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J Phys Chem B ; 128(16): 3824-3832, 2024 Apr 25.
Artigo em Inglês | MEDLINE | ID: mdl-38616737

RESUMO

We study the nontrivial thermodynamic responses of an overdamped Brownian system driven by an unbiased driving force when the particle is confined inside a bilobal irregular structure. The spatial irregularity of the confinement results in an effective entropic bistable potential along the direction of transport. We calculate the thermodynamic response functions in terms of the averaged work done and the absorbed heat over a cycle of driving. We find that the thermodynamic responses are influenced by the nonlinearity of the effective entropic potential, the frequency of the external periodic driving force, and the random thermal fluctuations in a nontrivial way. In the presence of an optimal amount of thermal noise and a favoring driving frequency, the process exhibits a resonance-like precedent in terms of both output work and absorbed heat. We explore the conditions to get best synchronized work extraction (or absorbed heat), which can be utilized as a potential quantifier of an entropic stochastic resonance phenomenon. Finally, we identify a hallmark of entropy dominance over an analogous energy-driven scenario in terms of output work.

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