1.
Carbohydr Res
; 304(2): 179-82, 1997 Nov 10.
Artigo
em Inglês
| MEDLINE
| ID: mdl-9527441
RESUMO
Glycosylation of 12beta-acetoxy-dammar-24-en-3beta,20(S)-diol (4), with hepta-O-acetyl-alpha-sophorosyl bromide (5) under catalysis by Ag2CO3 or Ag2O afforded a chromatographically unseparated mixture of the alpha- and beta-linked octaacetates 6 and 7 in an approximately 2.5:1 ratio. After deprotection and chromatographic purification, the free alpha- (8) and beta-glycosides (9) were obtained. Sophoroside 9 was identical in all respects with ginsenoside Rg3, the minor component of Ginseng Radix rubra. All compounds were fully characterized by 1H and 13C NMR spectroscopy.
Assuntos
Ginsenosídeos , Panax/química , Plantas Medicinais , Saponinas/síntese química , Acetilação , Glicosilação , Espectroscopia de Ressonância Magnética , Estrutura Molecular , Saponinas/química , Saponinas/isolamento & purificação
2.
Pediatriia
; (2): 26-7, 1983 Feb.
Artigo
em Russo
| MEDLINE
| ID: mdl-6682970
3.
Pediatriia
; (7): 17-20, 1982 Jul.
Artigo
em Russo
| MEDLINE
| ID: mdl-7133862