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Angew Chem Int Ed Engl
; 37(9): 1220-1223, 1998 May 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29711236
RESUMO
The largest inorganic molecular system so far, [(MoO3 )176 (H2 O)80 H32 ] (1; the picture on the right shows the polyhedral representation), which has been characterized by X-ray structure analysis, possesses a cavity of diameter 2.3 nm and remarkably shows the stoichiometry of a (reduced) protonated and hydrated "molecular molybdenum trioxide". It is formed by reduction of an aqueous solution of lithium molybdate with tin(II) chloride at very high H+ concentrations.