Reclamation effects of distinct volumes and concentrations of CaCl2-amended brackish ice in different saline-sodic soils.

The proper usage of marginal soil and water resources has major implications for the sustainability of agriculture, such as brackish water and saline-sodic soils. The saline soils can be ameliorated though melting process of calcium-containing brackish ice, however, the optimum concentration and volume of brackish ice (water) for the reclamation of different saline-sodic soils remain to be determined. In this study, 108 soil columns representing four Ice salinity levels (16, 26, 36, 46 mmolc L-1) and three Pore Volumes (2/3, 1.5, 2.5 PV) of calcium-amended brackish ice were tested to reveal the reclaiming effect on a range of saline-sodic soils. The linear mixed model (LMM), multiple regression equation, and principal coordinate analysis (PCoA) were applied to calculate the amelioration effect in terms of three factors: Ice volume, Ice salinity and Column depth. Our results showed that the soil salinity and sodicity generally decreased with increasing Ice volume and Ice salinity, and the saline-sodic soils with low exchangeable sodium percentages (i.e. ESP 20) were more sensitive to Ice salinity, with high salinity (26-46 mmolc L-1) and large volume (2.5 PV) of brackish ice reaching a better amelioration effect. The effect of Ice volume became more dominant in medium and high ESP soils (ESP 40 and ESP 70), whereas the high salinity combined with low volume of brackish ice would lead to worse soil properties, especially at the bottom layers. Meanwhile, the Column depth factor had a considerable effect on the soil chemical properties, with the variance explained ranging from 18.6% to 36.0%. These results provide theoretical guidance in the rational use of calcium-amended brackish ice and highlight the necessity to take layer effect into consideration for reclaiming saline-sodic soils.

Study on the difference of pore structure of anthracite under different particle sizes using low-temperature nitrogen adsorption method.

The low-temperature nitrogen adsorption test was used to study anthracite from Jiulishan coal mine with different particle size ranges of 60-80 mesh, 150-200 mesh, and > 200 mesh. The adsorption isotherm, adsorption capacity, pore volume, pore specific surface area, and average pore diameter of coal samples were analyzed by BET and DFT models in order to study the influence of particle size on the pore structure of anthracite and determine the optimal range of particle size for low-temperature nitrogen adsorption test. The results indicate that the particle size plays a significant effect on the pore structure of anthracite and the adsorption capacity of soft coal is less affected by particle size, while hard coal is substantially affected by particle size. The adsorption capacity of hard coal with particle size of > 200 mesh is increased by 7 times when compared with the particle size of 60-80 mesh, indicating that the gas molecular mobility hindrance decline and pore connectivity improves with the decrease of particle size. The average pore diameter of hard coal decreases continuously from 3.1424 to 2.854 nm, while that of soft coal expands from 2.8947 to 3.2515 nm and then to 3.0362 nm with the decrease of particle size. The effects of particle size on the pore surface area of soft and hard coal are concentrated within the < 10 nm pore aperture. Effect of particle size on hard coal pore volume is mainly focused in the pore size < 10 nm, whereas that of soft coal is primarily concentrated in the pore with aperture ranges of 2-100 nm. When the particle sizes varies from 60-80 mesh to 150-200 mesh, the collapse of large pore of hard coal appears better than that of closed pore. When the particle size of hard coal reaches > 200 mesh, the collapse of closed pores and the damage to small pores are stronger than the collapse of large pores. The fractal dimensions with relative pressure of 0-0.20 and 0.20-0.995 are defined as D1 and D2, respectively, and when the fractal dimension D1 increases, the surface roughness and structural complexity of coal samples increase with the decrease of anthracite particle size, while the fractal dimension D2 shows the opposite trend, which indicates that anthracite of smaller particle size possess higher adsorption capacity. Therefore, 150-200 mesh is recommended as the preferred anthracite particle size in low-temperature nitrogen adsorption test.

New Technology of Mechanical Cavitation in a Coal Seam to Promote Gas Extraction.

