Remarkable signals of the ancient Chinese civilization since the Early Bronze Age in the marine environment.

The signals of fire activity induced from climate and ancient human activities could be recorded in sedimentary strata. We examined a 6000-year black­carbon (BC) record-including char and soot-of a sediment core from the South Yellow Sea. The climate change had a threshold effect on the fire regime, and dominated the char emissions. The soot/BC signals depicted that the anthropogenic emissions related to the evolution of the Chinese civilization since the Early Bronze Age (~4 ka) have overwhelmed natural soot emissions. The soot variation in the record closely matched periods when there was large-scale use of coal or charcoal after the Han Dynasty and when indigenous coking technology was promoted after the Tang Dynasty; low soot-abundance in the record coincided with periods of social unrest. This work illustrates how soot signals can be a robust tracer of civilization evolution.

Variability of heavy metal transport during the water-sediment regulation period of the Yellow River in 2018.

To understand the impacts of the human-induced flood event on heavy metal (HM) transport, spatiotemporal variations in contents and fluxes of metals (Cr, Ni, Cu, Zn, As, Pb, Cd), Pb stable isotopes and characteristics of water and sediment transport into the sea during Water-Sediment Regulation Scheme (WSRS) in Yellow River (YR) were studied based on field investigation at Xiaolangdi Reservoir (XLD), Lijin Station and Yellow River estuary (YRE). The HM transport was significantly controlled by hydrological process and dominated by particulate form with strong associations with particle size and suspended sediment concentration (SSC). In first stage, dissolved heavy metal (DHM) and particulate heavy metal (PHM) contents both increased significantly as coarser sediment with a mixed source of downstream river channel and XLD, while that maintained higher value for stable source of fine-grained XLD sediment in second stage. The HMs into the sea were mainly originated from upper and middle reaches but also contributed by human emissions from downstream area. As the source of HMs into the sea, the downstream area also acted as an important sink, especially in first stage, playing a role of buffering and filtration. During WSRS, the YR discharged 49%-60% of annual HM flux into the sea, and the second stage is the main transport period, leading to a great alternation in geochemical composition of the YRE sediment.

Community Structure, Abundance and Potential Functions of Bacteria and Archaea in the Sansha Yongle Blue Hole, Xisha, South China Sea.

The Sansha Yongle Blue Hole is the deepest blue hole in the world and exhibits unique environmental characteristics. In this paper, Illumina sequencing and qPCR analysis were conducted to obtain the microbial information in this special ecosystem. The results showed that the richness and diversity of bacterial communities in the hole was greater than those of archaeal communities, and bacterial and archaeal communities were dominated by Proteobacteria and Euryarchaeota, respectively. Temperature and nitrate concentration significantly contributed to the heterogeneous distribution of major bacterial clades; salinity explained most variations of the archaeal communities, but not significant. A sudden increase of bacterial 16S rRNA, archaeal 16S rRNA, ANAMMOX 16S rRNA, nirS and dsrB gene was noticed from 90 to 100 m in the hole probably due to more phytoplankton at this depth. Sulfur oxidation and nitrate reduction were the most abundant predicted ecological functions in the hole, while lots of archaea were predicted to be involved in aerobic ammonia oxidation and methanogenesis. The co-occurrence network analysis illustrated that a synergistic effect between sulfate reduction and sulfur oxidation, and between nitrogen fixation and denitrification, a certain degree of coupling between sulfur and nitrogen cycle was also observed in the hole. The comparisons of bacterial and archaeal communities between the hole and other caves in the world (or other areas of the South China Sea) suggest that similar conditions are hypothesized to give rise to similar microbial communities, and environmental conditions may contribute significantly to the bacterial and archaeal communities.

Impact of water-sediment regulation on the transport of heavy metals from the Yellow River to the sea in 2015.

Variations in particulate and dissolved heavy metal (Cu, Co, Ni, Zn, Pb, Cr, Cd and As) concentrations and fluxes as well as their response to the Water-Sediment Regulation Scheme (WSRS) process in 2015 were studied based on a daily water and sediment survey at Lijin gauge. The results showed that the water and sediment flux increased rapidly in the first stage of the WSRS, which was characterized by high water discharge and suspended sediment concentration (SSC). The suspended sediment was coarser than the natural state, while the particulate and dissolved heavy metal contents increased. In the second stage, the SSC decreased rapidly followed by a gradual reduction in water discharge, the suspended sediment became even coarser and both the particulate and dissolved metal contents showed a decreasing trend. The heavy metal flux during the WSRS period accounted for 42%-54% of the total year, and the transport form was dominated by the particulate form. Dissolved metal contents were affected by the release of heavy metals derived from the channel in the lower reaches, while particulate heavy metals mainly came from erosion of the riverbed and their contents were much lower than Xiaolangdi reservoir sediment. Heavy metal transportation was influenced significantly by the WSRS process. Changes in sediment flux resulted in significant differences in the flux of heavy metals and the distribution of metals in different transport forms between the first and second stage of WSRS.

Seasonal variability and flux of particulate trace elements from the Yellow River: impacts of the anthropogenic flood event.

In this study, the suspended particulate matter (SPM) of the Yellow River (Huanghe) was collected biweekly at the outlet and analyzed for particulate trace element contents. The seasonal variations of the trace elements were primarily controlled by hydrological processes, which determined different sources of the SPM. Moreover, As, Co, Cr, and Ni primarily originated from lithogenic sources, whereas Cd, Cu, Pb and Zn were influenced by anthropogenic activities. The Yellow River has suffered moderate to considerable ecological risk during the late stage of Water and Sediment Regulation (WSR). Using the discharge-weighted contents method, the annual trace element fluxes were estimated, with ca. 30% of the annual fluxes occurring within the short WSR period (6% of one year). More specifically, 75% of the Cd flux was from an anthropogenic source, which likely posed a significant threat to the estuary and the adjacent coastal ecosystems.