One-pot synthesis of novel chitosan-salicylaldehyde polymer composites for ammonia sensing.

Chitosan (Chs)-salicylaldehyde (Sal) polymer derivatives were formed via the reaction of Chs-Sal with zinc oxide nanoparticles (ZnO NPs) and beta-cyclodextrin (ß-CD). These polymers were synthesized through inclusion with ß-CD and doping with ZnO NPs to give pseudopolyrotaxane and Chs-Sal/ZnO NPs composite, respectively, for low-temperature detection and sensing of NH3 vapors as great significance in environmental control and human health. Additionally, the polymer (Chs-Sal/ß-CD/ZnO NPs) was prepared via the insertion of generated composite (Chs-Sal/ZnO NPs) through ß-cyclodextrin ring. The structural and morphological characterizations of the synthesized derivatives were confirmed by utilizing FTIR, XRD and, SEM, respectively. Also, the optical properties and thermal gravimetric analysis (TGA) of the synthesized polymers were explored. The obtained results confirmed that using ß-CD or ZnO NPs for modification of polymer (Chs-Sal) dramatically enhanced thermal stability and optical features of the synthesized polymers. Investigations on the NH3-sensing properties of Chs-Sal/ß-CD/ZnO NPs composite were carried out at concentrations down to 10 ppm and good response and recovery times (650 s and 350 s, respectively) at room temperature (RT) and indicated that modification by ß-CD and doping with ZnO NPs effectively improves the NH3-sensing response of Chs-Sal from 712 to 6192 using Chs-Sal/ß-CD/ZnO NPs, respectively, with low LOD and LOQ of 0.12 and 0.4 ppb, respectively.

Performance evaluation of a UOWC system based on the FRS/OCDMA code for different types of Jerlov waters.

In this work, the fixed right shift (FRS) code is utilized for the optical code division multiple access (OCDMA) technique in an underwater optical wireless communication (UOWC) system. Additionally, in this system, a 532 nm laser diode (LD) source is employed to generate optical signals. The investigation encompasses an analysis of five distinct Jerlov water types, each exhibiting diverse chlorophyll concentrations. The performance of the proposed system is evaluated when each channel that is assigned a unique FRS code sequence carries different data rates (2.5, 5, and 10 Gbps). Underwater (UW) ranges, bit error rate (BER), eye diagrams, and quality factor (Q-factor) are the performance metrics used to evaluate the system performance. The proposed UOWC-FRS/OCDMA system is simulated, and the obtained results show that the eye diagram openings close, the BER increases, and the Q-factor decreases as the data rate per each channel increases from 2.5 to 10 Gbps, and the attenuation of water becomes higher. Moreover, the lower attenuation values caused by the Jerlov type I (JI) waterbody allow each channel to carry 10 Gbps of data to propagate longer UW for a range of 35 m with a log(BER) ≤-6.33 and Q-factor greater than 4.9. On the other hand, at the same values of BER and Q-factor, the shortest ranges of 12 and 5.15 m are obtained for JII and JIII waters, respectively, where their attenuation coefficient values are 0.5297 (JII) and 1.8998 m -1 (JIII). Furthermore, as our model uses three channels, the overall achieved capacity is 3×10G b p s=30G b p s.

An efficient watermarking algorithm for digital audio data in security applications.

Transform-domain audio watermarking systems are more robust than time-domain systems. However, the main weakness of these systems is their high computational cost, especially for long-duration audio signals. Therefore, they are not desirable for real-time security applications where speed is a critical factor. In this paper, we propose a fast watermarking system for audio signals operating in the hybrid transform domain formed by the fractional Charlier transform (FrCT) and the dual-tree complex wavelet transform (DTCWT). The central idea of the proposed algorithm is to parallelize the intensive and repetitive steps in the audio watermarking system and then implement them simultaneously on the available physical cores on an embedded systems cluster. In order to have a low power consumption and a low-cost cluster with a large number of physical cores, four Raspberry Pis 4B are used where the communication between them is ensured using the Message Passing Interface (MPI). The adopted Raspberry Pi cluster is also characterized by its portability and mobility, which are required in watermarking-based smart city applications. In addition to its resistance to any possible manipulation (intentional or unintentional), high payload capacity, and high imperceptibility, the proposed parallel system presents a temporal improvement of about 70%, 80%, and 90% using 4, 8, and 16 physical cores of the adopted cluster, respectively.

