Palladium nanoparticles supported on a nickel pyrazolate metal organic framework as a catalyst for Suzuki and carbonylative Suzuki couplings.

Methanolic reduction of [PdCl2(CH3CN)2] on a [Ni(2,5-di(1H-pyrazol-4-yl)benzenesulfonate)2] metal organic framework gives rise to Pd(2+)/Pd(0) nanocomposites with Suzuki and carbonylative Suzuki heterogeneous catalytic activities.

A vanadium(IV) pyrazolate metal-organic polyhedron with permanent porosity and adsorption selectivity.

A vanadium(IV) pyrazolate-based open metal-organic polyhedron of [V3(µ3-O)O(OH)2(µ4-BPD)1.5(µ-HCOO)3] (BDP = benzene-1,4-bipyrazolate) formulation gives rise to a porous crystal structure exhibiting micro and mesoporosity which is useful for selective adsorption of gases.