Stringlet excitation model of the boson peak.

The boson peak (BP), a low-energy excess in the vibrational density of states over the Debye contribution, is often identified as a characteristic of amorphous solid materials. Despite decades of efforts, its microscopic origin still remains a mystery. Recently, it has been proposed, and corroborated with simulations, that the BP might stem from intrinsic localized modes involving one-dimensional (1D) string-like excitations ("stringlets"). We build on a theory originally proposed by Lund that describes the localized modes as 1D vibrating strings, but we specify the stringlet size distribution to be exponential, as observed in simulations. We provide an analytical prediction for the BP frequency ωBP in the temperature regime well below the observed glass transition temperature Tg. The prediction involves no free parameters and accords quantitatively with prior simulation observations in 2D and 3D model glasses based on inverse power law potentials. The comparison of the string model to observations is more uncertain when compared to simulations of an Al-Sm metallic glass material at temperatures well above Tg. Nonetheless, our stringlet model of the BP naturally reproduces the softening of the BP frequency upon heating and offers an analytical explanation for the experimentally observed scaling with the shear modulus in the glass state and changes in this scaling in simulations of glass-forming liquids. Finally, the theoretical analysis highlights the existence of a strong damping for the stringlet modes above Tg, which leads to a large low-frequency contribution to the 3D vibrational density of states, observed in both experiments and simulations.

Engineering Flat Bands in Twisted-Bilayer Graphene away from the Magic Angle with Chiral Optical Cavities.

Twisted bilayer graphene (TBG) is a recently discovered two-dimensional superlattice structure which exhibits strongly correlated quantum many-body physics, including strange metallic behavior and unconventional superconductivity. Most of TBG exotic properties are connected to the emergence of a pair of isolated and topological flat electronic bands at the so-called magic angle, θ≈1.05°, which are nevertheless very fragile. In this work, we show that, by employing chiral optical cavities, the topological flat bands can be stabilized away from the magic angle in an interval of approximately 0.8°<θ<1.3°. As highlighted by a simplified theoretical model, time reversal symmetry breaking (TRSB), induced by the chiral nature of the cavity, plays a fundamental role in flattening the isolated bands and gapping out the rest of the spectrum. Additionally, TRSB suppresses the Berry curvature and induces a topological phase transition, with a gap closing at the Γ point, towards a band structure with two isolated flat bands with Chern number equal to 0. The efficiency of the cavity is discussed as a function of the twisting angle, the light-matter coupling and the optical cavity characteristic frequency. Our results demonstrate the possibility of engineering flat bands in TBG using optical devices, extending the onset of strongly correlated topological electronic phases in moiré superlattices to a wider range in the twisting angle.

Anharmonic theory of superconductivity and its applications to emerging quantum materials.

The role of anharmonicity on superconductivity has often been disregarded in the past. Recently, it has been recognized that anharmonic decoherence could play a fundamental role in determining the superconducting properties (electron-phonon coupling, critical temperature, etc) of a large class of materials, including systems close to structural soft-mode instabilities, amorphous solids and metals under extreme high-pressure conditions. Here, we review recent theoretical progress on the role of anharmonic effects, and in particular certain universal properties of anharmonic damping, on superconductivity. Our focus regards the combination of microscopic-agnostic effective theories for bosonic mediators with the well-established BCS theory and Migdal-Eliashberg theory for superconductivity. We discuss in detail the theoretical frameworks, their possible implementation within first-principles methods, and the experimental probes for anharmonic decoherence. Finally, we present several concrete applications to emerging quantum materials, including hydrides, ferroelectrics and systems with charge density wave instabilities.

Holographic Dissipative Spacetime Supersolids.

Driving a system out of equilibrium enriches the paradigm of spontaneous symmetry breaking, which could then take place not only in space but also in time. The interplay between temporal and spatial symmetries, as well as symmetries from other internal degrees of freedom, can give rise to novel nonequilibrium phases of matter. In this Letter, we investigate a driven-dissipative superfluid model using holographic methods and reveal the existence of a spacetime supersolid (STS) phase that concomitantly breaks the time translation, spatial translation, and the internal U(1) symmetry. The holographic methods naturally include finite temperature effects, which enables us to explore the complex phase diagram of this model and observe a cascade of out-of-equilibrium phase transitions from the STS phase to a synchronized superfluid phase, and finally to a normal fluid phase, by increasing the temperature.

A fresh look at the vibrational and thermodynamic properties of liquids within the soft potential model.