Realizing efficient gas drainage in low permeability coal seams has always been a difficult problem for coal miners. Based on this, this paper proposes a new technology of large-diameter mechanical cave-making to promote gas extraction in a coal seam. This technology mainly uses the pressure of a water injection pump to control the automatic opening and closing of a mechanical reaming device to realize mechanical cavitation, and the hole diameter can reach up to 500 mm. The gas drainage effect of mechanical cavitation drilling is analyzed by a numerical simulation, which shows that under the condition of the same drainage time, the larger the cavitation radius is, the larger the effective influence radius of gas drainage is. According to the field test results, the time of single cave-making is about 5 min, and the speed of cave-making is fast. The coal output of a single cave is 0.42 t/m, and the pressure relief effect is obvious. Compared with ordinary drilling, the gas drainage concentration of mechanical cavitation drilling is increased by 2 times and the net amount of drainage is increased by 1.8 times. Large-diameter mechanical cavitation technology can better improve the gas drainage effect of outburst coal seams with low permeability and has a good application prospect.

Temperature of the Core Tube Wall during Coring in Coal Seam: Experiment and Modeling.

Temperature is the primary factor affecting the law of coal gas desorption. When the core method is used to measure the coal seam gas content (CSGC), the temperature of the coal core sample (CCS) will increase because the heat generated by the core bit cutting and rubbing the coal is transferred to the CCS through the core tube. To solve the above problems, the temperature of the core tube wall during coring at core depths of 10, 20, and 30 m was measured by a self-designed temperature measuring device. The thermodynamic models of the core bit and the core tube during coring were established. The thermal flux of the system at different stages was inverted numerically by the dichotomy method. The reliability of the model was verified by comparing the numerical simulation results with the field measurement results. The main influencing factors during coring were studied by numerical simulations. The results show that the temperature change of the core tube wall goes through four stages: slowly rising, fast rising, slowly rising, and slowly falling, which correspond to the process of pushing the core tube, drilling the CCS, and the early stage and later stage of withdrawing the core tube, respectively. The maximum temperature of the core tube wall appears in the first 5 min of withdrawing the core tube and increases with the increase of core depth. When the core depth is 30 m, the maximum temperature of the core tube wall reaches 105.17 °C. The temperature of the measuring point at the end of drilling the CCS and the maximum temperature during coring linearly increase with the core depth, friction heat generated while pushing the core tube, and coal strength. This study can provide a basis for further research on the dynamic distribution characteristics of temperature in the CCS during coring, which is of profound significance to calculate the gas loss amount and CSGC.

Soil bacterial microbiota predetermines rice yield in reclaiming saline-sodic soils leached with brackish ice.

BACKGROUND: Saline-sodic lands threaten the food supply and ecological security in the western Songnen Plain of northeast China, and the gypsum is commonly adopted for restoration. However, the dynamics of soil bacterial community and the correlation with crop yield during restoring processes remain poorly understood. Here, we elucidated the soil chemical properties and bacterial communities and their associations with rice yield under different flue gas desulphurization gypsum (FGDG) application rates combined with brackish ice leaching. RESULTS: The increased application rate of FGDG generally improved soil reclamation effects, as indicated by soil chemical properties, bacterial diversity, and rice yield. Compared with fresh ice irrigation, the rice yield in brackish ice treatment increased by 15.84%, and the soil alkalinity and sodium adsorption ratio (SAR) decreased by 35.19% and 10.30%, respectively. The bacterial alpha diversity significantly correlated and predicted rice yield as early as brackish ice melt, suggesting the bacterial diversity was a sensitive indicator in predicting rice yield. Meanwhile, the bacterial communities in the control possessed a high abundance of oligotrophic Firmicutes, while eutrophic bacterial taxa (e.g. Proteobacteria) were enriched after brackish water irrigation and FGDG application. Moreover, we also established a Random Forest model and identified a bacterial consortium that explained an 80.0% variance of rice yield. CONCLUSION: Together, our results highlight the reclaiming effect of brackish ice in the saline-sodic field and demonstrate the sensitivity and importance of the soil bacterial community in predicting crop yield, which would provide essential knowledge on the soil quality indication and bio-fertilizer development for soil reclamation. © 2021 Society of Chemical Industry.

