A new method to map groundwater-dependent ecosystem zones in semi-arid environments: A case study in Chile.

Groundwater (GW) use has intensified in recent decades, threatening the ecological integrity of groundwater-dependent ecosystems (GDEs). The study of GDEs is limited; therefore, integrated, interdisciplinary environmental approaches that guarantee their monitoring and management amid current climate and anthropogenic changes are needed. A new geospatial method with an integrated and temporal approach was developed through a multicriteria approximation, taking into account expert opinion, remote sensing-GIS, and fieldwork to map groundwater-dependent ecosystem zones (GDEZ). A survey of experts (N = 26) was conducted to assign degrees of importance to the various geospatial parameters, and the mapping was carried out using 14 parameters. The reclassified parameters were normalized on a scale of 1 to 5 according to the degree of probability of the presence of GDE. The validation was carried out through fieldwork and statistical analysis. Then, the spatio-temporal changes amid changing GW levels were assessed using the summer season normalized difference vegetation index (NDVI). Two GDEZ maps were obtained, for 2002 and 2017, between which the high- and very-high-probability zones of GDEs decreased by 31,887 ha (~ 38%). The most sensitive temporal parameters that most influenced the spatio-temporal changes on GDEs were precipitation and land use, with rain exerting a slightly the greatest influence. It was also demonstrated that identified ecosystems decreased in area or were affected by aquifer depletion (NDVI-GW, r Pearson ≥0.74). This validated method allows spatio-temporal changes in GDEs to be mapped and analyzed at an annual scale and is transferable to other arid and semi-arid environments.

Hydrological, Environmental and Taxonomical Heterogeneity during the Transition from Drying to Flowing Conditions in a Mediterranean Intermittent River.

Intermittent rivers and ephemeral streams (IRES) are increasingly studied because of their often-unique aquatic and terrestrial biodiversity, biogeochemical processes and associated ecosystem services. This study is the first to examine the hydrological, physicochemical and taxonomic variability during the dry-wet transition of an intermittent river in the Chilean Mediterranean Zone. Based on 30-years of river monitoring data and the TREHS tool, the hydrology of the river was characterised. Overall, the river shows a significant reduction in streamflow (-0.031 m3/s per year) and a substantial increase of zero flow days (+3.5 days per year). During the transition of hydrological states, variations were observed in the environmental conditions and invertebrate communities. During the drying phase, abundance, richness, and diversity were highest, while species turn-over was highest during base flow conditions. The disconnected pools and the flow resumption phases were characterised by high proportions of lentic taxa and non-insects, such as the endemic species of bivalves, gastropods, and crustaceans, highlighting the relevance of disconnected pools as refuges. Future climatic change scenarios are expected to impact further the hydrology of IRES, which could result in the loss of biodiversity. Biomonitoring and conservation programmes should acknowledge these important ecosystems.

Application of the theory of planned behavior with agent-based modeling for sustainable management of vegetative filter strips.

This study proposes an innovative socio-hydrological modeling framework for the development of environmental policies that are tailored to farmers' attitudes and economic interests but also optimize environmental criteria. From a farmers' on-site survey, a behavior model is developed based on a modified Theory of Planned Behavior (TPB). The dynamics of the social and environmental system is implemented by coupling an agent-based model (ABM) with an agro-hydrological model for vegetative filter strips (VFS). A case study is conducted with farmers from the Larqui river basin, Chile to understand their standpoint on VFS to reduce soil loss in their agricultural fields and protect water bodies. Partial least square structural equation modeling is used to analyze the survey on farmers' aspiration and attitudes. It showed that the constructs added to TPB (behavioral morality, behavioral willingness, knowledge) had a significant effect on modeling the intention and behavior of farmers to have VFS. Based on the survey, the farmers were categorized into perceptive, proactive, bounded rational and interactive agents. An ABM was developed using the behavioral categorization, related decision rules, and utility functions of agricultural activities including the VFS implementation and management. The results of the ABM corroborate with the survey of the farmers. The survey supports the view that the decision on the width of VFS is not solely dependent on the utility generated and the reduction in soil losses but also on the behavior of farmers. This behavioral sociohydrological modeling framework is capable of supporting policy-makers in developing tailored environmental policies that might improve the acceptance of sustainable agricultural practices by farmers.

Use of environmental isotopes to assess groundwater pollution caused by agricultural activities.

