Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 12 de 12
Filtrar
Mais filtros










Base de dados
Intervalo de ano de publicação
1.
Sci Rep ; 10(1): 9934, 2020 Jun 18.
Artigo em Inglês | MEDLINE | ID: mdl-32555226

RESUMO

Neutron powder diffraction profiles were collected for iron deuteride (FeDx) while the temperature decreased from 1023 to 300 K for a pressure range of 4-6 gigapascal (GPa). The ε' deuteride with a double hexagonal close-packed (dhcp) structure, which coexisted with other stable or metastable deutrides at each temperature and pressure condition, formed solid solutions with a composition of FeD0.68(1) at 673 K and 6.1 GPa and FeD0.74(1) at 603 K and 4.8 GPa. Upon stepwise cooling to 300 K, the D-content x increased to a stoichiometric value of 1.0 to form monodeuteride FeD1.0. In the dhcp FeD1.0 at 300 K and 4.2 GPa, dissolved D atoms fully occupied the octahedral interstitial sites, slightly displaced from the octahedral centers in the dhcp metal lattice, and the dhcp sequence of close-packed Fe planes contained hcp-stacking faults at 12%. Magnetic moments with 2.11 ± 0.06 µB/Fe-atom aligned ferromagnetically in parallel on the Fe planes.

2.
Sci Rep ; 9(1): 12290, 2019 Aug 23.
Artigo em Inglês | MEDLINE | ID: mdl-31444386

RESUMO

Hexagonal close-packed iron hydride, hcp FeHx, is absent from the conventional phase diagram of the Fe-H system, although hcp metallic Fe exists stably over extensive temperature (T) and pressure (P) conditions, including those corresponding to the Earth's inner core. In situ X-ray and neutron diffraction measurements at temperatures ranging from 298 to 1073 K and H pressures ranging from 4 to 7 GPa revealed that the hcp hydride was formed for FeHx compositions when x < 0.6. Hydrogen atoms occupied the octahedral interstitial sites of the host metal lattice both partially and randomly. The hcp hydride exhibited a H-induced volume expansion of 2.48(5) Å3/H-atom, which was larger than that of the face-centered cubic (fcc) hydride. The hcp hydride showed an increase in x with T, whereas the fcc hydride showed a corresponding decrease. The present study provides guidance for further investigations of the Fe-H system over an extensive x-T-P region.

3.
Sci Rep ; 6: 26641, 2016 05 25.
Artigo em Inglês | MEDLINE | ID: mdl-27221010

RESUMO

We investigated molecular dissociation induced by 10-keV X-ray irradiation in dense ice at pressures up to 40 GPa at 300 K. The dissociation yield estimated from the oxygen K-edge X-ray Raman spectra, showed that the molecular dissociation was enhanced up to 14 GPa and gradually suppressed on further compression to 40 GPa. The molecular dissociation was detected for a rather narrow pressure span of 2-40 GPa by the X-ray spectroscopy. The pressure variation of the dissociation yield was similar to that observed in the electric conductivity of ice VII and likely interpreted in terms of proton mobility.

4.
Angew Chem Int Ed Engl ; 54(19): 5650-3, 2015 May 04.
Artigo em Inglês | MEDLINE | ID: mdl-25773066

RESUMO

Despite many exploratory studies over the past several decades, the presently known transition metals that form homoleptic transition-metal hydride complexes are limited to the Groups 7-12. Here we present evidence for the formation of Mg3 CrH8 , containing the first Group 6 hydride complex [CrH7 ](5-) . Our theoretical calculations reveal that pentagonal-bipyramidal H coordination allows the formation of σ-bonds between H and Cr. The results are strongly supported by neutron diffraction and IR spectroscopic measurements. Given that the Group 3-5 elements favor ionic/metallic bonding with H, along with the current results, the true boundary for the formation of homoleptic transition-metal hydride complexes should be between Group 5 and 6. As the H coordination number generally tends to increase with decreasing atomic number of transition metals, the revised boundary suggests high potential for further discovery of hydrogen-rich materials that are of both technological and fundamental interest.

5.
Nat Commun ; 5: 5063, 2014 Sep 26.
Artigo em Inglês | MEDLINE | ID: mdl-25256789

RESUMO

Hydrogen composition and occupation state provide basic information for understanding various properties of the metal-hydrogen system, ranging from microscopic properties such as hydrogen diffusion to macroscopic properties such as phase stability. Here the deuterization process of face-centred cubic Fe to form solid-solution face-centred cubic FeDx is investigated using in situ neutron diffraction at high temperature and pressure. In a completely deuterized specimen at 988 K and 6.3 GPa, deuterium atoms occupy octahedral and tetrahedral interstitial sites with an occupancy of 0.532(9) and 0.056(5), respectively, giving a deuterium composition x of 0.64(1). During deuterization, the metal lattice expands approximately linearly with deuterium composition at a rate of 2.21 Å(3) per deuterium atom. The minor occupation of the tetrahedral site is thermally driven by the intersite movement of deuterium atoms along the direction in the face-centred cubic metal lattice.

