Influence of ozone supply mode and aeration on photocatalytic ozonation of organic pollutants in wastewater using TiO2 and ZnO nanoparticles.

Photocatalytic ozonation, which combines the effects of lighting and ozonation, has been shown to enhance the decolorization and degradation of organic pollutants in wastewater. Dye solutions with concentrations of 10 ppm for both methylene blue and methyl orange dyes were used. The influence of ozoneation on the performance of photocatalytic activity of TiO2 and ZnO nanoparticles for the removal of organic dyes from aqueous solutions was investigated. To evaluate their efficacy for the removal of methylene blue and methyl orange dyes from aqueous solutions, the photocatalysts were exposed to UV light for 90 min, with ozone supplied either intermittently or continuously by an SDBD cold plasma reactor. The photocatalysts utilized in this study were characterized using SEM and XRD techniques. The degree of color degradation was determined using UV-Vis spectroscopy. The results demonstrate that TiO2 and ZnO nanoparticles exhibit different degrees of photocatalytic activity for the two dyes. The addition of ozone was found to enhance both the color degradation and mineralization rates of the pollutants, with intermittent ozonation proving more effective than continuous ozonation. The most significant color degradation results were obtained using TiO2 nanoparticles with intermittent ozonation for methylene blue dye (97 %) and ZnO nanoparticles with intermittent ozonation for methyl orange dye (40 %). Overall, this study provides evidence that photocatalytic ozonation represents a promising technique for water treatment.

Comparison of photocatalytic activity of ZnO, Ag-ZnO, Cu-ZnO, Ag, Cu-ZnO and TPPS/ZnO for the degradation of methylene blue under UV and visible light irradiation.

In this study, zinc oxide and silver and copper-doped zinc oxide nanorods were synthesized by a simple template-free precipitation technique. In addition, meso-tetrakis-(4-sulfonatophenyl) porphyrin (TPPS4) was prepared and immobilized on ZnO nanorods (TPPS/ZnO). The synthesized photocatalysts were characterized by various techniques such as X-ray powder diffraction, scanning electron microscopy, UV-visible spectroscopy, diffuse reflectance spectroscopy, and Fourier transform Infrared spectroscopy. The potential of the obtained photocatalysts in the degradation of methylene blue was investigated under UV and visible light irradiation. The results revealed that the photocatalytic activity of TPPS/ZnO was higher than those of the pure ZnO and doped ZnO under visible light irradiation.

Strategies to design efficient silica-supported photocatalysts for reduction of CO2.

The photocatalytic reduction of CO2 by water vapor to produce light hydrocarbons was studied over a series of catalysts consisting of variable loading of Ti incorporated in TUD-1 mesoporous silica, either modified by ZnO nanoparticles or isolated Cr-sites. Unexpectedly, the performance of ZnO-Ti-TUD-1 and Cr-Ti-TUD-1 was inferior to the parent Ti-TUD-1. An explanation can be found in experiments on the photocatalytic degradation of a mixture of hydrocarbons (i.e., CH4, C2H4, C2H6, C3H6, and C3H8) under the same illumination conditions. Ti-TUD-1 exhibits the poorest activity in hydrocarbon degradation, while ZnO-Ti-TUD-1 and Cr-Ti-TUD-1 showed very significant degradation rates. This study clearly demonstrates the importance of evaluating hydrocarbon conversion over photocatalysts active in converting CO2 to hydrocarbons (in batch reactors).