This work applied environmental isotope techniques to validate the results of previous studies on recharge sources in a rural area in central Chile (34.3° S and 71.3° W) and discern the origin of nitrate contamination in wells. Stream water and groundwater samples were taken during three surveys, two during spring snowmelt and one in low-water conditions. Chemical analyses included major cations and anions, isotope analyses included 18O-H2O; 2H-H20; 3H-H20; 18O-NO3 - and 15N-NO3 -. The stable isotope data show that surface water and deep groundwater present depleted isotope values associated with recharge from the Andes Mountains and that shallow groundwater has more enriched isotope values that reflect the contribution of local recharge from rainwater infiltration. Depleted isotope values observed in shallow groundwater show the effect of recirculated river water used for irrigation. These results are consistent with the conceptual groundwater model developed in previous studies. Some wells have nitrate concentrations above the allowable limit for drinking water. The stable nitrogen isotopes indicate that nitrate is associated mainly with urea and ammoniacal fertilizers, and nitrate is attenuated by denitrification. The results of this study are relevant to improving management of groundwater resources used for drinking water.

Understanding agricultural water footprint variability to improve water management in Chile.

Understanding water consumption is crucial for sustainable management of water resources. Under climate change scenarios that project highly variable water availability, the need for public policies that assure efficiency and equity in water resources is increasing. This work analyzes the case of the Cachapoal River agricultural basin (34°S 71°W), which presents temperature increases and a precipitation deficit, with a drought period that began more than eleven years ago having significantly decreased water availability. Water consumption in the basin for food production was determined from the agricultural water footprint (WFagricultural), using the green (WFgreen), blue (WFblue) and gray water footprint (WFgray) indicators, which were measured in the upper, middle and lower basin under conditions of climate variability (dry, wet and normal years). The greatest WFagricultural was established in the dry year, with a total of 18,221 m3 t-1, followed by 15,902 m3 t-1 in the wet year and 14,091 m3 t-1 in the normal year. Likewise, the greatest WFblue and WFgray, of 12,000 m3 t-1 and 4934 m3 t-1, respectively, were also observed in the dry year. The greatest WFgreen, 2000 m3 t-1, was calculated for a normal year. The 63% of agricultural area of the basin was covered by avocado (Persea americana), olive (Olea europaea), corn (Zea mays) and grape (Vitis sp) crops, which presented the greatest WFagricultural. This water footprint data provides a quantitative basis for the assessment of water consumption and degradation, considering agricultural production and its multiple variables. The success of the application of these results lies in the use of indicators to understand change processes and complement future water allocation plans with more rational water management models.

A new method to evaluate the vulnerability of watersheds facing several stressors: A case study in mediterranean Chile.

Freshwater systems are subjected to multiple anthropogenic stressors and natural disturbances that act as debilitating agents and modifiers of river systems, causing cumulative and synergistic effects that deteriorate their health and result in watershed vulnerability. This study proposes an easy-to-apply spatial method of watershed vulnerability evaluation using Geographic Information Systems (GIS) in the Andalién River watershed, located in the Chilean mediterranean. A watershed vulnerability index (WVI) based on three sub-indices - anthropogenic stressors, environmental fragility and natural disturbances - was developed. To determine the index grouping weights, expert surveys were carried out using the Delphi method. We subsequently normalized and integrated the factors of each sub-index with relative weights. The ranges of each thematic layer were re-classified to establish vulnerability scores. The watershed was divided into three sections: headwaters zone, transfer zone and depositional zone. The watershed vulnerability index showed that 41% of the watershed had very low vulnerability and 42% had medium vulnerability, while only 1% - in the depositional zone - had high vulnerability. A one-way ANOVA was carried out to analyze the vulnerability differences among the three sections of the watershed; it showed significant differences (F (2, 16) = 8.15: p < 0.05). The a posteriori test showed differences between the headwaters and depositional zones (Tukey test, p = 0.005) and between the transfer and depositional zones (Tukey test, p = 0.014). To validate the WVI, water quality was measured at 16 stations in the watershed; there was a significant correlation between vulnerability level and NO2- levels (r = 0.8; p = 0.87; α = 0.05) and pH (r = 0.8; p = 0.80; α = 0.05). The WVI showed the cumulative effects of multiple stressors in the depositional zone of the watershed. This is the first study to evaluate and validate non-regulated watershed vulnerability with GIS using multiple anthropogenic and natural stressors.

Fuzzy-based assessment of groundwater intrinsic vulnerability of a volcanic aquifer in the Chilean Andean Valley.