6.
Sci Rep ; 4: 5778, 2014 Jul 22.
Artigo em Inglês | MEDLINE | ID: mdl-25047728

RESUMO

It was discovered that a peak appears near a pressure of Pc = 10 GPa in the electrical conductivity of ice VII as measured through impedance spectroscopy in a diamond anvil cell (DAC) during the process of compression from 2 GPa to 40 GPa at room temperature. The activation energy for the conductivity measured in the cooling/heating process between 278 K and 303 K reached a minimum near Pc. Theoretical modelling and molecular dynamics simulations suggest that the origin of this unique peak is the transition of the major charge carriers from the rotational defects to the ionic defects.

7.
J Chem Phys ; 132(12): 121102, 2010 Mar 28.
Artigo em Inglês | MEDLINE | ID: mdl-20370105

RESUMO

The effects of temperature and pressure upon structural, dynamical, and electronic properties of liquid H(2)O were systematically investigated via first principles molecular dynamics and in situ x-ray diffraction in the chosen isochore (1.00-1.61 g/cm(3)) and isotherm (300-900 K) conditions. Our study suggests that the crossover occurs between H-bonded and simple-liquidlike liquids by raising temperature in molecular liquid phase.

9.
Phys Rev Lett ; 96(25): 255504, 2006 Jun 30.
Artigo em Inglês | MEDLINE | ID: mdl-16907320

RESUMO

To verify the high-pressure formation of the bulk metallic glass in elemental Zr and Ti, which Zhang and Zhao [Nature (London) 430, 332 (2004)] and Y. Wang et al. [Phys. Rev. Lett. 95, 155501 (2005)] recently reported, the high-pressure states were investigated by our newly developed in situ angle-dispersive x-ray diffraction using a two-dimensional detector and x-ray transparent anvils. Despite the disappearance of all the Bragg peaks in the one-dimensional energy-dispersive data, two-dimensional angle-dispersive data showed several intense Bragg spots even at the conditions where the amorphization was reported. This finding suggests that Zr and Ti do not transform into an amorphous state, but that their grain size becomes large, which causes the missing Bragg peaks in energy-dispersive data.

10.
Phys Rev Lett ; 96(10): 105702, 2006 Mar 17.
Artigo em Inglês | MEDLINE | ID: mdl-16605761

RESUMO

The phase study of a Cd-Yb 1/1 approximant crystal over a wide pressure and temperature range is crucial for the comparison study between periodic and quasiperiodic crystals. The Cd(4) tetrahedra, the most inner part of the atomic clusters, exhibited various structural ordering in the orientation sensitive to pressure and temperature. Five ordered phases appeared in a P-T span up to 5.2 GPa and down to 10 K. The propagation direction of ordering alternated from [110] to <111> to at about 1.0 GPa and again to [110] at 3.5-4.3 GPa. The primarily ordered phases that appeared by cooling to 210-250 K between 1.0-5.2 GPa further transformed to finely ordered ones at 120-155 K. Besides the original short-range type interaction, a long-range type interaction was likely developed under pressure to lead to the primary ordering of Cd(4) tetrahedra. Coexistence of these interactions is responsible for the complicated phase behavior.

11.
Nat Mater ; 2(11): 735-8, 2003 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-14578879

RESUMO

The synthesis of large single crystals of GaN (gallium nitride) is a matter of great importance in optoelectronic devices for blue-light-emitting diodes and lasers. Although high-quality bulk single crystals of GaN suitable for substrates are desired, the standard method of cooling its stoichiometric melt has been unsuccessful for GaN because it decomposes into Ga and N(2) at high temperatures before its melting point. Here we report that applying high pressure completely prevents the decomposition and allows the stoichiometric melting of GaN. At pressures above 6.0 GPa, congruent melting of GaN occurred at about 2,220 degrees C, and decreasing the temperature allowed the GaN melt to crystallize to the original structure, which was confirmed by in situ X-ray diffraction. Single crystals of GaN were formed by cooling the melt slowly under high pressures and were recovered at ambient conditions.


Assuntos
Cristalização/métodos , Gálio/química , Gálio/efeitos da radiação , Temperatura Alta , Lasers , Nanotecnologia/métodos , Estudos de Viabilidade , Teste de Materiais , Conformação Molecular , Pressão , Semicondutores , Temperatura , Temperatura de Transição/efeitos da radiação
12.
Acta Crystallogr C ; 59(Pt 8): m319-21, 2003 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-12909755

RESUMO

In the crystal structure of the title compound, [Fe(H(2)O)(6)](C(6)H(2)N(3)O(7))(2).2H(2)O, the centrosymmetric cationic iron complexes and picrate anions form separate stacks extending along the b axis. No picrate species ligate to the metal cation. Picrate ions are linked to one another in the stack via short intermolecular C.C contacts of 3.083 (4) and 3.055 (4) A. Variable-temperature X-ray diffraction measurements performed between room temperature and 93 K showed a linear decrease of the lattice parameters, suggesting that there is no phase transition.

SELEÇÃO DE REFERÊNCIAS
DETALHE DA PESQUISA
...