RESUMO
Phosphate rock is a finite, non-renewable mineral resource that is used primarily in fertiliser production. The scarcity and the increasing demand for this finite material led the European Commission to include it in the critical raw material list in 2014. As a consequence, efforts have been directed towards enhancing material use efficiency, initiating recycling efforts, and formulating waste policies to mitigate the criticality of raw materials. Interest in the development of technologies for nutrient recovery from organic waste streams has increased in recent years, and dairy processing sludge (DPS) is a potential input waste stream. Although the recovery of P from DPS can contribute to more circular flows of nutrients in society, it has to be assessed whether there are also overall environmental gains. This paper reports on a life cycle assessment (LCA) of the environmental impacts of three scenarios for phosphorus (P) recovery involving hydrothermal carbonization (HTC) and struvite precipitation and a comparison to a reference drying scenario. HTC produces a solid fraction (hydrochar), and a liquid fraction (process water) and in one of the scenarios (Scenario 3), leaching the hydrochar for additional P recovery is considered. From the process water as well as from the hydrochar leachate, P is precipitated in the form of struvite. Scenarios 1 and 2 both consider HTC and struvite production with the only difference that the hydrochar is used as a fuel instead of as a fertilizer in the latter case, and Scenario 3 adds leaching of the hydrochar with subsequent struvite production and considers that hydrochar is used as a fuel. In the fourth (reference) scenario, dewatering and drying of DPS is considered. The recovered product use in agriculture was not assessed at this stage. The assessment of the emerging technologies in Scenarios 1-3 was done by studying the technologies in early stages of development but modelling them as more developed in the future. Additional functions beyond the functional unit of one kg of P recovered were handled through a system expansion by substitution approach. This way, the system was credited for calcium ammonium nitrate (CAN) production in all scenarios and for wood chips production in Scenarios 2 and 3. Looking at net outcomes for all scenarios, the life cycle impact indicator results for scenario 2 are lower than the other scenarios in several impact categories. Large gains in scenario 2 are related to the avoided production of wood chips.
