1.
Org Lett
; 5(7): 971-4, 2003 Apr 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12659551
RESUMO
[structure: see text] To develop novel consecutive beta- and gamma-turn mimetics, we designed and characterized alpha-aminooxy tripeptides (trimers) consisting of oxanipecotic acid dimer and alpha-aminooxy acid. According to FT-IR and NMR data, as well as ab initio quantum calculations, the trimers adopted unusual folded structures with consecutive beta- and gamma-turnlike conformations.