1.
Org Lett
; 17(13): 3264-7, 2015 Jul 02.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26091063
RESUMO
A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined, and all delivered high enantioselectivity (up to 98:2 er) as well as good branch:linear ratios (up to 15:1).