Impact of Fireworks Industry Safety Measures and Prevention Management System on Human Error Mitigation Using a Machine Learning Approach.

In the fireworks industry (FI), many accidents and explosions frequently happen due to human error (HE). Human factors (HFs) always play a dynamic role in the incidence of accidents in workplace environments. Preventing HE is a main challenge for safety and precautions in the FI. Clarifying the relationship between HFs can help in identifying the correlation between unsafe behaviors and influential factors in hazardous chemical warehouse accidents. This paper aims to investigate the impact of HFs that contribute to HE, which has caused FI disasters, explosions, and incidents in the past. This paper investigates why and how HEs contribute to the most severe accidents that occur while storing and using hazardous chemicals. The impact of fireworks and match industry disasters has motivated the planning of mitigation in this proposal. This analysis used machine learning (ML) and recommends an expert system (ES). There were many significant correlations between individual behaviors and the chance of HE to occur. This paper proposes an ML-based prediction model for fireworks and match work industries in Sivakasi, Tamil Nadu. For this study analysis, the questionnaire responses are reviewed for accuracy and coded from 500 participants from the fireworks and match industries in Tamil Nadu who were chosen to fill out a questionnaire. The Chief Inspectorate of Factories in Chennai and the Training Centre for Industrial Safety and Health in Sivakasi, Tamil Nadu, India, significantly contributed to the collection of accident datasets for the FI in Tamil Nadu, India. The data are analyzed and presented in the following categories based on this study's objectives: the effect of physical, psychological, and organizational factors. The output implemented by comparing ML models, support vector machine (SVM), random forest (RF), and Naïve Bayes (NB) accuracy is 86.45%, 91.6%, and 92.1%, respectively. Extreme Gradient Boosting (XGBoost) has the optimal classification accuracy of 94.41% of ML models. This research aims to create a new ES to mitigate HE risks in the fireworks and match work industries. The proposed ES reduces HE risk and improves workplace safety in unsafe, uncertain workplaces. Proper safety management systems (SMS) can prevent deaths and injuries such as fires and explosions.

1,3-Dipolar Cycloaddition of 3-Chromonyl-Substituted Glycine Imino Esters with Arylidenes and in†situ Diastereodivergent via Retrocycloaddition.

1,3-Dipolar cycloaddition through in situ generation of azomethine ylide provides a straightforward and critically important sustainable approach for access to diverse pyrrolidine chemical space. Herein, we developed a metal-free AcOH-activated 1,3-dipolar cycloaddition protocol that permits the synthesis of uncommon pyrrolidine cycloadducts with excellent diastereoselectivity. The challenging substrates of 3-formylchromone, glycine ester.HCl and arylidene dipolarophile were reacted in the presence of AcONa, which played a dual role as a base and AcOH source, to deliver firstly endo-cycloadduct. Under prolonged reaction time at room temperature or heating; the endo-adduct underwent diastereodivergent via a sequence of retro-cycloaddition, stereomutation of the generated syn-dipole into anti-dipole and recycloaddition; to furnish the scarcely known exo'-cycloadduct with high diastereodivergency. The reaction worked well with a broad range of substrates and the stereochemistry of the obtained cycloadducts was determined without ambiguity using NMR- and X-ray analysis. Experimental and theoretical DFT calculation studies were performed to support the proposed reaction mechanism and elucidate the key role of AcOH in the process which seems more beneficial than other transition metal-catalyzed processes.

