1.
Dalton Trans
; 53(28): 11952-11958, 2024 Jul 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38958393
RESUMO
We disclose a novel series of N-heterocyclic carbene (NHC) gold complexes with varied steric and electronic properties, bearing fluorinated alkoxide anions. Early reactivity studies involving these synthons, lead to the synthesis of various complexes of relevance to gold chemistry and catalysis.
2.
Chem Commun (Camb)
; 59(59): 9126-9129, 2023 Jul 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37408525
RESUMO
The synthesis, isolation and full characterisation of a [Cu(IPr)(OC(H)(CF3)2)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) complex are reported. This new Cu(I) complex is a versatile synthon and can activate numerous X-H bonds including C-H, N-H and S-H bonds. [Cu(IPr)(OC(H)(CF3)2)] was investigated as a pre-catalyst in several catalytic reactions.