RESUMO
Cross-laminated timber (CLT) has become a massive commercial success in recent years due to its high performance, technological advantages, and low environmental impact. The finite softwood raw material supply has motivated researchers to find alternatives. This study presents an investigation of the viability of some Hungarian hardwood materials, such as CLT materials. Homogeneous beech, poplar, and spruce panels, as well as their combinations, were created using a polyurethane adhesive. The experimental results show the clear potential of Hungarian poplar, which performed much better than spruce. Poplar's modulus of elasticity (MOE) and modulus of rupture (MOR) values reached or exceeded those of high-grade commercial softwood CLT. The bending properties of beech and hybrid beech-poplar panels far exceeded the performance of commercial panels, which shows the excellent potential of high-density hardwoods for high-performance CLT production. Beech-spruce hybrid panels seriously underperformed. This was caused by gluing issues, probably due to the large density differences between the two species, as evidenced by the glueline failure exhibited by most of these specimens during testing. The average panel density proved to be the best predictor of mechanical performance, except for beech-spruce hybrid panels.
RESUMO
The green and facile synthesis of metallic silver nanoparticles (AgNPs) is getting tremendous attention for exploring superior applications because of their small dimensions and shape. AgNPs are already proven materials for superior coloration, biocidal, thermal, UV-protection, and mechanical performance. Originally, some conventional chemical-based reducing agents were used to synthesize AgNPs, but these posed potential risks, especially for enhanced toxicity. This became a driving force to innovate plant-based sustainable and green metallic nanoparticles (NPs). Moreover, the synthesized NPs using plant-based derivatives could be tuned and regulated to achieve the required shape and size of the AgNPs. AgNPs synthesized from naturally derived materials are safe, economical, eco-friendly, facile, and convenient, which is also motivating researchers to find greener routes and viable options, utilizing various parts of plants like flowers, stems, heartwood, leaves and carbohydrates like chitosan to meet the demands. This article intends to provide a comprehensive review of all aspects of AgNP materials, including green synthesis methodology and mechanism, incorporation of advanced technologies, morphological and elemental study, functional properties (coloration, UV-protection, biocidal, thermal, and mechanical properties), marketing value, future prospects and application, especially for the last 20 years or more. The article also includes a SWOT (Strengths, weaknesses, opportunities, and threats) analysis regarding the use of AgNPs. This report would facilitate the industries and consumers associated with AgNP synthesis and application through fulfilling the demand for sustainable, feasible, and low-cost product manufacturing protocols and their future prospects.
