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1.
Perspect Psychiatr Care ; 58(4): 1900-1906, 2022 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-35037249

RESUMO

PURPOSE: This study aimed to determine the relationship between the symptoms of anger and loneliness among women in the menopausal period. DESIGN AND METHODS: A total of 200 women in the menopausal period were interviewed within the scope of this study. Descriptive Information Form, UCLA Loneliness Scale, Trait Anger and Anger Expression Scale and Menopause-Specific Quality of Life Questionnaire were used to collect data. FINDINGS: The mean score of the UCLA Loneliness Scale was found as 53.61 ± 7.68 and it was observed that the participants had high traits of anger and a high-level of loneliness. Loneliness and anger increase when menopausal symptoms increase in women. PRACTICE IMPLICATIONS: Menopause is generally perceived by women as a troublesome period instead of being a normal life process. In order for women to spend this period at a more comfortable and desirable level, it is important to know cultural characteristics, social support systems, coping mechanisms.


Assuntos
Solidão , Qualidade de Vida , Feminino , Humanos , Menopausa , Ira , Inquéritos e Questionários
2.
Chemistry ; 27(30): 8021-8029, 2021 May 26.
Artigo em Inglês | MEDLINE | ID: mdl-33826188

RESUMO

A series of pyrrolyl and dipyrrinyl isoporphyrins carrying different phenyl and thienyl groups is reported. The compounds are obtained by a one-pot approach in the presence of a template reagent. Thienyl derivatives gave better yields, and were the only subclass to form with steric hindrance. The structural analyses carried out on compounds 1 and 14 revealed distinct conformational differences which are likely to result from an intramolecular NH… Cl hydrogen bridge of the pyrrolyl subclass. In addition, this hydrogen bridge strongly favors one of the two possible atropisomers. Hindered rotation of the meso-aryl groups is observed only in the cases of methylbenzothienyl derivatives 10 and 15 and leads to the observation of several diastereomers. NIR absorptions up to 923 nm are found throughout. Electrochemical investigations into the 1e- and 2e- reduced species unravel axial ligand exchange dynamics for the zinc isoporphyrin radical, and the probable formation of a zinc phlorinate.

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