Characteristics of typical intermediate and semi volatile organic compounds in Shanghai during China International Import Expo event.

To ensure good air quality during the China International Import Expo (CIIE) event, stringent emission-reduction measures were implemented in Shanghai. To assess the efficacy of these measures, this study measured typical categories of intermediate/semi volatile organic compounds (I/SVOCs), including alkanes (C10-C26 n-alkanes and pristane), EPA-priority polycyclic aromatic hydrocarbons (PAHs), alkylnaphthalenes, benzothiazole (BTH) and chlorobenzenes (CBs), at an urban site of Shanghai before and during two CIIE events (2019 and 2020; non-CIIE versus CIIE). The average concentrations of alkanes and PAHs during both 2019 and 2020 CIIE events decreased by approximately 41% and 17%, respectively, compared to non-CIIE periods. However, the decline in BTH and CBs was only observed during CIIE-2019. Secondary organic aerosol (SOA) formation from alkanes, PAHs and BTH was evaluated under atmospheric conditions, revealing considerable SOA contributions from dimethylnaphthalenes and BTH. Positive matrix factorization (PMF) analysis further revealed that life-related sources, such as cooking and residential emissions, make a noticeable contribution (21.6%) in addition to the commonly concerned gasoline-vehicle sources (31.5%), diesel-related emissions (20.8%), industrial emissions (18.6%) and ship emissions (7.5%). These findings provide valuable insights into the efficacy of the implemented measures in reducing atmospheric I/SVOCs levels. Moreover, our results highlight the significance of exploring additional individual species of I/SVOCs and life-related sources for further research and policy development.

An online method for monitoring atmospheric intermediate volatile organic compounds with a thermal desorption-gas chromatography/mass spectrometry.

As one of important precursors of secondary organic aerosol (SOA), intermediate volatile organic compounds (IVOCs) have attracted much attention in recent years. Most of the previous studies however largely focused on characteristics of IVOCs from different emission sources, while data from field observations to study their temporal variations was limited for lacking the sufficient time resolution monitoring data. In this study, an online thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS) method was developed to generate monitor data with a three-hour time resolution for gaseous atmospheric IVOCs. The method used two multi-sorbent traps that alternated for conducting sample collection and sample analysis. Compounds of C12C22 n-alkanes and 2-4 ring PAHs were chosen as surrogates to evaluate the performance of this method. Regression coefficients of external calibration curves were greater than 0.93 and 0.96 for all individual n-alkanes and PAHs, respectively. Average relative standard deviation (RSD) values among replicate samples spiked at 3 ng for each individual standard were 9% ± 5%. The detection limits of this method for individual n-alkanes and PAHs were 3.1-16.2 ng/m3 and 1.0-2.7 ng/m3, respectively. Atmospheric IVOCs were continuously monitored from September 28 to 30 and October 22 to November 9 in 2018, in an urban area of Shanghai. Besides targeted n-alkanes and PAHs, unspeciated complex mixtures (UCM) of IVOCs as well as total-IVOCs concentrations in the atmosphere were also determined. Measured concentrations and compositions of gaseous IVOCs in the atmosphere in this study were comparable to other similar studies.