Contrary to the case of solids and gases, where Debye theory and kinetic theory offer a good description for most of the physical properties, a complete theoretical understanding of the vibrational and thermodynamic properties of liquids is still missing. Liquids exhibit a vibrational density of states (VDOS) which does not obey Debye law, and a heat capacity which decreases monotonically with temperature, rather than growing as in solids. Despite many attempts, a simple, complete and widely accepted theoretical framework able to formally derive the aforementioned properties has not been found yet. Here, we revisit one of the theoretical proposals, and in particular we re-analyze the properties of liquids within the soft-potential model, originally formulated for glasses. We confirm that, at least at a qualitative level, many characteristic properties of liquids can be rationalized within this model. We discuss the validity of several phenomenological expressions proposed in the literature for the density of unstable modes, and in particular for its temperature and frequency dependence. We discuss the role of negative curvature regions and unstable modes as fundamental ingredients to have a linear in frequency VDOS. Finally, we compute the heat capacity within the soft potential model for liquids and we show that it decreases with temperature, in agreement with experimental and simulation data.

Observation of fast sound in two-dimensional dusty plasma liquids.

Equilibrium molecular dynamics simulations are performed to study two-dimensional (2D) dusty plasma liquids. Based on the stochastic thermal motion of simulated particles, the longitudinal and transverse phonon spectra are calculated, and used to determine the corresponding dispersion relations. From there, the longitudinal and transverse sound speeds of 2D dusty plasma liquids are obtained. It is discovered that, for wavenumbers beyond the hydrodynamic regime, the longitudinal sound speed of a 2D dusty plasma liquid exceeds its adiabatic value, i.e., the so-called fast sound. This phenomenon appears at roughly the same length scale of the cutoff wavenumber for transverse waves, confirming its relation to the emergent solidity of liquids in the nonhydrodynamic regime. Using the thermodynamic and transport coefficients extracted from the previous studies, and relying on the Frenkel theory, the ratio of the longitudinal to the adiabatic sound speeds is derived analytically, providing the optimal conditions for fast sound, which are in quantitative agreement with the current simulation results.

Reply to "Comment on 'Explaining the specific heat of liquids based on instantaneous normal modes'".

We reply to the Comment by Schirmacher et al. [Phys. Rev. E, 106, 066101 (2022)PREHBM2470-004510.1103/PhysRevE.106.066101]. We disagree that the heat capacity of liquids is not a mystery since a widely accepted theoretical derivation based on simple physical assumptions is still missing. We also disagree about the lack of evidence for a linear in frequency scaling of the liquid density of states, which is indeed reported in uncountable simulations and recently also in experiments. We emphasize that our theoretical derivation does not assume any Debye density of states. We agree that such an assumption would be incorrect. Finally, we remark that the Bose-Einstein distribution naturally tends to the Boltzmann distribution in the classical limit, which makes our results valid also for classical liquids. We hope that this scientific exchange will bring more attention to the description of the vibrational density of states and thermodynamics of liquids, which still present many open puzzles.

Possible enhancement of the superconductingTcdue to sharp Kohn-like soft phonon anomalies.

Phonon softening is a ubiquitous phenomenon in condensed matter systems which is often associated with charge density wave (CDW) instabilities and anharmonicity. The interplay between phonon softening, CDW and superconductivity is a topic of intense debate. In this work, the effects of anomalous soft phonon instabilities on superconductivity are studied based on a recently developed theoretical framework that accounts for phonon damping and softening within the Migdal-Eliashberg theory. Model calculations show that the phonon softening in the form of a sharp dip in the phonon dispersion relation, either acoustic or optical (including the case of Kohn-type anomalies typically associated with CDW), can cause a manifold increase of the electron-phonon coupling constantλ. This, under certain conditions, which are consistent with the concept of optimal frequency introduced by Bergmann and Rainer, can produce a large increase of the superconducting transition temperatureTc. In summary, our results suggest the possibility of reaching high-temperature superconductivity by exploiting soft phonon anomalies restricted in momentum space.

Reply to "Comment on 'Deformations, relaxation, and broken symmetries in liquids, solids, and glasses: A unified topological field theory' ".

We reply to the Comment by Bryk et al. [Phys Rev. E 106, 036601 (2022)10.1103/PhysRevE.106.036601] on our paper [Phys. Rev. E 105, 024602 (2022)2470-004510.1103/PhysRevE.105.024602].

Shear Flows in Far-from-Equilibrium Strongly Coupled Fluids.

