Rotation dynamics and internal structure of self-assembled binary paramagnetic colloidal clusters.

We study experimentally and theoretically the dynamics of two-dimensional self-assembled binary clusters of paramagnetic colloids of two different sizes and magnetic susceptibilities under a time-varying magnetic field. Due to the continuous energy input by the rotating field, these clusters are at a state of dissipative nonequilibrium. Dissipative viscoelastic shear waves traveling around their interface enable the rotation of isotropic binary clusters. The angular velocity of a binary cluster is much slower than that of the magnetic field; it increases with the concentration of big particles, and it saturates at a concentration threshold. We generalize an earlier theoretical model to successfully account for the observed effect of cluster composition on cluster rotation. We also investigate the evolution of the internal distribution of the two particle types, reminiscent of segregation in a drop of two immiscible liquids, and the effect of this internal structure on rotation dynamics. The binary clusters exhibit short-range order, which rapidly vanishes at a larger scale, consistent with the clusters' viscoelastic liquid behavior.

Dissipative non-equilibrium dynamics of self-assembled paramagnetic colloidal clusters.

We study experimentally and theoretically the dynamics of two-dimensional clusters of paramagnetic colloids under a time-varying magnetic field. These self-assembled clusters are a dissipative non-equilibrium system with shared features with aggregates of living matter. We investigate the dynamics of cluster rotation and develop a theoretical model to explain the emergence of collective viscoelastic properties. The model successfully captures the observed dependence on particle, cluster, and field characteristics, and it provides an estimate of cluster viscoelasticity. We also study the rapid cluster disassembly in response to a change in the external field. The experimentally observed disassembly dynamics are successfully described by a model, which also allows estimating the particle-substrate friction coefficient. Our study highlights physical mechanisms that may be at play in biological aggregates, where similar dynamical behaviors are observed.

Ordering of sedimenting paramagnetic colloids in a monolayer.

Sedimentation enables self-assembly of colloidal particles into crystalline structures, as needed for catalysis or photonics applications. Here we combine experiments, theory, and simulations to investigate the equilibrium structure of a colloidal monolayer with tunable interparticle repulsion via an applied external magnetic field. Experimental observations of the equilibrium structure are in excellent agreement with density functional theory. Within a (zero-temperature) local density approximation, we derive a simple analytical expression that quantitatively captures the inhomogeneous ordering ranging from solid to liquidlike states. Monte Carlo simulations corroborate these findings and explore an even wider range of sedimentation conditions, thus providing a global view of the sedimentation-mediated ordering in colloidal monolayers with tunable long-ranged interparticle repulsions. Our findings shed further light on the classical sedimentation problem in colloidal science and related areas.

Resonant reshaping of colloidal clusters on a current carrying wire.

Colloids in confined geometries promise a path towards tailored microscopic superstructures. Yet, a major roadblock is posed by kinetically trapped states that prevent the assemblies from reaching their anticipated shapes. We investigate magnetic colloids trapped on a cylindrical surface of a current carrying wire. If kinetic traps could be avoided the wire's surface would act as an ideal mold for colloidal rings and helical fibers. We devise here a way to dynamically shake down the clusters and avoid kinetic traps in their energy landscape. A low frequency magnetic modulation wave around the wire axis effectively eliminates defects from the clusters and stretches them into slender rings and helical filaments. A theoretical model is developed that qualitatively explains the observed resonant reshaping response of clusters.

Quantitatively mimicking wet colloidal suspensions with dry granular media.

Athermal two-dimensional granular systems are exposed to external mechanical noise leading to Brownian-like motion. Using tunable repulsive interparticle interaction, it is shown that the same microstructure as that observed in colloidal suspensions can be quantitatively recovered at a macroscopic scale. To that end, experiments on granular and colloidal systems made up of magnetized particles as well as computer simulations are performed and compared. Excellent agreement throughout the range of the magnetic coupling parameter is found for the pair distribution as well as the bond-orientational correlation functions. This finding opens new ways to efficiently and very conveniently explore phase transitions, crystallization, nucleation, etc in confined geometries.

Strain-induced droplet retraction memory in a pickering emulsion.

We studied the deformation and relaxation of a water droplet covered with polystyrene latex particles (diameter ca. 200 nm) and embedded in an immiscible fluid after a large strain jump. We show that the presence of the solid particles at the droplet interface slows down the retraction kinetics in comparison with a pure water droplet and induces flow singularity not observed with pure water droplets. The terminal relaxation time of the retraction process, defined as the characteristic time required for the droplet to relax to its spherical equilibrium shape, increases linearly with the applied strain. This result implies a memory effect induced by the presence of solid particles at the droplet interface in a solid-stabilized or Pickering emulsion.

Evidence for three-dimensional unstable flows in shear-banding wormlike micelles.

We report on an experimental study of the shear-banding phenomenon in the concentrated wormlike micellar system CTAB at 20wt.% in D2O . Time-resolved velocity profiles are recorded using ultrasonic velocimetry simultaneously to global rheological data. Our results confirm the studies performed previously by Fischer and Callaghan [Phys. Rev. E 64, 011501 (2001)]. Time averaged velocity profiles display an unsheared "nematic gel." In the range of applied shear rate, the flow field exhibits very fast temporal fluctuations. Suspicions for the presence of three-dimensional flow are evidenced and possible causes for a three-dimensional instability are discussed together with the coupling of wall slip to bulk dynamic.

Yielding and flow in adhesive and nonadhesive concentrated emulsions.

The nonlinear rheological response of soft glassy materials is addressed experimentally by focusing on concentrated emulsions where interdroplet attraction is tuned through varying the surfactant content. Velocity profiles are recorded using ultrasonic velocimetry simultaneously to global rheological data in the Couette geometry. Our data show that nonadhesive and adhesive emulsions have radically different flow behaviors in the vicinity of yielding: while the flow remains homogeneous in the nonadhesive emulsion and the Herschel-Bulkley model for a yield stress fluid describes the data very accurately, the adhesive system displays shear localization and does not follow a simple constitutive equation, suggesting that the mechanisms involved in yielding transitions are not universal.

Spatiotemporal dynamics of wormlike micelles under shear.

Velocity profiles in a wormlike micelle solution (cetyl trimethyl ammonium bromide in D2O) are recorded using ultrasound every 2 s during a startup experiment into the shear-banding regime. The stress relaxation occurs over more than 6 h and corresponds to the very slow nucleation and growth of the high-shear band. Moreover, oscillations of the interface position with a period of about 50 s are observed during the growth process. Strong wall slip, metastable states, and transient nucleation of three-band flows are also reported and discussed in light of previous experiments and theoretical models.