Plastic zone range of a roadway considering the creep effect.

The plastic zone range is an important parameter in the analysis of damage characteristics and the degree of damage to the rock surrounding a roadway. Based on the establishment of a plastic zone calculation model considering the creep effect, this paper obtains the characteristics of the change in the plastic zone damage range with time by solving the model. Additionally, the validity of the model is verified by field experiments. The research results can provide guidance for gas pressure measurement and gas drainage in coal mines.

Measurement and Modeling of Spontaneous Capillary Imbibition in Coal.

Coal is a typical dual-porosity medium. The implementation process of water invasion technology in coal is actually a process of spontaneous imbibition of external water. To obtain a model of spontaneous capillary imbibition in coal, the spontaneous imbibition of water in coal samples with different production loads is conducted experimentally. Due to the coal particle deformation and the cohesive forces, the porosity and maximum diameter decrease gradually with increasing pressing loads. Due to the filling effects and occupying effects, the proper particle grading can reduce the porosity and tortuosity. The Comiti model can be used to describe the tortuosity. The tortuosity increases with decreasing porosity. The smaller the porosity, the smoother the surface of the coal sample. The contact angle is negatively correlated with the surface roughness. The fractal dimension decreases with increasing pressing load. The difference in the pore characteristics between particles is the main reason for the difference in the fractal dimension. The proposed model of spontaneous capillary imbibition in coal is consistent with the experimental data. The implications of this study are important for understanding the law of spontaneous imbibition in coal and the displacement of gas by spontaneous capillary imbibition in coal, which is important for optimizing the parameters of coal seam water injection.

Amendments to saline-sodic soils showed long-term effects on improving growth and yield of rice (Oryza sativa L.).

BACKGROUND: Saline-sodic soils are widely distributed in arid and semi-arid regions around the world. High levels of salt and sodium inhibit the growth and development of crops. However, there has been limited reports on both osmotic potential in soil solutions (OPss) and characteristics of Na+ and K+ absorption in rice in saline-sodic soils under various amendments application. METHODS: A field experiment was conducted between 2009 and 2017 to analyze the influence of amendments addition to saline-sodic soils on rice growth and yield. Rice was grown in the soil with no amendment (CK), with desulfurization gypsum (DG), with sandy soil (SS), with farmyard manure (FM) and with the mixture of above amendments (M). The osmotic potential in soil solution, selective absorption of K+ over Na+ (SA), selective transport of K+ over Na+ (ST), the distribution of K+ and Na+and yield components in rice plants were investigated. RESULTS: The results indicated that amendments application have positive effects on rice yield. The M treatment was the best among the tested amendments with the highest rice grain yield. M treatment increased the OPss values significantly to relieve the inhibition of the water uptake by plants. Additionally, the M treatment significantly enhanced K+ concentration and impeded Na+ accumulation in shoots. SA values were reduced while ST values were increased for all amendments. In conclusion, a mixture of desulfurization gypsum, sandy soil and farmyard manure was the best treatment for the improvement of rice growth and yield in the Songnen Plain, northeast China.

Freezing method for rock cross-cut coal uncovering I: Mechanical properties of a frozen coal seam for preventing outburst.

A comprehensive technology is proposed to realize fast and safe rock cross-cut coal uncovering (RCCCU) based on artificial freezing engineering method. This comprehensive technology includes four steps, namely, drilling a borehole, wetting the coal body by water injection, gas drainage and freezing the coal seam by liquid nitrogen injection. In this paper, the compressive strength, tensile strength and shear strength of frozen coal specimens are tested to obtain the mechanical parameters of the specimen. Then, for RCCCU under freezing temperatures, the outburst prevention effects are calculated and quantitatively analysed with regard to three aspects, namely, the enhancement of coal the mechanical properties, the reduction in the coefficient of outburst hazard (COH) in the distressed zone and the reduction in the interfacial elastic energy ratio (IEER) between the coal seam and the roof/floor. The results show that a considerable improvement in the mechanical properties of frozen coal and that the coal mechanical parameters, such as the compressive strength and the tensile strength, increase linearly with decreasing temperature. The coefficient of outburst hazard in the distressed zone decreases rapidly and drops from above 0.8 to below 0.3. The interfacial elastic energy ratio is greatly reduced from dozens of times of that of the roof/floor before freezing to several times of that of the roof/floor after freezing, which effectively weakens the sudden change of the elastic energy at the coal-rock interface.

