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Anal Bioanal Chem ; 390(4): 1173-80, 2008 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-18157665

RESUMO

This work involved the development and application of a new analytical procedure for in-situ characterization of the lability of metal species in aquatic systems by using a system equipped with a diffusion membrane and cellulose organomodified with p-aminobenzoic acid groups (DM-Cell-PAB). To this end, the DM-Cell-PAB system was prepared by adding cellulose organomodified with p-aminobenzoic acid groups (Cell-PAB) to pre-purified cellulose bags. After the DM-Cell-PAB system was sealed, it was examined in the laboratory. The in-situ application involved immersing the DM-Cell-PAB system in two different rivers, enabling us to study the relative lability of metal species (Cu, Cd, Fe, Mn, and Ni) as a function of time and quantity of exchanger. The procedure is simple and opens up a new perspective for understanding environmental phenomena relating to the complexation, transport, stability, and lability of metal species in aquatic systems rich in organic matter.


Assuntos
Celulose , Resinas de Troca Iônica , Metais/análise , Água/química , Adsorção , Substâncias Húmicas , Concentração de Íons de Hidrogênio , Espectrofotometria Atômica , Temperatura
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