RESUMO
In the title compound, C18H20F2N2O2S, the central piperazine ring adopts a chair conformation. The dihedral angle between the two benzene rings is 40.20°, whereas those between the piperazine ring (considering the best fit plane through all the non-H atoms) and the sulfonyl-bound benzene and di-fluoro-benzene rings are 74.96 and 86.16°, respectively. In the crystal, mol-ecules are stacked along the a axis through weak C-Hâ¯O and C-Hâ¯F inter-actions.
RESUMO
In the title compound, C18H20Cl2N2O2S, the piperazine ring adopts a chair conformation. The dihedral angle between the sulfonyl-bound benzene ring and the best-fit plane through the six non-H atoms of the piperazine ring is 72.22â (12)°; those between the di-chloro-benzene ring and the sulfonyl and piperazine rings are 2.44â (13) and 74.16â (2)°, respectively. In the crystal, mol-ecules are connected through weak C-Hâ¯O inter-actions into a hexa-meric unit generating a R 6 (6)(60) motif in the ab plane. The mol-ecules are also connected into C(4) chains through weak C-Hâ¯N inter-actions. The solvent used to grow the crystal was a mixture of di-chloro-methane and methanol, but the resulting electron density was uninter-pretable. The solvent contribution to the scattering was removed with the SQUEEZE routine in PLATON [Spek (2009 â¶). Acta Cryst. D65, 148-155]. The formula mass and unit-cell characteristics do not take into account the disordered solvent.
RESUMO
In the crystal structure of the title compound, C(19)H(21)F(3)N(2)O(2)S, the piperazine ring adopts a chair conformation. The dihedral angles between the mean plane of the piperazine ring and the tosyl and trifluoro-methyl-phenyl rings are 74.52â (3) and 68.30â (2)°, respectively. The sulfonamide N atom deviates from the plane defined by the three attached atoms by 0.327â (1)â Å. The crystal structure is stabilized by weak C-Hâ¯π inter-actions.