Alginate-based nano-adsorbent materials - Bioinspired solution to mitigate hazardous environmental pollutants.

Population growth and industrialization is associated with the elevation of hazardous pollutants, including heavy metals, biomedical wastes, personal-care products, endocrine-disrupters, pharmaceutically active compounds, and colorants in the environment. The scientific focus has been devoted to developing novel adsorbents to mitigate hazardous pollutants by constructing hybrids of different polymers and nano-structured materials for improved workability and physicochemical attributes. Recently, much attention has been devoted to nanomaterials in environmental remediation, owning to their exceptional characteristics including novel electrical/chemical features, quantum size effects, tunable functionalization, high scalability, and surface-area-to-volume ratio. Target-specific designing of nanocomposites impart high functionality. The cost-effective and eco-friendly synthesis of bioadsorbent materials is increasing for the removal of hazardous pollutants. Due to biocompatible, biodegradable, and eco-friendly nature, sodium alginate has been widely reported for the preparation of bioadsorbent materials to remove different inorganic/organic pollutants. In this review, the potentialities of alginate-based nanocomposites have been described for environmental remediation purposes. Different nanomaterials, including silica, metallic oxide, graphene oxide, hybrid inorganic-organic, non-magnetic-magnetic, carbon nanorods, nanotubes, polymeric nanocarriers, and several other materials have been described in combination with alginate biopolymer for environmental remediation.

Nano-engineered materials for sensing food pollutants: Technological advancements and safety issues.

Food spoilage and safety are key concerns of the modern food sector. Among them, several types of polluting agents are the prime grounds of food deterioration. In this context, nanotechnology-based measures are setting new frontiers to strengthen food applications. Herein, we summarize the nanotechnological dimension of the food industry for both processing and packaging applications. Active bioseparation, smart delivery, nanoencapsulation, nutraceuticals, and nanosensors for biological detection are a few emerging topics of nanobiotechnology in the food sector. The development of functional foods is another milestone set by food nanotechnology by building the link between humans and diet. However, the establishment of optimal intake, product formulations, and delivery matrices, the discovery of beneficial compounds are a few of the key challenges that need to be addressed. Nanotechnology provides effective solutions for the aforementioned problem giving various novel nanomaterials and methodologies. Various nanodelivery systems have been designed, e.g., cochleate, liposomes, multiple emulsions, and polysaccharide-protein coacervates. However, their real applications in food sciences are very limited. This review also provides the status and outlook of nanotechnological systems for future food applications.

Carrageenan-based nano-hybrid materials for the mitigation of hazardous environmental pollutants.

Fast industrialization and population growth are associated with the increased release of hazardous contaminants in the environment. These hazardous substances, including pharmaceutical, biomedical, personal-care products, heavy metals, endocrine-disrupters, and colorants, pollute the ecosystem by disturbing nature's balance. Nanotechnology has paved new horizons in biochemical engineering by designing novel approaches of integrating nanoscale science with biotechnology to construct improved quality materials for target uptake of pollutants. Recently, nanostructured materials have emerged as research and development frontiers owing to their excellent properties. The tailored designing of nanohybrids constructs with physicochemical alteration enables the nano-bioadsorbent with high target specificity and efficiency. The development of eco-friendly, biodegradable, cost-efficient, and biopolymer-based nanohybrid constructs is gaining attention to remove hazardous environmental pollutants. κ-carrageenan biopolymer is frequently used with different nanomaterials to design nanohybrid bio-adsorbents to remove various contaminants. Herein, the potentialities of carrageenan-based nanohybrid constructs in environmental remediation have been summarized. Different nanostructures, e.g., silica, non-magnetic/magnetic, carbon nanotubes/nanorods, nanoclay/nanomembrane, metal organic frameworks, graphene oxide, and other nanomaterials have been described in combination with carrageenan biopolymers focusing on environmental remediation.

Polysaccharides-based bio-nanostructures and their potential food applications.

Polysaccharides are omnipresent biomolecules that hold great potential as promising biomaterials for a myriad of applications in various biotechnological and industrial sectors. The presence of diverse functional groups renders them tailorable functionalities for preparing a multitude of novel bio-nanostructures. Further, they are biocompatible and biodegradable, hence, considered as environmentally friendly biopolymers. Application of nanotechnology in food science has shown many advantages in improving food quality and enhancing its shelf life. Recently, considerable efforts have been made to develop polysaccharide-based nanostructures for possible food applications. Therefore, it is of immense importance to explore literature on polysaccharide-based nanostructures delineating their food application potentialities. Herein, we reviewed the developments in polysaccharide-based bio-nanostructures and highlighted their potential applications in food preservation and bioactive "smart" food packaging. We categorized these bio-nanostructures into polysaccharide-based nanoparticles, nanocapsules, nanocomposites, dendrimeric nanostructures, and metallo-polysaccharide hybrids. This review demonstrates that the polysaccharides are emerging biopolymers, gaining much attention as robust biomaterials with excellent tuneable properties.