A fuzzy logic approach has been proposed to face the uncertainty caused by sparse data in the assessment of the intrinsic vulnerability of a groundwater system with parametric methods in Las Trancas Valley, Andean Mountain, south-central Chile, a popular touristic place in Chile, but lacking of a centralized drinking and sewage water public systems; this situation is a potentially source of groundwater pollution. Based on DRASTIC, GOD, and EKv and the expert knowledge of the study area, the Mamdani fuzzy approach was generated and the spatial data were processed by ArcGIS. The groundwater system exhibited areas with high, medium, and low intrinsic vulnerability indices. The fuzzy approach results were compared with traditional methods results, which, in general, have shown a good spatial agreement even though significant changes were also identified in the spatial distribution of the indices. The Mamdani logic approach has shown to be a useful and practical tool to assess the intrinsic vulnerability of an aquifer under sparse data conditions.

Unravel biophysical factors on river water quality response in Chilean Central-Southern watersheds.

Identifying the key anthropogenic (land uses) and natural (topography and climate) biophysical drivers affecting river water quality is essential for efficient management of water resources. We tested the hypothesis that water quality can be predicted by different biophysical factors. Multivariate statistics based on a geographical information system (GIS) were used to explore the influence of factors (i.e., precipitation, topography, and land uses) on water quality (i.e., nitrate (NO 3 (-)), phosphate (PO 4 (3-)), silicate (Si(OH)4), dissolved oxygen (DO), suspended solids (TSS), biological oxygen demand (DO), temperature (T), conductivity (EC), and pH) for two consecutive years in the Itata and Biobío river watersheds, Central Chile (36° 00' and 38° 30'). The results showed that (NO 3 (-)), (PO 4 (3-)), Si(OH)4, TSS, EC, and DO were higher during rainy season (austral fall, winter, and spring), whereas BOD and temperature were higher during dry season. The spatial variation of these parameters in both watersheds was related to land use, topography (e.g., soil moisture, soil hydrological group, and erodability), and precipitation. Soil hydrological group and soil moisture were the strongest explanatory predictors for PO 4 (3-) , Si(OH)4 and EC in the river, followed by land use such as agriculture for NO 3 (-) and DO and silviculture for TSS and Si(OH)4. High-resolution water leaching and runoff maps allowed us to identify agriculture areas with major probability of water leaching and higher probability of runoff in silviculture areas. Moreover, redundancy analysis (RDA) revealed that land uses (agriculture and silviculture) explained in 60 % the river water quality variation. Our finding highlights the vulnerability of Chilean river waters to different biophysical drivers, rather than climate conditions alone, which is amplified by human-induced degradation.

A methodology to identify representative configurations of sensors for monitoring soil moisture.

Soil moisture is the key link among hydroecological compartments, responding dynamically to sequences of atmospheric processes and management conditions and modulating physical, chemical, and biological processes in the soil. Currently, there are a variety of monitoring techniques to measure, directly or indirectly, the soil moisture. However, some practical issues remain open like the definition a priori of the number, location and depth of the monitoring points, and the impact of failing or poor performance soil moisture sensors. Here, we present a set of techniques, namely Δθ time series, wavelet filtering, and time stability, to identify representative points and monitoring depths through an analysis of hourly soil moisture time series for different configuration of the monitoring network. We used real data from a monitoring network consisting of seven monitoring points, each one with four EC-5 probes (Decagon Devices Inc., Pullman, WA) at 20, 40, 60, and 100 cm. The use of simple time series of Δθ allowed us to assess the spatiotemporal influence of the monitoring points, while the wavelet periodograms allowed us to get insight about the response of the monitoring points at different time scales. Both methods are easy to implement or adapt to specific conditions, being coherent to the results derived from time stability analysis. For our case study, we concluded that we could reallocate 16 sensors (out of 28) without a significant loss of information. However, the final decision strongly relies on a deep knowledge of the site features and the objectives of the monitoring network.

A simple method to identify areas of environmental risk due to manure application.

The management of swine manure is becoming an important environmental issue in Chile. One option for the final disposal of manure is to use it as a biofertilizer, but this practice could impact the surrounding environment. To assess the potential environmental impacts of the use of swine manure as a biofertilizer, we propose a method to identify zones of environmental risk through indices. The method considers two processes: nutrient runoff and solute leaching, and uses available information about soils, crops and management practices (irrigation, fertilization, and rotation). We applied the method to qualitatively assess the environmental risk associated with the use of swine manure as a biofertilizer in an 8,000-pig farm located in Central Chile. Results showed that the farm has a moderate environmental risk, but some specific locations have high environmental risks, especially those associated with impacts on areas surrounding water resources. This information could assist the definition of better farm-level management practices, as well as the preservation of riparian vegetation acting as buffer strips. The main advantage of our approach is that it combines qualitative and quantitative information, including particular situations or field features based on expert knowledge. The method is flexible, simple, and can be easily extended or adapted to other processes.