Although the viscosity of a fluid ranges over several orders of magnitude and is extremely sensitive to microscopic structure and molecular interactions, it has been conjectured that its (opportunely normalized) minimum displays a universal value which is experimentally approached in strongly coupled fluids such as the quark-gluon plasma. At the same time, recent findings suggest that hydrodynamics could serve as a universal attractor even when the deformation gradients are large and that dissipative transport coefficients, such as viscosity, could still display a universal behavior far from equilibrium. Motivated by these observations, we consider the real-time dissipative dynamics of several holographic models under large shear deformations. In all the cases considered, we observe that at late time both the viscosity-entropy density ratio and the dimensionless ratio between energy density and entropy density approach a constant value. Whenever the shear rate in units of the energy density is small at late time, these values coincide with the expectations from near equilibrium hydrodynamics. Surprisingly, even when this is not the case, and the system at late time is far from equilibrium, the viscosity-to-entropy ratio approaches a constant which decreases monotonically with the dimensionless shear rate and can be parametrically smaller than the hydrodynamic result.

Nonlinear elasticity, yielding, and entropy in amorphous solids.

The holographic duality has proven successful in linking seemingly unrelated problems in physics. Recently, intriguing correspondences between the physics of soft matter and gravity are emerging, including strong similarities between the rheology of amorphous solids, effective field theories for elasticity, and the physics of black holes. However, direct comparisons between theoretical predictions and experimental/simulation observations remain limited. Here, we study the effects of nonlinear elasticity on the mechanical and thermodynamic properties of amorphous materials responding to shear, using effective field and gravitational theories. The predicted correlations among the nonlinear elastic exponent, the yielding strain/stress, and the entropy change due to shear are supported qualitatively by simulations of granular matter models. Our approach opens a path toward understanding the complex mechanical responses of amorphous solids, such as mixed effects of shear softening and shear hardening, and offers the possibility to study the rheology of solid states and black holes in a unified framework.

The ω3 scaling of the vibrational density of states in quasi-2D nanoconfined solids.

The vibrational properties of crystalline bulk materials are well described by Debye theory, which successfully predicts the quadratic ω2 low-frequency scaling of the vibrational density of states. However, the analogous framework for nanoconfined materials with fewer degrees of freedom has been far less well explored. Using inelastic neutron scattering, we characterize the vibrational density of states of amorphous ice confined inside graphene oxide membranes and we observe a crossover from the Debye ω2 scaling to an anomalous ω3 behaviour upon reducing the confinement size L. Additionally, using molecular dynamics simulations, we confirm the experimental findings and prove that such a scaling appears in both crystalline and amorphous solids under slab-confinement. We theoretically demonstrate that this low-frequency ω3 law results from the geometric constraints on the momentum phase space induced by confinement along one spatial direction. Finally, we predict that the Debye scaling reappears at a characteristic frequency ω× = vL/2π, with v the speed of sound of the material, and we confirm this quantitative estimate with simulations.

Deformations, relaxation, and broken symmetries in liquids, solids, and glasses: A unified topological field theory.

We combine hydrodynamic and field theoretic methods to develop a general theory of phonons as Goldstone bosons in crystals, glasses, and liquids based on nonaffine displacements and the consequent Goldstone phase relaxation. We relate the conservation, or lack thereof, of specific higher-form currents with properties of the underlying deformation field-nonaffinity-which dictates how molecules move under an applied stress or deformation. In particular, the single-valuedness of the deformation field is associated with conservation of higher-form charges that count the number of topological defects. Our formalism predicts, from first principles, the presence of propagating shear waves above a critical wave vector in liquids, thus giving a formal derivation of the phenomenon in terms of fundamental symmetries. The same picture provides also a theoretical explanation of the corresponding "positive sound dispersion" phenomenon for longitudinal sound. Importantly, accordingly to our theory, the main collective relaxation timescale of a liquid or a glass (known as the α relaxation for the latter) is given by the phase relaxation time, which is not necessarily related to the Maxwell time. Finally, we build a nonequilibrium effective action using the in-in formalism defined on the Schwinger-Keldysh contour, that further supports the emerging picture. In summary, our work suggests that the fundamental difference between solids, fluids, and glasses has to be identified with the associated generalized higher-form global symmetries and their topological structure, and that the Burgers vector for the displacement fields serves as a suitable topological order parameter distinguishing the solid (ordered) phase and the amorphous ones (fluids, glasses).

Explaining the specific heat of liquids based on instantaneous normal modes.

