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1.
Chemosphere ; 351: 141261, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38244873

RESUMO

Rapid industrial growth and urbanization have resulted in a significant rise in environmental pollution issues, particularly indoor air pollutants. As a result, it is crucial to design and develop technologies and/or catalysts that are not only cost-effective but also promising high performance and practical applicability. However, achieving this goal has been so far remained a challenging task. Herein, a series of transition metal M - TiO2 (M = W, Fe, Mn) nanocrystals was prepared for photocatalytic degradation of volatile organic compounds (VOCs), i.e., toluene. Of the nanocomposites tested, W-TiO2 showed significantly improved photocatalytic activity for VOC degradation under UV irradiation compared to the others. In particular, the optimized W dopant amount of 0.5 wt% resulted in the outstanding degradation performance of toluene (96%) for the obtained W-TiO2(0.5%) nanocomposite. Moreover, W-TiO2(0.5%) nanocomposite exhibited good stability for 32 h working under high toluene concentration (10 ppm) compared to the pristine TiO2. The current work demonstrates the potential usage of M - TiO2 nanocrystals, particularly W-TiO2(0.5%), as a promising photocatalyst for efficient VOCs degradation.


Assuntos
Poluentes Atmosféricos , Nanocompostos , Titânio/química , Raios Ultravioleta , Tolueno/química , Nanocompostos/química , Catálise , Poluentes Atmosféricos/química
2.
Environ Sci Process Impacts ; 24(12): 2191-2216, 2022 Dec 14.
Artigo em Inglês | MEDLINE | ID: mdl-36278886

RESUMO

The rapid spread of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) and the resulting worldwide death toll have prompted worries regarding its transmission mechanisms. Direct, indirect, and droplet modes are the basic mechanisms of transmission. SARS-CoV-2 spreads by respiratory droplets (size range >10 µm size ranges), aerosols (5 µm), airborne, and particulate matter. The rapid transmission of SARS-CoV-2 is due to the involvement of tiny indoor air particulate matter (PM2.5), which functions as a vector. SARS-CoV-2 is more contagious in the indoor environment where particulate matter floats for a longer period and greater distances. Extended residence time in the environment raises the risk of SARS-CoV-2 entering the lower respiratory tract, which may cause serious infection and possibly death. To decrease viral transmission in the indoor environment, it is essential to catch and kill the SARS-CoV-2 virus and maintain virus-free air, which will significantly reduce viral exposure concerns. Therefore, effective air filters with anti-viral, anti-bacterial, and anti-air-pollutant characteristics are gaining popularity recently. It is essential to develop cost-effective materials based on nanoparticles and metal-organic frameworks in order to lower the risk of airborne transmission in developing countries. A diverse range of materials play an important role in the manufacturing of effective air filters. We have summarized in this review article the basic concepts of the transmission routes of SARS-CoV-2 virus and precautionary measures using air purifiers with efficient materials-based air filters for the indoor environment. The performance of air-filter materials, challenges and alternative approaches, and future perspectives are also presented. We believe that air purifiers fabricated with highly efficient materials can control various air pollutants and prevent upcoming pandemics.


Assuntos
Filtros de Ar , Poluentes Atmosféricos , COVID-19 , Humanos , SARS-CoV-2 , COVID-19/epidemiologia , COVID-19/prevenção & controle , Aerossóis e Gotículas Respiratórios , Material Particulado/análise , Fatores de Risco
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