Dynamics of a wetting layer and Marangoni convection in microgravity.

Near the liquid-vapor critical point in pure fluids, material and thermal properties vary considerably with temperature. In a series of microgravity experiments, sulfur hexafluoride (SF6) was heated ∼1 K above its critical temperature, then quenched below the critical temperature in order to form gas and liquid domains. We found a power law exponent of 0.389 ± 0.010 for the growth of the wetting layer thickness during the intermediate stage of phase separation. Full and microscopic view images of the sample cell unit were analyzed to determine the changes in the size distribution of liquid droplets inside the gas phase over time. We found that the distribution of diameters for liquid droplets always contains a fraction of very small droplets, presumably due to a continuous nucleation process. At the same time, the size distribution flattens over time and rapidly includes large-size droplets, presumably generated through a coalescence mechanism. By following both a large gas bubble over two hours of video recordings, we found periodic and synchronous motion of the gas bubble along both the x and y directions. By following a large liquid droplet embedded into the large gas bubble, we found periodic, out of phase motions, which we related to Marangoni convection. The experimentally measured velocity of the liquid droplet is in good agreement with the theoretical predicted velocity of ∼0.386 µm/s obtained from Young's thermocapillary effect.

Relaxation of nonspherical sessile drops towards equilibrium.

We present a theoretical study related to a recent experiment on the coalescence of sessile drops. The study deals with the kinetics of relaxation towards equilibrium, under the action of surface tension, of a spheroidal drop on a flat surface. For such a nonspherical drop under partial wetting conditions, the dynamic contact angle varies along the contact line. We propose a new nonlocal approach to the wetting dynamics, where the contact line velocity depends on the geometry of the whole drop. We compare our results to those of the conventional approach in which the contact line velocity depends only on the local value of the dynamic contact angle. The influence on drop dynamics of the pinning of the contact line by surface defects is also discussed.