1.
Org Lett
; 3(5): 723-6, 2001 Mar 08.
Artigo
em Inglês
| MEDLINE
| ID: mdl-11259046
RESUMO
[structure: see text]. C2-symmetric, oxygenated macrocycles have been synthesized from simple acyclic precursors in a single step by a tandem hetero Diels-Alder reaction. Thermolysis and Lewis acid catalysis can effect this novel transformation. The tandem reaction product is formed in preference to the intramolecular cycloaddition product, and an explanation for this result is proposed.