High-flow nasal oxygen as an adjunct for the safe removal of impacted metallic upper airway foreign bodies.

Foreign body airway obstruction is considered an airway emergency and is a challenging clinical scenario for both the otolaryngologist and the anaesthetist. We present three cases of impacted upper airway metallic foreign bodies. Supra-glottic airways were obstructed and precarious. Apnoeic oxygenation utilizing high-flow nasal oxygen (HFNO), a form of tubeless anaesthetic, was used in all three cases, leading to the safe removal of the foreign bodies. Increased training, awareness and equipment availability to provide HFNO apnoeic oxygenation in the emergency setting for otolaryngology airway procedures will lead to better outcomes for patients and decreases the risk of a potential surgical airway.

6G enabling FSO communication system employing integrated PDM-OAM-OCDMA transmission: impact of weather conditions in India.

Currently, free space optics (FSO) transmission has gained attention due to its capability to deliver high data rates with a high level of security. In addition, using multiplexing techniques with FSO makes it capable of handling the excessive increase in traffic data and supporting the 5G and 6G wireless network requirements. Accordingly, in this paper, a novel, to the best of our knowledge, FSO system integrating three multiplexing techniques-orbital angular momentum (OAM) (four OAM beams are used) polarization-division multiplexing (two polarization states are used), and optical code division multiple access (four channels assigned with permutation vector codes are used)-is proposed. Additionally, the effects of rainy, foggy, dusty weather and the real weather for four different Indian cities that have different geographical locations are studied and investigated. The system performance is evaluated based on the bit error rate (BER), quality factor (Q-factor), maximum FSO range, and eye diagram opening. The simulation results show successful transmission of 320 Gbps overall capacity with a maximum achievable FSO range of 7 km under clear weather. On the other hand, the shortest FSO range of 0.105 km is achieved when there are heavy dust storms. As for the Indian cities, Srinagar (hilly area of India) achieves the shortest FSO link, which is 4.2 km while the largest range of 7 km is observed for Chennai city (coastal area of India). All these ranges are evaluated for a log(BER) value <-7. Consequently, this proposed transmission model is suggested for use in 6G applications of FSO communication systems.

Investigation on Enamel and Dentine of Tooth through 1D Photonic Structure to Identify the Caries in Human Teeth.

In this research, a one-dimensional (1D) photonic structure was employed to study the nature of both enamel and dentine teeth at the signal of 1.8 THz. A simple three layer one-dimensional crystal is chosen to avoid fabrication intricacy. The materials and methods for sample preparations are discussed. The principle of investigation of caries in the teeth relies on the amount of reflected signal from the structure. Similarly, reflectance is a function of refractive indices and thickness of each layer, the nature of both substrate and infiltrated materials, and the configuration of the structure. Apart from this, the fabrication process of one-dimensional structure and experimental set-up was proposed in this article. The numerical treatment is explained here to obtain reflectance, and subsequently, the output potential. Comparison studies on output potential between enamel and dentine are also shown through graphical representation. The output result in terms of milli-Volt (mV) were obtained at the output end and collected at the photodiode. Interesting results were also observed at the photodetector. For example; the output potential of the reflected signal is around 0.18 mV for both enamel and dentine teeth whereas the potential is more than 0.26 mV and 0.31 mV for caries in dentine and enamel, respectively. Finally, it was inferred that the nature of teeth pertaining to the caries in the enamel and dentine teeth can be investigated by identifying the amount of potential at the output end.

Performance analysis of serial relay orbital satellite optical communication over turbulent channels.

