Coastal groundwater salinization: Focus on the vertical variability in a multi-layered aquifer through a multi-isotope fingerprinting (Roussillon Basin, France).

The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place. The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000µS·cm(-1). The δ(2)H-δ(18)O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using (3)H, (14)C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers (87)Sr/(86)Sr ratios are close to that of seawater and then increase with depth, reflecting water-rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water-rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation. Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.

Analytical solution for modeling discharge into a tunnel drilled in a heterogeneous unconfined aquifer.

Predicting transient inflow rates into a tunnel is an important issue faced by hydrogeologists. Most existing analytical solutions overestimate the initial discharge due to the assumption that drilling was instantaneous over the entire tunnel length. In addition, they assume a homogeneous system. An alternative model was recently developed for tunnels intersecting heterogeneous formations, but its application was reduced to the case of confined flow to deep tunnels in weakly diffusive aquifers. In this paper, we adapt existing analytical solutions for drainage systems to the specific case of a tunnel progressively drilled in a highly diffusive heterogeneous unconfined aquifer. The case of a tunnel overlying an impervious layer is analytically solved by applying the superposition principle, while the case of a tunnel constructed some distance above an impervious layer is solved by discretizing the tunnel length into subsectors. Both models can simulate transient discharge into a tunnel drilled at various speeds through a heterogeneous unconfined aquifer, and allow the prediction of discharge rates in shallow tunnels located in highly diffusive aquifers. We successfully applied this approach to a tunnel in heterogeneous volcanic rock.