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1.
Odontostomatol Trop ; 39(154): 38-48, 2016 06.
Artigo em Francês | MEDLINE | ID: mdl-30234273

RESUMO

This paper relates, through a clinical case, the different steps of the prosthodontic rehabilitation of a palate-pharyngeal cleft, sequelae to surgery, by performing a Suersen's Velar obturator since the soft Palate is divided but toned. A functional reeducation in conjunction with a prosthodontic care improves the quality of life's patients and help for their resocialization. This therapeutic is non-invasive, quick, efficient and evolutive method.


Assuntos
Fissura Palatina/reabilitação , Obturadores Palatinos , Prostodontia/métodos , Humanos , Qualidade de Vida , Adulto Jovem
2.
J Oleo Sci ; 64(2): 143-51, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-25748374

RESUMO

Trimethylolpropane triesters are biodegradable synthetic lubricant base oil alternative to mineral oils, polyalphaolefins and diesters. These oils can be produced from trimethylolpropane (TMP) and fatty acid methyl esters via chemical or enzymatic catalyzed synthesis methods. In the present study, a commercial palm oil derived winter grade biodiesel (ME18) was evaluated as a viable and sustainable methyl ester source for the synthesis of high oleic trimethylolpropane triesters (HO-TMPTE). ME18 has fatty acid profile containing 86.8% oleic acid, 8.7% linoleic acid with the remaining minor concentration of palmitic acid, stearic acid and linolenic acid. It's high oleic property makes it superior to produce synthetic lubricant base oil that fulfills both the good low temperature property as well as good oxidative stability. The synthetic base oil produced had a viscosity of 44.3 mm(2)/s at 40°C meeting the needs for ISO 46 oils. It also exhibited an excellent viscosity index of 219 that is higher than some other commercial brands of trimethylolpropane trioleate. Properties of base oil such as cloud point, density, acid value, demulsibility and soap content were also examined. The oil was then used in the formulation of tapping oil and appraised in term of adaptability, stability and field test performance.


Assuntos
Ésteres/síntese química , Lubrificantes/síntese química , Metalurgia , Óleos de Plantas/química , Propilenoglicóis/química , Biocombustíveis , Catálise , Fenômenos Químicos , Indústrias , Ácido Linoleico/química , Ácido Oleico/química , Óleo de Palmeira
3.
ScientificWorldJournal ; 2013: 268385, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-24363616

RESUMO

Many kinetics studies on methanolysis assumed the reactions to be irreversible. The aim of the present work was to study the dynamic modeling of reversible methanolysis of Jatropha curcas oil (JCO) to biodiesel. The experimental data were collected under the optimal reaction conditions: molar ratio of methanol to JCO at 6 : 1, reaction temperature of 60°C, 60 min of reaction time, and 1% w/w of catalyst concentration. The dynamic modeling involved the derivation of differential equations for rates of three stepwise reactions. The simulation study was then performed on the resulting equations using MATLAB. The newly developed reversible models were fitted with various rate constants and compared with the experimental data for fitting purposes. In addition, analysis of variance was done statistically to evaluate the adequacy and quality of model parameters. The kinetics study revealed that the reverse reactions were significantly slower than forward reactions. The activation energies ranged from 6.5 to 44.4 KJ mol⁻¹.


Assuntos
Biocombustíveis , Jatropha/química , Metanol/química , Modelos Químicos , Óleos de Plantas/química
4.
Kyobu Geka ; 59(12): 1075-8, 2006 Nov.
Artigo em Japonês | MEDLINE | ID: mdl-17094543

RESUMO

From April 2002 to March 2005, 18 patients having undergone bidirectional Glenn shunt (BDG) without cardiopulmonary bypass (CPB) [off-pump BDG] were retrospectively reviewed. During BDG anastomosis, a temporary bypass was established between superior vena cava (15) or innominate vein (3) and main pulmonary artery (16) or right atrium (2). Hemodynamics and oxygenation were maintained well throughout the temporary bypass time. There was no emergent use of CPB. Mean transpulmonary pressure gradient immediately after and 24 hours after the BDG were 6.7 and 5.6 mmHg, respectively. Echocardiography showed mild flow turbulence at the anastomosis in 1 case. This simple and inexpensive technique provided good surgical view with stable hemodynamics enabling satisfactory BDG in selected cases. Furthermore, it could avoid adverse effects of CPB such as lung injury and possible blood transfusion. This experience would encourage off-pump BDG combined with more challenging procedures.


Assuntos
Procedimentos Cirúrgicos Cardíacos/métodos , Ponte de Artéria Coronária sem Circulação Extracorpórea , Cardiopatias Congênitas/cirurgia , Artéria Pulmonar/cirurgia , Veia Cava Superior/cirurgia , Anastomose Cirúrgica/métodos , Pressão Sanguínea , Veias Braquiocefálicas/cirurgia , Criança , Pré-Escolar , Feminino , Cardiopatias Congênitas/fisiopatologia , Humanos , Masculino , Estudos Retrospectivos
5.
Trans R Soc Trop Med Hyg ; 99(11): 803-8, 2005 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-16099005

RESUMO

Cutaneous leishmaniasis in Sudan is caused by Leishmania major zymodeme LON1. Self-healing usually occurs within 1 year but occasionally its duration is prolonged and treatment is required. The clinical forms are ulcers, nodules and noduloulcerative lesions. Here we describe seven patients with uncommon lesions that were difficult to recognize as Leishmania infections. These included mycetoma-like lesions, lesions that resembled L. tropica infection and others. One HIV/AIDS patient had Kaposi's sarcoma with Leishmania parasites in the Kaposi lesions. Most of these uncommon clinical forms were difficult to treat. The diagnosis depended on a high degree of suspicion and the demonstration of parasites in smears or culture. PCR was used to characterize parasites from the patients described here. Leishmania major was found by kDNA PCR in all patients, except one, who had a leishmanioma due to L. donovani. In three patients, including one with a L. tropica like-lesion, the parasites were confirmed as L. major by gp63 PCR-RFLP.


Assuntos
Leishmaniose Cutânea/diagnóstico , Adulto , Animais , Antifúngicos/uso terapêutico , Antimônio/uso terapêutico , Criança , Feminino , Humanos , Cetoconazol/uso terapêutico , Leishmaniose Cutânea/tratamento farmacológico , Leishmaniose Cutânea/patologia , Masculino , Reação em Cadeia da Polimerase , Sudão
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