RESUMO
Titania photocatalysts have great potential as remediators of air pollution. Although various aspects of photocatalyst synthesis, adsorption and photoactivity have been investigated, a thorough understanding of the particle surface behavior has not yet been fully realized. In order to learn more about the principles behind the surface behavior, we investigate the Hansen solubility/similarity parameters (HSPs) for analyzing and evaluating three photocatalysts synthesized by the gas phase method, solvothermal reaction and sol-gel method, respectively. A particle size distribution-based categorization scheme is introduced for characterizing each material's Hansen parameters based on its interaction with a list of selected probe liquids. The latter was deduced from particle size distributions assessed by analytical centrifugation. Subsequent comparison of the Hansen parameters of the investigated materials shows how HSPs can potentially be used as a model for predicting the pollutant adsorption behavior on the photocatalyst surface. This serves as a first step in heading towards an improved understanding of the particle behavior and translating it into a knowledge-based design, i.e., synthesis and hybridization of novel photocatalysts.
RESUMO
The removal of kidney stones can lead to small residual fragments remaining in the human body. Residual stone fragments can act as seeds for kidney stone crystallization and may necessitate another intervention. Therefore, it is important to create a consistent model with a particle size comparable to the range of kidney stone fragments. Thus, the size-determining parameters such as supersaturation ratio, energy input, and pH value are examined. The batch crystallizations were performed with supersaturation ratios between 5.07 and 6.12. The compositions of the dried samples were analyzed with Raman spectroscopy, infrared spectroscopy, and X-ray diffraction (XRD). The samples were identified as calcium oxalate monohydrate with spectroscopic analysis, while calcium oxalate dihydrate being the most prominent crystalline species at all supersaturation ratios for the investigated conditions. The aggregate size, obtained with analytical centrifugation, varied between 2.9 and 4.3 µm, while the crystallite domain size, obtained from XRD, varied from 40 to 61 nm. Our results indicate that particle sizes increase with increasing supersaturation, energy input, and pH. All syntheses yield a high particle heterogeneity and represent an ideal basis for reference materials of small kidney stone fragments. These results will help better understand and control the crystallization of calcium oxalate and the aggregation of such pseudopolymorphs.
RESUMO
A thorough understanding of complex interactions within particulate systems is a key for knowledge-based formulations. Hansen solubility parameters (HSP) are widely used to assess the compatibility of the dispersed phase with the continuous phase. At present, the determination of HSP is often based on a liquid ranking list obtained by evaluating a pertinent dispersion parameter using only one pre-selected characterization method. Furthermore, one cannot rule out the possibility of subjective judgment especially for liquids for which it is difficult to decipher the compatibility or underlying interactions. As a result, the end value of HSP might be of little or no information. To overcome these issues, we introduce a generalized and technology-agnostic combinatorics-based procedure. We discuss the principles of the procedure and the implications of evaluating and reporting particle HSP values. We demonstrate the procedure by using SiN x particles synthesized in the gas phase. We leverage the analytical centrifugation data to evaluate stability trajectories of SiN x dispersions in various liquids to deduce particle-liquid compatibility.