Optical space communication has been proven to be a reliable relay satellite transmission system. The difficulty that occurs in RF satellite communication (SatCom) can be alleviated by using free-space optical (FSO) or laser SatCom. In this work, we analyze a proposed laser downlink relay SatCom model with existing channel turbulence employing intensity modulation and direct detection (IM/DD), and amplify-and-forward (AF) technology and compare it with the optical direct link SatCom. Accounting for atmospheric attenuation and turbulence, the effect of model parameters such as zenith angle, receiver aperture radius, best number of optical ground stations (OGSs), and end-to-end operating wavelength on system performance is investigated for different OGS height scenarios. We provide exact closed-form expressions for the proposed model and optimize system performance by selecting the best number of OGSs using a selective diversity technique that can boost the system signal-to-noise (SNR) by up to 37 dB (99.9%).

Enhanced ADO-OFDM-based adaptive digital dimming VLC system.

Visible light communication (VLC) has shown significant growth in recent years. VLC simultaneously offers illumination and communication. In VLC systems, dimming control is used to handle the lighting and energy consumption constraints. In this paper, a new, to the best of our knowledge, adaptive digital dimming optical-orthogonal frequency division multiplexing (ADDO-OFDM) based on pulse width modulation is proposed to combine enhanced asymmetrically clipped DC biased optical OFDM (EADO-OFDM) and negative EADO-OFDM (ENADO-OFDM). It exploits the performance benefits of EADO-OFDM and ENADO-OFDM. The proposed ADDO-OFDM controls the dimming level in a vast range with an acceptable bit error rate with a favorable data length.

SMF/FSO integrated dual-rate reliable and energy efficient WDM optical access network for smart and urban communities.

To handle the massive high-speed internet traffic, free space optics (FSO) or single-mode fiber (SMF) based fiber optic communication is being used everywhere across the world. These technologies are capable of providing huge bandwidth and transmitting the data at very high speed with low energy consumption. FSO is a very convenient technology to quickly expand the legacy network in the adverse geographical areas. However, its link performance is highly dependent of inconsistent weather conditions. SMF based fiber optic link has a very low loss and its performance is almost independent on the weather conditions. Though, the installation and maintenance of fibers are quite complex and costly. Individually, FSO or SMF links have their limitations and have to be integrated to leverage their benefits. In this paper, we integrated FSO/SMF links and compared the performance of the proposed architecture which is capable of providing high-speed dual-rate data transmission. The proposed architecture transmits data over either FSO or SMF or both links simultaneously and has 100% more reliability against any one of the link failures. In case of operational link failure (FSO/SMF), data may be switched to the alternative working link (SMF/FSO), simply by tuning the transmitted signal by 50 GHz. The proposed architecture is also reliable against the optical line terminal transceiver (TRx) failure as each user located in the network can be served by two transceivers (1 Gbps and 10 Gbps). The proposed architecture also supports the wavelength division multiplexing overlay transmission for broadcasting the common signal to all the available users in the networks. The architecture reduces ~ 27% of the energy consumption by utilizing the appropriate link of hybrid architecture and TRx according to weather conditions and traffic load. The integrated architecture looks attractive for providing energy-efficient, high speed, and reliable internet coverage to the areas where there is a difficulty of laying fibers and has frequent fiber faults. The architecture is useful for strengthening and boosting rural and urban development.

LED nonlinearity mitigation in LACO-OFDM optical communications based on adaptive predistortion and postdistortion techniques.

The preinstalled white light emitting diodes (WLEDs) inside buildings can be exploited as an optical source in visible light communications (VLC) motivated by high optical efficiency and low cost. One of the main challenges for VLC is LED nonlinear distortion, which has a detrimental effect on system performance. Estimation and compensation of the LED nonlinear behavior can be accomplished using predistortion or postdistortion techniques. Three compensation techniques are adopted to mitigate the effect of LED nonlinearity on layered asymmetrically clipped optical, orthogonal frequency division multiplexing. Their performance and efficiency are discussed and compared with the aid of error vector magnitude and bit error rate (BER) in an additive white Gaussian noise channel. The obtained results reveal that polynomial-based predistorters and postdistorters can overcome the LED nonlinear behavior with extra SNR of only 0.25 dB at BER of 10-3. Furthermore, the look-up-table-based predistorter can provide the same BER with lower SNR penalty than the previous two systems.

