RESUMO
Deintercalation of carbonate from layered double hydroxides (LDH) followed by intercalation of another anion (decarbonative intercalation) is a good method for the synthesis of crystalline LDH with different intercalated anions. We have carried out decarbonative intercalation of halides, nitrate, acetate, and sulfate by refluxing the carbonate-LDH with the corresponding ammonium salt in 1-butanol to obtain ordered LDH incorporating the desired anion. The crystallinity of the precursor LDH is retained in the anion-exchanged products, making this reaction a useful tool to prepare ordered LDH containing various anions. In addition, the morphology of the LDH is also retained after the exchange, making the reaction morphotactic. As the reaction is facilitated by the weak acidity of the ammonium salt, just grinding the carbonate-LDH with the ammonium salt of the desired anion also results in anion exchange. However, while the crystallinity of the LDH is retained, the morphology changes possibly due to breaking up of the crystals during the reaction.
RESUMO
Surfactant anion intercalated hydroxy salts of copper and cobalt of the formula M(OH)2- x (surf)x.mH2O [M = Cu, Co; surf = dodecyl sulfate, dodecyl benzene sulfonate, and x = 0.5 for Cu and 0.67 for Co] delaminate readily in 1-butanol to give translucent colloidal dispersions that are stable for months. The extent of delamination and the colloidal dispersion observed in these solids is higher than what had been observed for layered double hydroxides. The dispersions yield the corresponding nanoparticulate oxides on solvothermal decomposition. While the copper hydroxy salt forms approximately 300 nm dendrimer-like CuO nanostructures comprising nanorods of approximately 10 nm diameter, the cobalt analogue forms approximately 20 nm superparamagnetic particles of Co3O4.