Evaluación del riesgo de contaminación con nitrato de pozos de suministro de agua potable rural en Chile / Risk analysis of nitrate contamination in wells supplying drinking water in a rural area of Chile

OBJETIVOS: Evaluar el riesgo asociado a la contaminación con nitrato de pozos noria de suministro de agua potable rural en la zona de Parral, Chile. MÉTODOS: Se recogieron datos de concentración de nitrato obtenidos de un muestreo de agua de 94 pozos noria. Se analizó la distribución de la concentración de nitrato en los pozos para determinar la existencia de algún tipo de correlación espacial. En el análisis de riesgo, se identificaron dos situaciones de exposición de la población (adultos y lactantes) y se elaboraron mapas de riesgo para la salud. RESULTADOS: El 14 por ciento de los pozos estudiados presentó valores de concentración de nitrato mayores que los permitidos por la normativa nacional relativa al agua potable. No se detectó correlación espacial de las concentraciones de nitrato. El valor medio del cociente de peligro (CP) para los adultos en la zona de estudio fue 0,12, lo que indica la ausencia de riesgo para la salud de esa población. Para los lactantes, el cociente de peligro medio fue 0,69, pero se identificaron algunos pozos donde el cociente de peligro indica un riesgo para esta población. CONCLUSIONES: En la zona de Parral, la contaminación de pozos noria por nitrato está asociada principalmente a la existencia de ciertos factores, como los métodos constructivos o la cercanía de animales, que afectan de manera aislada la calidad del agua. No se detectó la existencia de riesgo para la población adulta, pero sí para los lactantes alimentados con fórmulas preparadas con agua proveniente de los pozos contaminados.

OBJECTIVES: To assess the risk associated with nitrate contamination of wells that supply drinking water in the rural, Parral region of central Chile. METHODS: The nitrate concentration levels were determined using water samples from 94 wells. An analysis of the distribution of nitrate concentration levels was performed in order to assess possible geographic correlations. For the risk analysis, two exposure situations were identified among the population (for adults and for infants), and the health risks were mapped. RESULTS: Fourteen percent of the wells studied had nitrate concentration levels greater than what the Chilean health standards allow for drinking water. There was no geographic correlation for the nitrate concentration levels. The mean hazard quotient (HQ) for adults in the study area was 0.12, indicating an absence of risk for this population group. For infants, the HQ values had a maximum value of 3.1 in some locations, but the average was 0.69 (still below 1.0), indicating that the well water in the study area was generally not hazardous for infants. CONCLUSIONS: In the Parral region of Chile, nitrate contamination of wells is primarily linked to certain factors such as construction practices and the proximity of livestock. These factors affect the quality of drinking water in isolated cases. There was no risk found for the adult population, but there was for infants fed on formula mixed with water coming from the contaminated wells.

[Risk analysis of nitrate contamination in wells supplying drinking water in a rural area of Chile]. / Evaluación del riesgo de contaminación con nitrato de pozos de suministro de agua potable rural en Chile.

OBJECTIVES: To assess the risk associated with nitrate contamination of wells that supply drinking water in the rural, Parral region of central Chile. METHODS: The nitrate concentration levels were determined using water samples from 94 wells. An analysis of the distribution of nitrate concentration levels was performed in order to assess possible geographic correlations. For the risk analysis, two exposure situations were identified among the population (for adults and for infants), and the health risks were mapped. RESULTS: Fourteen percent of the wells studied had nitrate concentration levels greater than what the Chilean health standards allow for drinking water. There was no geographic correlation for the nitrate concentration levels. The mean hazard quotient (HQ) for adults in the study area was 0.12, indicating an absence of risk for this population group. For infants, the HQ values had a maximum value of 3.1 in some locations, but the average was 0.69 (still below 1.0), indicating that the well water in the study area was generally not hazardous for infants. CONCLUSIONS: In the Parral region of Chile, nitrate contamination of wells is primarily linked to certain factors such as construction practices and the proximity of livestock. These factors affect the quality of drinking water in isolated cases. There was no risk found for the adult population, but there was for infants fed on formula mixed with water coming from the contaminated wells.