Crystal structure and Hirshfeld surface analysis of N-[(Z)-(2-hy-droxy-phen-yl)methyl-idene]aniline N-oxide.

The conformation of the title compound, C13H11NO2, is partially determined by a strong, intra-molecular O-H⋯O hydrogen bond. The crystal packing consists of strongly corrugated layers parallel to the ac plane and associated through C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most significant contributions to the crystal packing are from H⋯H (44.1%), C⋯H/H⋯C (29.4%) and O⋯H/H⋯O (17.3%) contacts.

Nitro-Substituted Benzaldehydes in the Generation of Azomethine Ylides and Retro-1,3-Dipolar Cycloadditions.

1,3-Dipolar cycloaddition of 2- and 3-nitrobenzaldehydes with 2-aminomethylpyridine and ethyl (2E)-2-cyano-3-(4-nitrophenyl)prop-2-enoate yielded endo-cycloadducts as the sole products under various reaction conditions. Fortuitously, 4-nitrobenzaldehyde behaved differently in three- and four-component cascades to produce a mixture of endo- and exo'-cycloadducts. This reaction is solvent- and temperature-dependent, and consequently, both the endo- and exo'-cycloadducts were synthesized in an excellent regio-, stereo-, and chemoselective fashion. Retro-1,3-dipolar cycloadditions of the endo-cycloadducts were conducted under mild reaction conditions, and the generated syn-dipoles were stereomutated into anti-dipoles which recycloadded with the dipolarophiles to provide the exo'-cycloadducts. Mechanistic studies were carried out to support the proposed mechanisms. Unprecedentedly, particular arylidene scaffolds participated as aldehyde or activated methylene precursors. Density functional theory calculations were performed to shed light on the importance of AcOH in the generation and isomerization of dipoles and to explain the high selectivity and the possibility of retro-cycloaddition.

Follow-up neutrophil-lymphocyte ratio after stroke thrombectomy is an independent biomarker of clinical outcome.

BACKGROUND: Admission neutrophil-lymphocyte ratio (NLR) is significantly correlated to clinical outcomes in acute ischemic stroke (AIS). We investigated follow-up NLR and temporal changes in NLR after endovascular thrombectomy (EVT) with respect to successful revascularization, clinical outcomes, symptomatic intracranial hemorrhage (sICH) and mortality. METHODS: Retrospective analysis of EVT for anterior circulation emergent LVO was performed with both admission (NLR1) and 3-7 day follow-up NLR (NLR2) laboratory data. Patient demographics, National Institutes of Health Stroke Scale (NIHSS) presentations, reperfusion efficacy (modified Thrombolysis in Cerebral Infarction (mTICI) score), sICH, and clinical outcomes (modified Rankin Scale (mRS)) at 90 days were studied. Univariate analyses correlated NLR1, NLR2, and temporal change in NLR (NLR2-NLR1) with successful reperfusion (mTICI ≥2b), favorable outcomes (mRS ≤2), sICH, and mortality. Multivariable logistic regression model evaluated the independent effects of NLR2 on favorable outcomes. RESULTS: 142 AIS patients with median NIHSS 17 underwent EVT within 24 hours, and met NLR laboratory inclusion criteria. Lower follow-up NLR2 and less temporal change in NLR over 3-7 days, but not admission NLR1, inversely correlated with successful reperfusion (p<0.05) and favorable clinical outcomes (p<0.001). Higher follow-up NLR2 and greater temporal change in NLR was significantly associated with sICH and mortality (p≤0.05). In multivariable logistic regression, lower follow-up NLR2 remained a predictor of favorable outcomes (OR 0.785, p=0.001), independent of age or successful reperfusion. CONCLUSIONS: Follow-up NLR is a readily available and modifiable biomarker that correlates with the degree of reperfusion after mechanical stroke thrombectomy. Lower follow-up NLR2 at 3-7 days is associated with successful reperfusion and an independent predictor of favorable clinical outcomes, with reduced risk for sICH and mortality.

