Efficacious adsorption of divalent nickel ions over sodium alginate-g-poly(acrylamide)/hydrolyzed Luffa cylindrica-CoFe2O4 bionanocomposite hydrogel.

Existing Ni2+ heavy metal ions in an aqueous medium are highly hazardous for living organisms and humans. Therefore, designing low-cost adsorbents with enhanced effectiveness is essential for removing nickel ions to safeguard public health. In this study, a novel green nanocomposite hydrogel was synthesized through the free radical solution and bulk polymerization method, and its capability to remove divalent nickel ions from aqueous media was examined. The bionanocomposite hydrogel named as SA-g-poly(AAm)/HL-CoFe2O4 was produced by grafting polyacrylamide (AAm) onto sodium alginate (SA) in the presence of a magnetic composite recognized as HL-CoFe2O4, where HL represents hydrolyzed Luffa Cylindrica. By employing FT-IR, XRD, VSM, SEM, EDX-Map, BET, DLS, HPLC, and TGA techniques, morphological evaluation and characterization of the adsorbents were carried out. The performance of the adsorption process was studied under varying operational conditions including pH, temperature, contact duration, initial concentration of pollutant ions, and adsorbent dosage. HPLC analysis proved the non-toxic structure of the bionanocomposite hydrogel. The number of unreacted acrylamide monomers within the hydrogel matrix was measured at 20.82 mg/kg. The optimum conditions was discovered to be pH = 6, room temperature, adsorbent dosage of 1 of g.L-1, initial Ni2+ concentration of 10 mg.L-1, and contact time of 100 min, and the maximum adsorption efficiency at optimal state was calculated as 70.09, 90.25, and 93.83 % for SA-g-poly (AAm), SA-g-poly(AAm)/HL, and SA-g-poly(AAm)/HL-CoFe2O4 samples, respectively. Langmuir isotherm model was in good agreement with the experimental data and the maximum adsorption capacity of SA-g-poly(AAm), SA-g-poly(AAm)/HL, and SA-g-poly(AAm)/HL-CoFe2O4 samples was calculated to be 31.37, 43.15, and 45.19 mg.g-1, respectively. The adsorption process, according to kinetic studies, follows a pseudo-second-order kinetic model. Investigations on thermodynamics also demonstrated that the process is exothermic and spontaneous. Exploring the interference effect of co-existing ions showed that the adsorption efficiency has decreased with concentration enhancement of Ca2+ and Na+ cations in aqueous medium. Furthermore, the adsorption/desorption assessments revealed that after 8 consecutive cycles, there had been no noticeable decline in the adsorption effectiveness. Finally, actual wastewater treatment outcomes demonstrated that the bionanocomposite hydrogel successfully removes heavy metal pollutants from shipbuilding industry effluent. Therefore, the findings revealed that the newly fabricated bionanocomposite hydrogel is an efficient, cost-effective, easy-separable, and green adsorbent that could be potentially utilized to remove divalent nickel ions from wastewater.

Surface magnetization of hydrolyzed Luffa Cylindrica biowaste with cobalt ferrite nanoparticles for facile Ni2+ removal from wastewater.

A novel magnetic adsorbent based on hydrolyzed Luffa Cylindrica (HLC) was synthesized through the chemical co-precipitation technique, and its potential was evaluated in the adsorptive elimination of divalent nickel ions from water medium. Morphological assessment and properties of the adsorbent were performed using FTIR, SEM, EDX, XRD, BET, and TEM techniques. The effect of pH, temperature, time and nickel concentration on the removal efficiency was studied, and pH = 6, room temperature (25 °C), contact time of 60 min, and Ni2+ ion concentration of 10 mg.L-1 were introduced as the optimal values. At optimal conditions, the removal efficiency of Ni2+ ions using HLC and HLC/CoFe2O4 magnetic composite was calculated as 96.38 and 99.13%, respectively. The adsorption process kinetic followed a pseudo-first-order model. Langmuir isotherm was suitable for modelling the experimental data of the Ni2+ adsorption. The maximum elimination capacity of HLC and HLC/CoFe2O4 samples was calculated as 42.75 and 44.42 mg g-1, respectively. Furthermore, thermodynamic investigations proved the spontaneous and exothermic nature of the process. The adsorption efficiency was decreased with increasing the content of Ca2+ and Na + cations in aqueous media. During reusability of the synthesized adsorbents, it was found that after 8 cycles, no significant decrease has occurred in the adsorption efficiency. In addition, real wastewater treatment results proved that HLC/CoFe2O4 magnetic composite has an excellent performance in removal of heavy metals pollutant from shipbuilding effluent.