Devonian to Carboniferous continental-scale carbonate turnover in Western Laurentia (North America): upwelling or climate cooling?

The Devonian to Carboniferous (DC) transition coincided with a green-to-ice house climatic shift, anoxia, disappearance of lower latitude carbonate banks, and turnover from warm-to-cool water carbonate factories. In western Laurentia, the switch to carbonate factories dominated by cool-water biota was contemporaneous with a tectonically driven palaeogeographic change. To investigate this depositional shift and infer the relative impact of climate vs tectonics, a continental-scale sedimentological and geochemical study was conducted on twelve stratigraphic sections of DC strata from western Canada to southern Nevada (USA). The spatial-temporal distribution of microfacies records the turnover from [i] a Famennian lime mud-rich, shallow warm-water carbonate ramp with low sedimentation rates, mesotrophic conditions and tabular geometry to [ii] Tournaisian to Viséan lime mud-depleted and grainstone dominated cool-water carbonate ramp with anomalous high sedimentation rates, oligotrophic conditions and a pronounced slope. Positive excursions of δ 18Ocarb (+ 2‰ V-PDB) and δ 13Ccarb (+ 4‰ V-PDB) of Lower Mississippian carbonates likely correspond to the first cooling peak of the Carboniferous-Permian icehouse climate, following carbon withdrawal during black shale deposition during the late Famennian and early Tournaisian. However, late Tournaisian return of photozoan elements and their persistence throughout the Viséan suggests that warmer surface water existed, revealing a decoupling of the lower latitude ocean and the atmosphere. Shoaling of the thermocline was likely a result of cold-water upwelling along an open coast, as the Antler orogen no longer provided an oceanic obstruction to the west. This study shows that carbonate platforms are more susceptible to regional changes than global shifts. Supplementary Information: The online version contains supplementary material available at 10.1007/s10347-022-00653-4.

Nickel isotopes link Siberian Traps aerosol particles to the end-Permian mass extinction.

The end-Permian mass extinction (EPME) was the most severe extinction event in the past 540 million years, and the Siberian Traps large igneous province (STLIP) is widely hypothesized to have been the primary trigger for the environmental catastrophe. The killing mechanisms depend critically on the nature of volatiles ejected during STLIP eruptions, initiating about 300 kyr before the extinction event, because the atmosphere is the primary interface between magmatism and extinction. Here we report Ni isotopes for Permian-Triassic sedimentary rocks from Arctic Canada. The δ60Ni data range from -1.09‰ to 0.35‰, and exhibit the lightest δ60Ni compositions ever reported for sedimentary rocks. Our results provide strong evidence for global dispersion and loading of Ni-rich aerosol particles into the Panthalassic Ocean. Our data demonstrate that environmental degradation had begun well before the extinction event and provide a link between global dispersion of Ni-rich aerosols, ocean chemistry changes, and the EPME.

Sulfuric acid Speleogenesis associated with a glacially driven groundwater system-paleo-spring "pipes" at Borup Fiord Pass, Nunavut.

Gypsum filled "pipe" features were discovered in the proglacial area of the Borup Fiord Pass supraglacial sulfur spring. Stable isotope data suggest that gypsum is formed through oxidation of sulfides and are consistent with models of sulfuric acid speleogenesis. These results suggest that gypsum pipes are paleo-spring discharge channels analogous to those that feed the modern sulfur spring at Borup Fiord. A conceptual model is proposed whereby retreat of the glacial front and associated growth of permafrost in ground exposed now to low arctic temperatures leads to "freezing-in" of the spring system and abandonment of old channels in favor of more open flow systems in the subglacial region. Results provide a model for glacially driven groundwater systems that may form in association with Mars' polar icecaps and potential geological signatures for paleo-groundwater discharge.

Supraglacial sulfur springs and associated biological activity in the Canadian high arctic-signs of life beneath the ice.

Unique springs, discharging from the surface of an arctic glacier, release H(2)S and deposit native sulfur, gypsum, and calcite. The presence of sulfur in three oxidation states indicates a complex series of redox reactions. Physical and chemical conditions of the spring water and surrounding environment, as well as mineralogical and isotopic signatures, suggest biologically mediated reactions. Cell counts and DNA analyses confirm bacteria are present in the spring system, and a limited number of sequenced isolates suggests that complex communities of bacteria live within the glacial system.