RESUMO
We have developed an improved three-dimensional (3D) percolation model to investigate the effect of the alignment of carbon nanotubes (CNTs) on the electrical conductivity of nanocomposites. In this model, both intrinsic and contact resistances are considered, and a new method of resistor network recognition that employs periodically connective paths is developed. This method leads to a reduction in the size effect of the representative cuboid in our Monte Carlo simulations. With this new technique, we were able to effectively analyze the effects of the CNT alignment upon the electrical conductivity of nanocomposites. Our model predicted that the peak value of the conductivity occurs for partially aligned rather than perfectly aligned CNTs. It has also identified the value of the peak and the corresponding alignment for different volume fractions of CNTs. Our model works well for both multi-wall CNTs (MWCNTs) and single-wall CNTs (SWCNTs), and the numerical results show a quantitative agreement with existing experimental observations.
Assuntos
Modelos Químicos , Nanocompostos/química , Nanotubos de Carbono/química , Simulação por Computador , Condutividade Elétrica , Método de Monte Carlo , Reprodutibilidade dos TestesRESUMO
Considering electron-impurity and electron-phonon scattering, we present a balance-equation-based theoretical examination of thermoelectric power (TEP) in a two-dimensional single-layer graphene away from the carrier neutrality point. Both the boundary scattering and phonon-phonon interaction in phonon relaxation processes are taken into account. We find that, at temperatures T > 10 K, the contribution to TEP mainly comes from diffusive processes and the phonon-drag effect can be ignored. However, at T ≤ 10 K, the phonon-phonon interaction leads to a phonon-drag peak in the temperature dependence of TEP. We also compare our results with experiments.
RESUMO
Considering electron-impurity, electron-acoustic-phonon and electron-optical-phonon scatterings, the nonlinear steady-state transport properties of graphene are studied theoretically by means of the balance equation approach. We find that the conductivity as a function of electric field strength, E, exhibits strongly nonlinear behavior for E larger than a critical value, E(c)≈0.1 kV cm(-1). With the increase of E from zero, the conductivity first decreases slowly and then it falls rapidly when E>E(c). The dependence of electron temperature on E is also demonstrated.
RESUMO
AIM: To investigate the influence of Ginkgo biloba extract (GbE) on cardiomyocytes damaged by H2O2. METHODS: Cultured rat cardiomyocytes were divided into 3 groups randomly: control group; H2O2 (2.5 mmol.L-1) group; H2O2 2.5 mmol.L-1 + GbE 150 mg.L-1 group. The cardiomyocytes were cultured in MEM (Eagle's) at 37 degrees C in the presence of 5% CO2 for 4 h. Lactate dehydrogenase (LDH) was assayed by colorimetric method. Lipid peroxidation was determined by measuring thiobarbituric acid-reactive substances. Ultrastructure was viewed under transmission electron microscope. RESULTS: Compared with the control group, LDH leakage and malondialdehyde (MDA) content increased in H2O2 group, LDH increased from (2166 +/- 247) U.L-1 to (5180 +/- 648) U.L-1, MDA increased from (3.5 +/- 0.2) nmol/10(6) cells to (7.2 +/- 0.4) nmol/10(6) cells (P < 0.01). The ultrastructure was damaged seriously. GbE inhibited the increase of LDH leakage and MDA content induced by H2O2. In this group, LDH decreased from (5180 +/- 648) U.L-1 to (3496 +/- 386) U.L-1, MDA decreased from (7.2 +/- 0.4) nmol/10(6) cells to (4.8 +/- 0.9) nmol/10(6) cells (P < 0.01). Ultrastructure of cells was also protected by GbE. CONCLUSION: GbE protected the cardiomyocyte against H2O2 injury, the protective action was attributed to its antiperoxidative effect.