The impact of irrigation on yield of alfalfa and soil chemical properties of saline-sodic soils.

BACKGROUND: Forage production in the saline-sodic soil of the western Songnen Plain Northeast China depends on irrigation. Therefore, the water use efficiency (WUE) and soil chemical properties are key factors in the overall forage productivity in this water scarce region. Improving forage yield, WUE, and soil properties under irrigation are very important for food and ecological security in this water-deficient region. Additionally, a suitable irrigation schedule for this region is necessary. METHODS: A field experiment was conducted between 2015 and 2018 to evaluate the effects of irrigation on artificial grassland productivity and the changes in soil chemical properties as well as to plan a reliable irrigation schedule for the western Songnen Plain. Eight irrigation treatments were designed, which depended on the three growth stages of alfalfa. The shoot height (SH), the chlorophyll content (SPAD), the dry yield (DM), the ratio of stem to leaves (SLR), the WUE, the changes in the chemical properties of the soil, and precipitation and evaporation were investigated. RESULTS: The SH, DM, WUE, and SLR were significantly increased by irrigation (P < 0.01). However, the SPAD resulting from irrigation was not significantly higher than the SPAD of CK (no irrigation) (P < 0.05). In addition, the soil chemical properties at the depth of 0-100 cm were significantly decreased by irrigation P (0.05). For example, the soil electrical conductivity, sodium absorption ratio, and total alkalization were reduced 182-345 µS cm-1, 8.95-9.00 (mmolc/L)1/2, and 3.29-4.65 mmolc L-1 by different irrigation treatments, respectively. Finally, considering the highest WUE of I5 (irrigation at branch stage) (2.50 kg m-3), relative high DM of I5 (787.00 g m-2), the precipitation, the evaporation, the water resources, and the changes of the soil's chemical properties, 236.50 mm of irrigation water was recommended at the branching stage of alfalfa for the western Songnen Plain, Northeast China.

The effect of a tectonic stress field on coal and gas outbursts.

Coal and gas outbursts have always been a serious threat to the safe and efficient mining of coal resources. Ground stress (especially the tectonic stress) has a notable effect on the occurrence and distribution of outbursts in the field practice. A numerical model considering the effect of coal gas was established to analyze the outburst danger from the perspective of stress conditions. To evaluate the outburst tendency, the potential energy of yielded coal mass accumulated during an outburst initiation was studied. The results showed that the gas pressure and the strength reduction from the adsorbed gas aggravated the coal mass failure and the ground stress altered by tectonics would affect the plastic zone distribution. To demonstrate the outburst tendency, the ratio of potential energy for the outburst initiation and the energy consumption was used. Increase of coal gas and tectonic stress could enhance the potential energy accumulation ratio, meaning larger outburst tendency. The component of potential energy for outburst initiation indicated that the proportion of elastic energy was increased due to tectonic stress. The elastic energy increase is deduced as the cause for a greater outburst danger in a tectonic area from the perspective of stress conditions.

A fractal theory based fractional diffusion model used for the fast desorption process of methane in coal.

Based on the realistic property of the pore structure in coal, we established a fractal theory based Fractional diffusion model (FFDModel) by introducing the fractal dimension df to the Fick's classical model and changing the first-order partial differential equation about time into a υ fractional-order partial differential equation. Then, the solution of the FFDModel was obtained with separation variables technique. In order to verify the correctness of the solution, three coal samples with different rank from China were collected to do the methane desorption experiment of the fast desorption stage. The results indicate that the fractal dimension (df) of the coking coal is the lowest of the three coal ranks. By comparing the FFDModel with Fick's classical model, we can see that the FFDModel fits better with the three measured samples.