Understanding Protein and Polysaccharide Fouling with Silicon Dioxide and Aluminum Oxide in Low-Pressure Membranes.

Humic, protein, and polysaccharide substances have been recognized as significant types of foulants in membrane systems. Despite the remarkable amount of research that has been performed on the interaction of these foulants, particularly humic and polysaccharide substances, with inorganic colloids in RO systems, little attention has been paid to the fouling and cleaning behavior of proteins with inorganic colloids in UF membranes. This research examined the fouling and cleaning behavior of bovine serum albumin (BSA) and sodium alginate (SA) with silicon dioxide (SiO2) and α-aluminum oxide (Al2O3) in individual and combined solutions during dead-end UF filtration. The results showed that the presence of SiO2 or Al2O3 in water alone did not cause significant fouling or a flux decline in the UF system. However, the combination of BSA and SA with inorganics was observed to have a synergistic effect on membrane fouling, in which the combined foulants caused higher irreversibility than individual foulants. Analysis of blocking laws demonstrated that the fouling mechanism shifted from cake filtration to complete pore blocking when the combined organics and inorganics were present in water, which resulted in higher BSA and SA fouling irreversibility. The results suggest that membrane backwash needs to be carefully designed and adjusted for better control of BSA and SA fouling with SiO2 and Al2O3.

Box dimension of the border of Kingdom of Saudi Arabia.

Fractal dimension unlike topological dimension is (usually) a non-integer number which measures complexity, roughness, or irregularity of an object with respect to the space in which the set lies. It is used to characterize highly irregular objects in nature containing statistical self-similarity such as mountains, snowflakes, clouds, coastlines, borders etc. In this article, box dimension (a version of fractal dimension) of the border of Kingdom of Saudi Arabia (KSA) is computed using a multicore parallel processing algorithm based on the classical box-counting method. A power law relation is obtained from numerical simulations which relates the length of the border with the scale size and provides a very close estimate of the actual length of the KSA border within the scaling regions and scaling effects on the length of KSA border are considered. The algorithm presented in the article is shown to be highly scalable and efficient and the speedup of the algorithm is computed using Amdahl's and Gustafson's laws. For simulations, a high performance parallel computer is employed using Python codes and QGIS software.

Life Cycle Assessment of Construction and Demolition Waste Management in Riyadh, Saudi Arabia.

Extensive construction augmenting the infrastructure and real estate projects underpin Saudi Arabia's Vision 2030 of sustainable cities. A part of this struggle involves the transformation of the existing infrastructure together with new construction, which generates a large amount of construction and demolition waste (CDW). In the absence of a structured life cycle assessment (LCA) framework, the waste management companies are planning future scenarios (phased expansions of material recovery facilities to improve the recycling rate) primarily on economic grounds. This study assesses the environmental impacts of the existing and planned CDW management practices of the Saudi Investment Recycling Company in Riyadh City by dint of LCA. Impact 2002+ performs life cycle impact assessment of the base case (45% recycling), four treatments (61, 76, 88, and 100% recycling), and zero waste scenarios. The study demonstrates the benefits of current CDW (mixed soil, concrete blocks, clay bricks, glazed tiles, and asphalt) recycling in terms of avoided impacts of non-renewable energy, global warming, carcinogens, non-carcinogens, and respiratory inorganics potentially generated by landfilling. For the treatment scenario of 100% recycling, CDW conversion into a wide range of aggregates (0-50 mm) can replace 10-100% virgin aggregates in backfilling, precast concrete manufacturing, encasements and beddings of water mains and sewers, manholes construction, non-load bearing walls, and farm-to-market roads. To achieve long-term economic and environmental sustainability, municipalities need to improve source segregation, handling, and storage practices to enhance the existing (45%) recycling rate to 100% in the next five years and approach the zero-waste scenario by 2030. The findings of the present study motivate the generators for source reduction as well as encourage the recycling companies and concerned organizations in the continuous performance improvement of the CDW management systems across Saudi Arabia on environmental grounds, as an addition to the perceived economic benefits.

Chemical cleaning of ceramic ultrafiltration membranes - Ozone versus conventional cleaning chemicals.

This study investigates chemical cleaning mechanisms of a tubular ceramic UF membrane. The effect of cleaner type (ozone (O3), sodium hypochlorite (NaOCl) and sodium hydroxide (NaOH)), clean in place (CIP) pH (11 vs. 12), and cleaning sequence on the removal of irreversible fouling of hydrophobic (humic acids) and hydrophilic (alginate with and without calcium (alginate + Ca+2 and alginate - Ca+2, respectively)) NOM fractions were investigated. Results showed that different NOM types responded differently to chemical cleaning. Alginate-Ca+2 and humic acids were equivalently removed by NaOCl or NaOH whereas a lower cleaning efficiency of alginate + Ca+2 was observed. Increasing the pH of NaOCl and NaOH CIP increased the removal of the chemically reversible fouling index (UMFIcr). The efficiency of NaOCl was always lower than that of NaOH at the same pH, which was attributed to surface tension (λ) differences in the CIP water and potential differences in cleaning mechanism. The ceramic UF CIP cleaning using O3 (0.50 mg O3/mgC) for 1 h demonstrated higher cleaning efficiency for humic acids and alginate ±â€¯Ca+2, (%UMFIcr > 98%), than NaOCl or NaOH alone (%UMFIcr>80%). The O3 CIP was as effective as 4 h cleaning using a sequential NaOH/NaOCl or combined NaOCl + NaOH CIP.