The successful prediction of the specific heat of solids is a milestone in the kinetic theory of matter due to Debye. No such success, however, has ever been obtained for the specific heat of liquids, which has remained a mystery for over a century. A theory of specific heat of liquids is derived here using a recently proposed analytical form of the vibrational density of states of liquids, which takes into account saddle points in the liquid energy landscape via the so-called instantaneous normal modes (INMs), corresponding to negative eigenvalues (imaginary frequencies) of the Hessian matrix. The theory is able to explain the typical monotonic decrease in specific heat with temperature observed in liquids in terms of the average INM excitation lifetime decreasing with T (in accordance with the Arrehnius law) and provides an excellent single-parameter fitting to several sets of experimental data for atomic and molecular liquids. It also correlates the height of the liquid energy barrier with the slope of the specific heat in the function of temperature in accordance with the available data. These findings demonstrate that the specific heat of liquids is controlled by the instantaneous normal modes, i.e., by localized unstable (exponentially decaying) vibrational excitations and provide the missing connection among anharmonicity, saddle points in the energy landscape, and the thermodynamics of liquids.

Plasticity in Amorphous Solids Is Mediated by Topological Defects in the Displacement Field.

The microscopic mechanism by which amorphous solids yield plastically under an externally applied stress or deformation has remained elusive in spite of enormous research activity in recent years. Most approaches have attempted to identify atomic-scale structural "defects" or spatiotemporal correlations in the undeformed glass that may trigger plastic instability. In contrast, in this Letter we show that the topological defects that correlate with plastic instability can be identified, not in the static structure of the glass, but rather in the nonaffine displacement field under deformation. These dislocation-like topological defects (DTDs) can be quantitatively characterized in terms of Burgers circuits (and the resulting Burgers vectors) that are constructed on the microscopic nonaffine displacement field. We demonstrate that (i) DTDs are the manifestation of incompatibility of deformation in glasses as a result of violation of Cauchy-Born rules (nonaffinity); (ii) the resulting average Burgers vector displays peaks in correspondence of major plastic events, including a spectacular nonlocal peak at the yielding transition, which results from self-organization into shear bands due to the attractive interaction between antiparallel DTDs; and (iii) application of Schmid's law to the DTDs leads to prediction of shear bands at 45° for uniaxial deformations, as widely observed in experiments and simulations.

Anomalous diffusion and Noether's second theorem.

Despite the fact that conserved currents have dimensions that are determined solely by dimensional analysis (and hence no anomalous dimensions), Nature abounds in examples of anomalous diffusion in which L∝t^{γ}, with γ≠1/2, and heat transport in which the thermal conductivity diverges as L^{α}. Aside from breaking of Lorentz invariance, the true common link in such problems is an anomalous dimension for the underlying conserved current, thereby violating the basic tenet of field theory. We show here that the phenomenological nonlocal equations of motion that are used to describe such anomalies all follow from Lorentz-violating gauge transformations arising from Noether's second theorem. The generalizations lead to a family of diffusion and heat transport equations that systematize how nonlocal gauge transformations generate more general forms of Fick's and Fourier's laws for diffusive and heat transport, respectively. In particular, the associated Goldstone modes of the form ω∝k^{α}, α∈R are direct consequences of fractional equations of motion.

Universal law for the vibrational density of states of liquids.

An analytical derivation of the vibrational density of states (DOS) of liquids, and, in particular, of its characteristic linear in frequency low-energy regime, has always been elusive because of the presence of an infinite set of purely imaginary modes-the instantaneous normal modes (INMs). By combining an analytic continuation of the Plemelj identity to the complex plane with the overdamped dynamics of the INMs, we derive a closed-form analytic expression for the low-frequency DOS of liquids. The obtained result explains, from first principles, the widely observed linear in frequency term of the DOS in liquids, whose slope appears to increase with the average lifetime of the INMs. The analytic results are robustly confirmed by fitting simulations data for Lennard-Jones liquids, and they also recover the Arrhenius law for the average relaxation time of the INMs, as expected.

Physics of phonon-polaritons in amorphous materials.

The nature of bosonic excitations in disordered materials has remained elusive due to the difficulties in defining key concepts such as quasi-particles in the presence of disorder. We report on an experimental observation of phonon-polaritons in glasses, including a prominent boson peak (BP), i.e., excess of THz modes over the Debye law. A theoretical framework based on the concept of diffusons is developed to describe the broadening linewidth of the polariton due to disorder-induced scattering. It is shown here for the first time that the BP frequency and the Ioffe-Regel (IR) crossover frequency of the polariton collapse onto the same power-law decay with the diffusivity of the bosonic excitation. This analysis dismisses the hypothesis of the BP being caused by a relic of the van Hove singularity. The presented framework establishes a new methodology to analyze bosonic excitations in amorphous media, well beyond the traditional case of acoustic phonons, and establishes the IR crossover as the fundamental physical mechanism behind the BP.