Photoinduced large polaron transport and dynamics in organic-inorganic hybrid lead halide perovskite with terahertz probes.

Organic-inorganic hybrid metal halide perovskites (MHPs) have attracted tremendous attention for optoelectronic applications. The long photocarrier lifetime and moderate carrier mobility have been proposed as results of the large polaron formation in MHPs. However, it is challenging to measure the effective mass and carrier scattering parameters of the photogenerated large polarons in the ultrafast carrier recombination dynamics. Here, we show, in a one-step spectroscopic method, that the optical-pump and terahertz-electromagnetic probe (OPTP) technique allows us to access the nature of interplay of photoexcited unbound charge carriers and optical phonons in polycrystalline CH3NH3PbI3 (MAPbI3) of about 10 µm grain size. Firstly, we demonstrate a direct spectral evidence of the large polarons in polycrystalline MAPbI3. Using the Drude-Smith-Lorentz model along with the FrÓ§hlich-type electron-phonon (e-ph) coupling, we determine the effective mass and scattering parameters of photogenerated polaronic carriers. We discover that the resulting moderate polaronic carrier mobility is mainly influenced by the enhanced carrier scattering, rather than the polaron mass enhancement. While, the formation of large polarons in MAPbI3 polycrystalline grains results in a long charge carrier lifetime at room temperature. Our results provide crucial information about the photo-physics of MAPbI3 and are indispensable for optoelectronic device development with better performance.

Measuring heavy metal ions in water using nature existed microalgae as medium based on terahertz technology.

Heavy metal pollution in water seriously affects human health. The disadvantages of traditional metal ion detection methods involve long and cumbersome chemical pretreatment in the early stage, and large volume of samples. In this study, microalgae were used as the medium, and terahertz spectroscopy technology was employed to collect the changes of material components in it, so as to deduce the types and concentrations of heavy metal pollution in water. Through the partial least square(PLS), we establish the prediction model of heavy metal concentration, and the results show that the best detection time for Pb2+ is 6 h and Ni2+ is 18 h. The principal component analysis(PCA) shows that ß-carotene is the most affected substance. Afterward we collect five real surface waters in East China and verify that the judgment accuracy of Pb2+ and Ni2+ are 100% and 93.2% respectively. The results indicate that the time is shorter than the traditional pretreatment time from more than 20-6 h, the sample volume is reduced from 50 mL to 10 mL, the detection accuracy is improved from 10 ng/mL to 1 ng/mL. In a word, we provide a new fast and real-time method for biological monitoring of heavy metal pollution in water.

Excitation of graphene surface plasmons polaritons by guided-mode resonances with high efficiency.

An Otto-like configuration for the excitation of graphene surface plasmon polaritons (GSPPs) is proposed. The configuration is composed of a metallic grating-dielectric-waveguide structure and a monolayer graphene with a subwavelength vacuum gap between them. The evanescent field located at the bottom surface of the dielectric waveguide corresponding to grating-coupled guided-mode resonances (GMRs) is utilized to efficiently excite the highly confined GSPPs. The finite difference time domain method is used to investigate the behaviors of the GMR-GSPP hybrid modes. The dispersion relations of GMRs and GSPPs are calculated and the numerical results further identify the excitation of GMR-GSPP hybrid modes. By changing the gap between the graphene layer and the bottom of the dielectric waveguide and the Fermi energy of graphene, the resonant frequencies of GMR-GSPP hybrid modes can be continuously tuned. When the optimized excitation condition is satisfied, the maximum energy enhancement factor in the gap can reach about 500 at the resonant frequencies. The proposed structure can be used to realize highly sensitive, compatible with planar fabrication technology, and electrically (mechanically) tunable sensors.

Terahertz-frequency temporal differentiator enabled by a high-Q resonator.

Terahertz (THz) fundamental "building blocks" equivalent to those used in multi-functional electronic circuits are very helpful for actual applications in THz data-processing technology and communication. Here, we theoretically and experimentally demonstrate a THz temporal differentiator based on an on-chip high-quality (Q) factor resonator. The resonator is made of low-loss high-resistivity silicon material in a monolithic, integrated platform, which is carefully designed to operate near the critical coupling region. The experiment demonstrates that the device can perform the first-order time derivative of the input signal electric field complex envelope at 214.72 GHz. Our investigation provides an effective approach for terahertz pulse re-shaping and real-time differential computing units.

Metal-graphene hybridized plasmon induced transparency in the terahertz frequencies.

In this work, metal-graphene hybridized plasmon induced transparency (PIT) is systematically studied in the proposed simple metal/dielectric/graphene system. The PIT effect is the result of the coupling between the bright dipolar modes excited in the graphene regions under the shorter metallic bars and the dark quadrupolar modes excited in the graphene regions under the longer metallic bars. The coupled Lorentz oscillator model is used to help explain the physical origin of the PIT effect. Other than being tuned by the distance and the lateral displacement of the orthogonal metallic bars, the coupling efficiency can be further enhanced by the in-phase coupling or quenched by the out-of-phase coupling between the adjacent unit cells. Reduced barrier thickness will result in the enhancement of the coupling strengths and the scaling down of the device. Finally, we show that the PIT window can be actively tuned by changing the Fermi energy of graphene. The proposed structure has potential applications in actively tunable THz modulators, sensors and filters.