A Generalized Spatial Modulation System Using Massive MIMO Space Time Coding Antenna Grouping.

Massive multiple input multiple output (MIMO), also known as a very large-scale MIMO, is an emerging technology in wireless communications that increases capacity compared to MIMO systems. The massive MIMO communication technique is currently forming a major part of ongoing research. The main issue for massive MIMO improvements depends on the number of transmitting antennas to increase the data rate and minimize bit error rate (BER). To enhance the data rate and BER, new coding and modulation techniques are required. In this paper, a generalized spatial modulation (GSM) with antenna grouping space time coding technique (STC) is proposed. The proposed GSM-STC technique is based on space time coding of two successive GSM-modulated data symbols on two subgroups of antennas to improve data rate and to minimize BER. Moreover, the proposed GSM-STC system can offer spatial diversity gains and can also increase the reliability of the wireless channel by providing replicas of the received signal. The simulation results show that GSM-STC achieves better performance compared to conventional GSM techniques in terms of data rate and BER, leading to good potential for massive MIMO by using subgroups of antennas.

Exploring the effect of LED nonlinearity on the performance of layered ACO-OFDM.

Visible light communication (VLC) depends on light emitting diodes (LEDs) for data transmission. This is one of the strengths of VLC motivated by high optical efficiency and low cost. However, LEDs impose nonlinear effects on the transmitted signal and limit overall system performance, especially in the case of multicarrier modulation systems. This paper extends to the layered asymmetrically clipped optical, orthogonal frequency division multiplexing (LACO-OFDM) and investigates the impact of LED nonlinearity on system performance. The effect of the second-order nonlinear distortion in addition to the clipping noise is presented and analyzed at different power values assuming different strengths of nonlinearity. With a variable number of layers, the system performance is explored considering a nonlinear LED model. Finally, the impact of nonlinearity is investigated in the case of ACO-OFDM for the sake of comparison, bearing in mind that ACO-OFDM represents the first layer of LACO-OFDM.

On the performance of adaptive hybrid MQAM-MPPM scheme over Nakagami and log-normal dynamic visible light communication channels.

In this paper, we introduce the idea of using adaptive hybrid modulation techniques to overcome channel fading effects on visible light communication (VLC) systems. A hybrid $ M $M-ary quadrature-amplitude modulation ($ M{\rm QAM} $MQAM) and multipulse pulse-position modulation (MPPM) technique is considered due to its ability to make gradual changes in spectral efficiency to cope with channel effects. First, the Zemax optics studio simulator is used to simulate dynamic VLC channels. The results of Zemax show that Nakagami and log-normal distributions give the best fitting for simulation results. The performance of $ M{\rm QAM} $MQAM-MPPM is analytically investigated for both Nakagami and log-normal channels, where we obtain closed-form expressions for the average bit-error rate (BER). The optimization problem of evaluating the hybrid modulation technique settings that lead to the highest spectral efficiency under a specific channel status and constraint of outage probability is formulated and solved using an exhaustive search. Our results reveal that the adaptive hybrid scheme improves system spectral efficiency compared to ordinary QAM and MPPM schemes. Our results reveal that the adaptive hybrid scheme improves system spectral efficiency compared to ordinary QAM and MPPM schemes. Specifically, at low average transmitted power, $ - 32\;{\rm dBm} $-32dBm, the adaptive hybrid scheme shows 280% improvement in spectral efficiency compared to adaptive versions of ordinary schemes. At higher power, $ - 20\;{\rm dBm} $-20dBm, 6.5% and 725% improvement are obtained compared to ordinary QAM and ordinary MPPM, respectively. Also, the adaptive hybrid scheme shows great improvement in average BER and outage probability compared to ordinary schemes. The hybrid scheme shows 28%, 34%, and 38% improvement, respectively, for $ m = 1,2,3 $m=1,2,3 for Nakagami channels at $ {\rm BER}{ = 10^{ - 3}} $BER=10-3. Also, the outage probability of hybrid schemes of $ {\rm BER}{ = 10^{ - 3}} $BER=10-3 shows 30% and 14% better performance than ordinary $ M{\rm QAM} $MQAM and MPPM schemes, respectively.

