Early steps in layer-by-layer construction of polyelectrolyte films: the transition from surface/polymer to polymer/polymer determining interactions.

The layer-by-layer deposition of two polyelectrolytes, quaternized poly(dimethylaminoethyl methacrylate chloride) (MADQUAT) and poly(acrylic acid) (PAA) on a silica substrate was investigated using optical reflectometry, as a function of pH (pH 4, 5.5 and 9), ionic strength (10(-3) to 10(-1) M) and type of salt. Attention was given to the successive deposited weights and to the corresponding deposited charge densities within the ten first deposited layers. Results show a change of growth regime between an early stage where the substrate had a dominating influence in the build-up and a second stage where the polymer uptake was ruled essentially by polymer-polymer interactions. The pH was seen to influence the growth via the charge densities of silica (first stage) and PAA (first and second stages). The increase of NaCl concentration induced an increase of the film weight between 10(-3) and 10(-2) M, but the trend was more sophisticated between 10(-2) and 10(-1) M where the polymer uptake increased in the first stage of the growth and decreased in subsequent layers. The film weight increased in accordance with the rank of ions in the Hofmeister series. AFM images revealed a heterogeneous film morphology with bumps and valleys, which was explained by a growth mechanism made of the successive formation and growth of polymer complexes.

Smallest lithographic marks generated by optical focusing systems.

We show that the combination of Bessel beams and photosensitive materials exhibiting polarization filtering properties allows one to reach the smallest mark that can be lithographically generated by focusing systems. This property is of interest in current optical data storage techniques.

Shaping the reflection near-field optical probe: finite domain time difference modelling and fabrication using a focused ion beam.

An optical fibre ending in a trihedral tip is proposed as a convenient probe for reflection near-field optical microscopy in emission/collection mode. Its shape is obtained by ion milling. A first example of manufacturing and numerical models using the bi-dimensional FDTD method is presented. It confirms the strong influence of the facet angle on the intensity reflected by the probe, which is predicted by a rough analysis. This method can help us to optimize the 'reflection probe' by reducing this offset signal.

Analysis of optical near-field images by Karhunen-Loève transformation.

With regard to classical image transformations, the Karhunen-Loève transform is based on the statistical analysis of signal or image data. We propose using it to analyze and recognize the content of images generated in near-field microscopy. It is shown that such a transform is an efficient tool for separating actual information from noise without reducing the spatial-frequency band.