RESUMO
Herein, we successfully fabricated a novel nanostructure based on hierarchical urchin-like FeCo oxide supported carbon spheres (FeCo Oxide/CSs) via a two-step hydrothermal method followed by a simple annealing step at 300 °C under air. It was found that such urchin-like FeCo Oxide/CSs structure exhibited superior catalytic activity towards hydrazine oxidation to CSs, Fe Oxide/CSs, Co Oxide/CSs, and FeCo Hydroxide/CSs material. In this regard, the FeCo Oxide/CSs displayed a wide linear detection range of 0.1-516.6 µM, low detection limit of 0.1 µM, and long-term stability. The material also showed good selectivity towards hydrazine detection in the presence of various interferences, such as uric acid, ascorbic acid, urea, dopamine, Na+, SO42-, K+, and Cl-. The excellent sensing performance of the FeCo Oxide/CSs was assumed to the unique hierarchical urchin structure with the high density and uniformity of nano-sized FeCo Oxide nanoneedles, which produced massive electroactive sites and enhanced charge transfer ability. The achieved results implied that the FeCo Oxide/CSs may be a great candidate for sensitive hydrazine detection.
