1.
Chem Commun (Camb)
; 58(31): 4909-4912, 2022 Apr 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35355045
RESUMO
Herein we report the zirconooxaziridine promoted aziridination of alkenes using chloramine T as the quantitative source of N. The reaction works with high yields, diastereoselectivities and stereospecificity for a wide variety of substituted alkenes. A potential mechanism involving the formation of a zirconooxaziridine complex as the active catalyst has been proposed and initial mechanistic data would indicate that a highly associative mechanism is the predominant pathway for this transformation.