in achieving superconductivity is highlighted by similarly doped nonsuperconducting anhydrous samples, differing from the superconducting hydrate only in interlayer spacing.