NLoS underwater VLC system performance: static and dynamic channel modeling.

In this paper, the impact of water channels under different communication link parameters is studied for underwater visible light communication (UVLC). The objective is to highlight the best results for non-line of sight (NLoS) communication links. In addition, NLoS links are studied under different parameters: LED colors, viewing angle, receiving angle, and data rates. The results are obtained and plotted using MATLAB simulation. The performance of the received power is first measured at different wavelengths and data rates. Then, the best results are further investigated at different viewing angles and receiving angles. The obtained results show that using cyan color provides more depth for the NLoS case, as well as a low bit error rate compared to the other colors. Most of the literature is concerned with unpractical configurations in underwater scenarios, such as an empty sea or assuming no human-object or blockage environment. We use the practical setup in Zemax Optics Studio to allow a precise description of ray tracing and high order of reflections inside a sea water environment. The channel impulse response (CIR) is obtained for static channel modeling, including a blockage environment to evaluate the best transmitters in sea water. Also, we are able to compare the average delay and the average delay spread of the source colors. The reflection characteristics of the sea water are considered as wavelength dependent. The CIR obtained by Zemax Solver and MATLAB indicates that cyan is the best source in sea water for different LED chips. Moreover, other previous studies assume perfect alignment scenarios between divers, which is not practical and not suitable for real channel gain results. Accordingly, we present a comprehensive dynamic channel modeling and characterization study for UVLC. Our study is based on Zemax programming language (ZPL) combined with Zemax Optics Studio. Using ZPL enables us to apply a mobility algorithm for divers and measure the channel gain variations due to random motion. We introduce a dynamic motion in a single-input single-output scenario and a single-input multiple-output scenario in the presence of blockage divers. Statistical analyses are studied for the appropriate distributions that can fit the data with various transmitter and receiver specifications. All dynamic scenarios are performed using cyan color in sea water, as it is proven to have satisfactory performance. The statistical results are beneficial for further analysis. As case studies, we consider various underwater scenarios, and the resulting parameters of statistical distributions can be used for future analysis in UVLC dynamic environments.

Cerebral Artery Vasospasm Detection Using Transcranial Doppler Signal Analysis.

OBJECTIVES: Silent cerebral artery vasospasm in aneurysmal subarachnoid hemorrhage causes serious complications such as cerebral ischemia and death. A transcranial Doppler (TCD) ultrasound system is a noninvasive device that can effectively detect cerebral artery vasospasm as soon as it sets in, even before and in the absence of clinical deterioration. Continuous or even daily TCD monitoring is challenging because of the operator expertise and certification required in the form of a trained sonographer and interpretive experience required in the form of an additionally trained and certified physician to perform these studies. This barrier exists because of a lack of automation for detection (without human intervention) of cerebral artery vasospasm using TCD ultrasound. To overcome this barrier, we present an algorithm that automates detection of cerebral artery vasospasm. METHODS: We extracted features such as the energy, energy entropy, zero-crossing rate, spectral centroid, spectral speed, spectral entropy, spectral flux, spectral roll-off, harmonic ratio, chroma, and Mel frequency cepstral coefficients for signal classification. Then we applied principal component analysis to reduce the data dimensionality. RESULTS: All of the chosen features were used for training a decision-tree classifier. The algorithm had high accuracy for cerebral artery vasospasm detection, with overall sensitivity of 87.5% and specificity of 89.74%. CONCLUSIONS: The algorithm has the potential for development into a continuous cerebral artery vasospasm monitor.